D(+)-Phenylalaninol

ChemicalBook > CAS DataBase List > D(+)-Phenylalaninol

D(+)-Phenylalaninol

Detected method

Product Name: D(+)-Phenylalaninol
CAS No.: 5267-64-1
Chemical Name: D(+)-Phenylalaninol
Synonyms: D-PHENYLALANINOL;H-D-PHE-OL;D-Phenylalanino;(R)-2-AMINO-3-PHENYL-1-PROPANOL;(2R)-2-amino-3-phenylpropan-1-ol;(R)-2-AMINO-3-PHENYL-PROPAN-1-OL;H-D-Phen-ol;R-228060-001;D-PHENYLANINOL;D-PHEYLALANINOL
CBNumber: CB9741308
Molecular Formula: C9H13NO
Formula Weight: 151.21
MOL File: 5267-64-1.mol

Less

D(+)-Phenylalaninol Property

Melting point:: 93-95 °C(lit.)
Boiling point:: 122 °C / 4mmHg
alpha: 23 º (c=1.2, 1 N HCl 22 ºC)
Density: 1.0406 (rough estimate)
refractive index: 23.5 ° (C=1.2, 1mol/L HCl)
storage temp.: Keep in dark place,Sealed in dry,Room Temperature
solubility: Soluble in Dichloromethane, Ethyl Acetate, Methanol.
form: Crystalline Powder and Chunks
pka: 12.85±0.10(Predicted)
color: White to yellow
optical activity: [α]/D +22.8°, c = 1.2 in 1 M HCl
Sensitive: Air Sensitive
BRN: 4665408
InChI: InChI=1/C9H13NO/c10-9(7-11)6-8-4-2-1-3-5-8/h1-5,9,11H,6-7,10H2/t9-/s3
InChIKey: STVVMTBJNDTZBF-DJEYLCQNNA-N
SMILES: C(C1C=CC=CC=1)[C@@H](N)CO |&1:7,r|
CAS DataBase Reference: 5267-64-1(CAS DataBase Reference)

Less

Safety

Hazard Codes: C,Xi
Risk Statements: 34
Safety Statements: 26-36/37/39-45-27
RIDADR: UN 3259 8/PG 3
WGK Germany: 3
F: 10-23
HazardClass: IRRITANT
HazardClass: 8
PackingGroup: III
HS Code: 29221990

Less

Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Danger

Hazard statements

H314Causes severe skin burns and eye damage

Precautionary statements

P260Do not breathe dust/fume/gas/mist/vapours/spray.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P363Wash contaminated clothing before reuse.

Less

N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 284491
Product name: (R)-(+)-2-Amino-3-phenyl-1-propanol
Purity: 98%
Packaging: 5g
Price: $142
Updated: 2023/01/07

TCI Chemical

Product number: P1289
Product name: D-Phenylalaninol
Purity: >98.0%(GC)(T)
Packaging: 5g
Price: $72
Updated: 2024/03/01

TCI Chemical

Product number: P1289
Product name: D-Phenylalaninol
Purity: >98.0%(GC)(T)
Packaging: 25g
Price: $218
Updated: 2024/03/01

Alfa Aesar

Product number: L09697
Product name: D-Phenylalaninol, 98%
Packaging: 1g
Price: $40.65
Updated: 2024/03/01

Usbiological

Product number: 019430
Product name: D-Phenylalaninol
Packaging: 5g
Price: $403
Updated: 2021/12/16

Less

D(+)-Phenylalaninol Chemical Properties,Usage,Production

Detected method

Phenomena, including gelation and fluorescence, are used as easily detected sensors of chiral recognition. Qin et al. have developed a new type of isomerized diphenylalanine-based supramolecular gel (LFDF), which showed the visible enantiomeric discrimination of phenylalaninol enantiomers via fluorescence and gelation measurements. The addition of L- or D-phenylalaninol to the peptide gel led to complete collapse within one minute after adding the L-form, which was not observed in D-phenylalaninol. Meanwhile, by doping with the fluorescent dye thioflavin T (ThT), the prepared ThT-LFDF gel system can sensitively detect the L/D-phenylalanine enantiomer through fluorescence quenching, which has the advantages of visualization, easy manipulation, and high detection sensitivity.

Description

D-phenylalanine is the D-enantiomer of phenylalanine. It is a conjugate base of a D-phenylalaninium and an enantiomer of a L-phenylalanine. D-Phenylalanine is a metabolite found in or produced by Escherichia coli (strain K12, MG1655). It may be light-sensitive. This compound reacts with strong oxidizing agents, acids and bases. It acts as a weak acid in solution.

