Methylmagnesium chloride
- Product Name
- Methylmagnesium chloride
- CAS No.
- 676-58-4
- Chemical Name
- Methylmagnesium chloride
- Synonyms
- CH3MgClinTHF;chloromethyl-magnesiu;Methylchloromagnesium;METHYLMAGNESIUM CHLORIDE;Magnesium, chloromethyl-;Methyl(chloro) magnesium;Magnesium carbanide chloride;Methylmagnesium chloride 3.0 M;METHYLMAGNESIUM CHLORIDE IN TFE;Methylmagnesiumchloride,3MinTHF
- CBNumber
- CB9774414
- Molecular Formula
- CH3ClMg
- Formula Weight
- 74.79
- MOL File
- 676-58-4.mol
Methylmagnesium chloride Property
- Boiling point:
- 66 °C
- Density
- 1.013 g/mL at 25 °C
- Flash point:
- −1 °F
- storage temp.
- Store below +30°C.
- solubility
- Miscible with diethyl ether and tetrahydrofuran.
- form
- Liquid
- color
- Pale brown to dark green
- Water Solubility
- reacts
- Sensitive
- Air & Moisture Sensitive
- BRN
- 3587199
- Exposure limits
- ACGIH: TWA 50 ppm; STEL 100 ppm (Skin)
OSHA: TWA 200 ppm(590 mg/m3)
NIOSH: IDLH 2000 ppm; TWA 200 ppm(590 mg/m3); STEL 250 ppm(735 mg/m3) - CAS DataBase Reference
- 676-58-4(CAS DataBase Reference)
- EPA Substance Registry System
- Magnesium, chloromethyl- (676-58-4)
Safety
- Hazard Codes
- F,C
- Risk Statements
- 11-14/15-34-19-15-37-14
- Safety Statements
- 26-30-36/37/39-43-45-7/8-33-29-16
- RIDADR
- UN 3399 4.3/PG 2
- WGK Germany
- 1
- F
- 1-3-10
- Autoignition Temperature
- 609 °F
- TSCA
- Yes
- HazardClass
- 4.3
- PackingGroup
- I
- HS Code
- 29319090
- Hazardous Substances Data
- 676-58-4(Hazardous Substances Data)
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Danger
- Hazard statements
-
H225Highly Flammable liquid and vapour
H260In contact with water releases flammable gases which may ignite spontaneously
H261In contact with water releases flammable gas
H302Harmful if swallowed
H314Causes severe skin burns and eye damage
H318Causes serious eye damage
H335May cause respiratory irritation
H351Suspected of causing cancer
- Precautionary statements
-
P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P231+P232Handle under inert gas. Protect from moisture.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P309IF exposed or if you feel unwell:
P310Immediately call a POISON CENTER or doctor/physician.
P370+P378In case of fire: Use … for extinction.
P402+P404Store in a dry place. Store in a closed container.
P403+P235Store in a well-ventilated place. Keep cool.
N-Bromosuccinimide Price
- Product number
- 189901
- Product name
- Methylmagnesium chloride solution
- Purity
- 3.0 M in THF
- Packaging
- 8l
- Price
- $1390
- Updated
- 2024/03/01
- Product number
- 189901
- Product name
- Methylmagnesium chloride solution
- Purity
- 3.0?M in THF
- Packaging
- 18L
- Price
- $2510
- Updated
- 2024/03/01
- Product number
- 042101
- Product name
- Methylmagnesium chloride, 3M in THF, packaged under Argon in resealable ChemSeal? bottles
- Packaging
- 1mole
- Price
- $164
- Updated
- 2021/12/16
- Product number
- 042101
- Product name
- Methylmagnesium chloride, 3M in THF, packaged under Argon in resealable ChemSeal? bottles
- Packaging
- 0.25mole
- Price
- $50.2
- Updated
- 2021/12/16
- Product number
- 93-1266
- Product name
- Methylmagnesium chloride, 3M in THF
- Packaging
- 0.25mole
- Price
- $43
- Updated
- 2023/01/06
Methylmagnesium chloride Chemical Properties,Usage,Production
Chemical Properties
dark brown solution
Uses
Methylmagnesium chloride is used as a Grignard reagent and an alkylating agent in organic synthesis.
Application
Methylmagnesium chloride solution (3 M in THF) undergoes 1,3-addition with dialdose derived nitrones to form N-benzylhydroxylamines. The reductive cleavage of the N-O bond of these N-benzylhydroxylamines results in N-benzylaminosugars, which are key moieties of bioactive compounds. It can also react with Garner type aldehydes to form the corresponding secondary alcohols.
Preparation
reaction of methyl chloride and magnesium in anhydrous diethyl ether, usually in the presence of an initiator.
Definition
ChEBI: Methylmagnesium chloride is an alkylmagnesium halide and a one-carbon compound. available as a solutionin tetrahydrofuran.
Reactions
Methylmagnesium chloride can react with acidic hydrogen on oxygen, sulfur and alkyne carbon of compounds containing active hydrogen (such as water, alcohol, mercaptan, amine, amide, acid, sulfonic acid, etc.); Propyl bromide, etc.) undergoes a coupling reaction; it can react with oxygen and carbon dioxide, aldehydes, ketones, etc.
Hazard
Flammable, dangerous fire and explosionrisk.
Methylmagnesium chloride Preparation Products And Raw materials
Raw materials
Preparation Products
Methylmagnesium chloride Suppliers
- Tel
- --
- Fax
- --
- info@acros.com
- Country
- Belgium
- ProdList
- 6772
- Advantage
- 81
View Lastest Price from Methylmagnesium chloride manufacturers
- Product
- Methylmagnesium chloride 676-58-4
- Price
- US $110.00-70.00/kg
- Min. Order
- 1kg
- Purity
- 99%
- Supply Ability
- 5000
- Release date
- 2024-08-14
- Product
- Methylmagnesium chloride 676-58-4
- Price
- US $10.00-8.00/kg
- Min. Order
- 1kg
- Purity
- 99%
- Supply Ability
- 10 mt
- Release date
- 2024-12-04
- Product
- Methylmagnesium chloride 676-58-4
- Price
- US $5.00-2.00/KG
- Min. Order
- 1KG
- Purity
- 99%
- Supply Ability
- 10000kg
- Release date
- 2024-08-14