Chemical Properties

white to light yellow crystal powde

Uses

D-Phenylalaninol is used as a chiral auxiliary for asymmetric Michael reactions. It is an enantiomer of L-Phenylalaninol, an inhibitor of intestinal Phenylalanine absorption. It acts as an inhibiting agent to the enzymes which are responsible for the breakdown of endorphins.

Purification Methods

It can be recrystallised from Et2O, *C6H6/pet ether (b 40-60o) or toluene and distilled in a vacuum. It has been purified by dissolving in Et2O, drying over K2CO3, filtering, evaporating to a small volume, cooling in ice and collecting the plates. Store them in the presence of KOH (i.e. CO2—free atm). [Karrer & Ehrhardt Helv Chim Acta 34 3203 1951, Oeda Bull Chem Soc Jpn 13 465 1938.] The picrate has m 141-141.5o (from EtOH/pet ether). The hydrogen oxalate has m 177o, 161-162o [Hunt & McHale J Chem Soc 2073 1957]. The racemate has m 87-88o from *C6H6/pet ether (75-77o from Et2O), and the hydrochloride has m 139-141o [Fodor et al. J Chem Soc 1858 1951]. [Beilstein 13 IV 1920.]

D(+)-Phenylalaninol Preparation Products And Raw materials

Raw materials

Preparation Products

Less

D(+)-Phenylalaninol Suppliers

Americas 1 Austria 1 Belgium 3 Canada 3 China 364 Europe 6 France 2 Germany 10 India 24 Italy 1 Japan 7 Russia 1 Slovakia 1 South Korea 1 Switzerland 2 The Netherlands 1 Ukraine 1 United Kingdom 20 United States 68 Global 518

Pure Chemistry Scientific Inc.

Tel: 001-857-928-2050 or 1-888-588-9418
Fax: 001-617-206-9595
Email: sales@chemreagents.com
Country: United States
ProdList: 10186
Advantage: 62

HBCChem, Inc.

Tel: +1-510-219-6317
Fax: +1-650-486-1361
Email: sales@hbcchem.com
Country: United States
ProdList: 10648
Advantage: 60

Accela ChemBio Inc.

Tel: +1(858) 699-3322
Fax: +1(858) 876-1948
Email: marketing@accelachem.com
Country: United States
ProdList: 6024
Advantage: 65

TargetMol Chemicals Inc.

Tel: +1-781-999-5354 +1-00000000000
Email: marketing@targetmol.com
Country: United States
ProdList: 32165
Advantage: 58

BOC Sciences

Tel: 16314854226; +16314854226
Email: inquiry@bocsci.com
Country: United States
ProdList: 19741
Advantage: 58

Accela ChemBio Inc.

Tel: +1-858-6993322
Fax: (+1)-858-876-1948
Email: info@accelachem.com
Country: United States
ProdList: 17322
Advantage: 58

Alchem Pharmtech,Inc.

Tel: 8485655694
Email: sales@alchempharmtech.com
Country: United States
ProdList: 63687
Advantage: 58

Aladdin Scientific

Tel: +1-+1(833)-552-7181
Email: sales@aladdinsci.com
Country: United States
ProdList: 57505
Advantage: 58

Aceschem Inc.

Tel: +1-817863-6948 +1-（817）863-6948
Email: sales@aceschem.com
Country: United States
ProdList: 19632
Advantage: 58

Alfa Chemistry

Tel: --
Fax: --
Email: info@Alfa-Chemistry.com
Country: United States
ProdList: 6814
Advantage: 0

Fluorochem Ltd.

Tel: --
Fax: --
Email: enquiries@fluorochem.co.uk
Country: United States
ProdList: 4583
Advantage: 58

AstaTech, Inc.

Tel: --
Fax: --
Email: sales@astatechinc.com
Country: United States
ProdList: 904
Advantage: 58

Alichem Inc.

Tel: --
Fax: --
Email: sales@alichem.com
Country: United States
ProdList: 6167
Advantage: 58

Redox Scientific

Tel: --
Fax: --
Email: info@redoxsci.com
Country: United States
ProdList: 2380
Advantage: 58

Brightek LLC

Tel: --
Fax: --
Country: United States
ProdList: 782
Advantage: 58

Advanced ChemTech (a division of CreoSalus Inc.)

Tel: --
Fax: --
Email: info@advancedchemtech.com
Country: United States
ProdList: 177
Advantage: 58

VWR International, LLC.

Tel: --
Fax: --
Email: @sargentwelch.com
Country: United States
ProdList: 6262
Advantage: 58

OChem Incorporation

Tel: --
Fax: --
Email: sales@ocheminc.com
Country: United States
ProdList: 6501
Advantage: 60

AAPPTEC

Tel: --
Fax: --
Email: info@aapptec.com
Country: United States
ProdList: 533
Advantage: 0

Oakwood Products, Inc.

Tel: --
Fax: --
Email: sales@oakwoodchemical.com
Country: United States
ProdList: 6193
Advantage: 74

Chiral Management

Tel: --
Fax: --
Email: sales@chiralmanagement.com
Country: United States
ProdList: 1332
Advantage: 30

SynQuest Laboratories, Inc.

Tel: --
Fax: --
Email: info@synquestlabs.com
Country: United States
ProdList: 6871
Advantage: 62

Riedel-de Haen AG

Tel: --
Fax: --
Country: United States
ProdList: 6773
Advantage: 87

TCI America

Tel: --
Fax: --
Email: sales@tciamerica.com
Country: United States
ProdList: 6909
Advantage: 75

Frontier Scientific, Inc.

Tel: --
Fax: --
Email: sales@frontiersci.com
Country: United States
ProdList: 6222
Advantage: 86

Matrix Scientific

Tel: --
Fax: --
Email: sales@matrixscientific.com
Country: United States
ProdList: 6632
Advantage: 80

SK Energy and Chemical, Inc.

Tel: --
Fax: --
Email: info@skechem.com
Country: United States
ProdList: 78
Advantage: 50

Hexagon Labs

Tel: --
Fax: --
Email: sales@hexagonlabs.com
Country: United States
ProdList: 437
Advantage: 50

Labseeker Inc

Tel: --
Fax: --
Email: marketing@labseeker.com
Country: United States
ProdList: 1495
Advantage: 55

Anvia Chemicals, LLC

Tel: --
Fax: --
Email: sales@anviachem.com
Country: United States
ProdList: 3933
Advantage: 0

HBCChem Inc.

Tel: --
Fax: --
Email: sales@hbcchem-inc.com
Country: United States
ProdList: 4569
Advantage: 30

3B Scientific Corporation

Tel: --
Fax: --
Email: sales@3bsc.com
Country: United States
ProdList: 6962
Advantage: 56

Waterstone Technology, LLC

Tel: --
Fax: --
Email: sales@waterstonetech.com
Country: United States
ProdList: 6786
Advantage: 30

AlliChem, LLC

Tel: --
Fax: --
Email: sales@allichemllc.com
Country: United States
ProdList: 6516
Advantage: 60

Combi-Blocks Inc.

Tel: --
Fax: --
Email: sales@combi-blocks.com
Country: United States
ProdList: 6618
Advantage: 69

Chem-Impex International, Inc.

Tel: --
Fax: --
Country: United States
ProdList: 6730
Advantage: 64

Magical Scientific LLC

Tel: --
Fax: --
Country: United States
ProdList: 703
Advantage: 0

Rintech, Inc.

Tel: --
Fax: --
Email: info@rintechinc.com
Country: United States
ProdList: 3416
Advantage: 60

Ivy Fine Chemicals

Tel: --
Fax: --
Email: sales@ivychem.com
Country: United States
ProdList: 6493
Advantage: 58

NetQem

Tel: --
Fax: --
Email: sales@netqem.us
Country: United States
ProdList: 1641
Advantage: 38

Beta Pharma, Inc.

Tel: --
Fax: --
Email: sales@betapharma.com
Country: United States
ProdList: 6226
Advantage: 60

INDOFINE Chemical Company, Inc.

Tel: --
Fax: --
Email: chemical@indofinechemical.com
Country: United States
ProdList: 6176
Advantage: 69

The K-Genix Group

Tel: --
Fax: --
Email: export@k-genix.com
Country: United States
ProdList: 31
Advantage: 64

2A PharmaChem USA

Tel: --
Fax: --
Email: sales@2apharmachem.com
Country: United States
ProdList: 6137
Advantage: 39

3B Scientific Corporation

Tel: --
Fax: --
Email: sales@3bsc.com
Country: United States
ProdList: 6718
Advantage: 47

HONEST JOY HOLDINGS LIMITED

Tel: --
Fax: --
Email: sales@honestjoy.cn
Country: United States
ProdList: 6675
Advantage: 54

APAC Pharmaceutical, LLC

Tel: --
Fax: --
Email: sales@apacpharma.com
Country: United States
ProdList: 6322
Advantage: 38

Chemiplus Corporation

Tel: --
Fax: --
Email: okazaki@chemiplus.com
Country: United States
ProdList: 3198
Advantage: 38

Global Pharma Sourcing, LLC

Tel: --
Fax: --
Email: philma@globalphs.com
Country: United States
ProdList: 323
Advantage: 58

Syntech Labs

Tel: --
Fax: --
Email: info@syntechlabs.com
Country: United States
ProdList: 730
Advantage: 43

Less

View Lastest Price from D(+)-Phenylalaninol manufacturers

WUHAN FORTUNA CHEMICAL CO., LTD

Product: D(+)-Phenylalaninol 5267-64-1
Price: US $0.00/Kg/Drum
Min. Order: 1KG
Purity: 98%min
Supply Ability: 1000kg
Release date: 2021-08-28

Sichuan HongRi Pharma-Tech Co.,Ltd

Product: d-phe-ol 5267-64-1
Price: US $0.00-0.00/kg
Min. Order: 1kg
Purity: 98%
Supply Ability: 1T+
Release date: 2024-01-20

Hebei Chuanghai Biotechnology Co,.LTD

Product: D(+)-Phenylalaninol 5267-64-1
Price: US $5.00-2.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 10000kg
Release date: 2024-08-23

5267-64-1, D(+)-PhenylalaninolRelated Search:

TRISTEARIN Tris(hydroxymethyl)aminomethane Dexketoprofen trometamol (S)-(-)-2-Methyl-1-butanol Phenprobamate ALTRENOGEST 1-Phenyl-2-nitropropene Acetaminophen PHENYL VALERATE 6-Aminocaproic acid 1-Propanol Fosfomycin tromethamine Ketorolac tromethamine Glycine Diethylstilbestrol Isopropyl alcohol EC 2.6.1.2 D-Phenylglycinol

D-(+)-Phenylalinol

S/R-Phenylalaninol

(2R)-2-amino-3-phenylpropan-1-ol

BENZENEPROPANOL, .BETA.-AMINO-, (.BETA.R)-

D-Penylalaninol

D-PHEYLALANINOL

D-PHENYLANINOL

(D)-(+)-2-PHENYLALANINOL / D-(+)-2-AMINO-3-PHENYL-1-PROPANOL

D-Phenylalaninol(R+Phenylalaninol)

Benzenepropanol, beta-amino-, (R)-

D-Phenylalaninol ,98%

(R)-3-Phenyl-2-amino-1-propanol

(R)-3-Phenyl-2-aminopropane-1-ol

(αR)-α-(Hydroxymethyl)benzeneethanamine

H-D-Phen-ol

D(+)-2-Amino-3-phenyl-1-propanol,98%

D-PHENYLALANINOL ((R)-(+)-2-AMINO-3-PHENYL-1-PROPANOL)

((1R)-1-HydroxyMethyl-2-phenylethyl)aMine

(2R)-2-AMino-3-phenyl-1-propanol

(R)-(+)-2-AMino-3-phenyl-1-glycinol

(R)-2-AMino-1-hydroxy-3-phenylpropane

(R)-2-BenzylethanolaMine

(βR)-β-AMino-benzenepropanol

D-Phenylalaninol, (2R)-2-Amino-1-hydroxy-3-phenylpropane

BENZENEPROPANOL, B-AMINO-, (BR)-

D-(R)-PHENYLALANINOL

(+)-D-PHENYLALANINOL

D(+)-PHENYLALANINOL

D-PHENYLALANINOL

D-ALPHA-PHENYLALANINOL

D(+)-2-AMINO-3-PHENYL-1-PROPANOL

D-2-PHENYLALANINOL

H-D-PHE-OL

H-D-PHENYLALANINOL

(R)-(+)-2-AMINO-3-PHENYL-1-PROPANOL

(R)-2-AMINO-3-PHENYL-1-PROPANOL

(R)-2-AMINO-3-PHENYL-PROPAN-1-OL

(R)-(+)-PHENYLALANINOL

(R)-PHENYLALANINOL

PHENYLALANINOL-D

(R)-2-amino-3-phenylpropanol

(R)-2-Amino-3-phenyl-1-propanol D(+)-Phenylalaninol D(+)-2-Amino-3-phenyl-1-propanol

D-2-Amino-3-phenyl-1-propanol,99%e.e.

R-228060-001

(R)-(+)-2-Amino-3-phenyl-1-propanol 98%

D-Phenylalaninol&gt

Benzenepropanol, β-amino-, (βR)-

D-Phenylalanino

D(+)-Phenylalaninol USP/EP/BP

D-(+)-2-Amino-3-phenyl-1-proanol

(+)-D-Phenylalaninol

(2S)-2-amino-1-phenylpropan-1-ol

5267-64-1

15267-64-1

Amino Alcohols (Chiral)

Chiral Building Blocks

Asymmetric Synthesis

Amino Acid Derivatives