Methylmagnesium chloride

Product Name: Methylmagnesium chloride
CAS No.: 676-58-4
Chemical Name: Methylmagnesium chloride
Synonyms: CH3MgClinTHF;chloromethyl-magnesiu;Methylchloromagnesium;METHYLMAGNESIUM CHLORIDE;Magnesium, chloromethyl-;Methyl(chloro) magnesium;Magnesium carbanide chloride;Methylmagnesium chloride 3.0 M;METHYLMAGNESIUM CHLORIDE IN TFE;Methylmagnesiumchloride,3MinTHF
CBNumber: CB9774414
Molecular Formula: CH3ClMg
Formula Weight: 74.79
MOL File: 676-58-4.mol

More

Less

Methylmagnesium chloride Property

Boiling point:: 66 °C
Density: 1.013 g/mL at 25 °C
Flash point:: −1 °F
storage temp.: Store below +30°C.
solubility: Miscible with diethyl ether and tetrahydrofuran.
form: Liquid
color: Pale brown to dark green
Water Solubility: reacts
Sensitive: Air & Moisture Sensitive
BRN: 3587199
Exposure limits: ACGIH: TWA 50 ppm; STEL 100 ppm (Skin)
OSHA: TWA 200 ppm(590 mg/m3)
NIOSH: IDLH 2000 ppm; TWA 200 ppm(590 mg/m3); STEL 250 ppm(735 mg/m3)
CAS DataBase Reference: 676-58-4(CAS DataBase Reference)
EPA Substance Registry System: Magnesium, chloromethyl- (676-58-4)

More

Less

Safety

Hazard Codes: F,C
Risk Statements: 11-14/15-34-19-15-37-14
Safety Statements: 26-30-36/37/39-43-45-7/8-33-29-16
RIDADR: UN 3399 4.3/PG 2
WGK Germany: 1
F: 1-3-10
Autoignition Temperature: 609 °F
TSCA: Yes
HazardClass: 4.3
PackingGroup: I
HS Code: 29319090
Hazardous Substances Data: 676-58-4(Hazardous Substances Data)

More

Less

Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Danger

Hazard statements

H225Highly Flammable liquid and vapour

H260In contact with water releases flammable gases which may ignite spontaneously

H261In contact with water releases flammable gas

H302Harmful if swallowed

H314Causes severe skin burns and eye damage

H318Causes serious eye damage

H335May cause respiratory irritation

H351Suspected of causing cancer

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P231+P232Handle under inert gas. Protect from moisture.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P309IF exposed or if you feel unwell:

P310Immediately call a POISON CENTER or doctor/physician.

P370+P378In case of fire: Use … for extinction.

P402+P404Store in a dry place. Store in a closed container.

P403+P235Store in a well-ventilated place. Keep cool.

More

Less

N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 189901
Product name: Methylmagnesium chloride solution
Purity: 3.0 M in THF
Packaging: 8l
Price: $1390
Updated: 2024/03/01

Sigma-Aldrich

Product number: 189901
Product name: Methylmagnesium chloride solution
Purity: 3.0?M in THF
Packaging: 18L
Price: $2510
Updated: 2024/03/01

Alfa Aesar

Product number: 042101
Product name: Methylmagnesium chloride, 3M in THF, packaged under Argon in resealable ChemSeal? bottles
Packaging: 1mole
Price: $164
Updated: 2021/12/16

Alfa Aesar

Product number: 042101
Product name: Methylmagnesium chloride, 3M in THF, packaged under Argon in resealable ChemSeal? bottles
Packaging: 0.25mole
Price: $50.2
Updated: 2021/12/16

Strem Chemicals

Product number: 93-1266
Product name: Methylmagnesium chloride, 3M in THF
Packaging: 0.25mole
Price: $43
Updated: 2023/01/06

More

Less

Methylmagnesium chloride Chemical Properties,Usage,Production

Chemical Properties

dark brown solution

Uses

Methylmagnesium chloride is used as a Grignard reagent and an alkylating agent in organic synthesis.

Application

Methylmagnesium chloride solution (3 M in THF) undergoes 1,3-addition with dialdose derived nitrones to form N-benzylhydroxylamines. The reductive cleavage of the N-O bond of these N-benzylhydroxylamines results in N-benzylaminosugars, which are key moieties of bioactive compounds. It can also react with Garner type aldehydes to form the corresponding secondary alcohols.

Preparation

reaction of methyl chloride and magnesium in anhydrous diethyl ether, usually in the presence of an initiator.

Definition

ChEBI: Methylmagnesium chloride is an alkylmagnesium halide and a one-carbon compound. available as a solutionin tetrahydrofuran.

Reactions

Methylmagnesium chloride can react with acidic hydrogen on oxygen, sulfur and alkyne carbon of compounds containing active hydrogen (such as water, alcohol, mercaptan, amine, amide, acid, sulfonic acid, etc.); Propyl bromide, etc.) undergoes a coupling reaction; it can react with oxygen and carbon dioxide, aldehydes, ketones, etc.

Hazard

Flammable, dangerous fire and explosionrisk.

Methylmagnesium chloride Preparation Products And Raw materials

Raw materials

Preparation Products

More

Less

Methylmagnesium chloride Suppliers

Belgium 1 China 253 Europe 1 France 1 Germany 5 India 38 Japan 2 Slovakia 1 Switzerland 1 United Kingdom 5 United States 18 Global 326

Shaoxing Shangyu Hualun Chemical Co. Ltd.

Tel: 0575-82732398 13735223794
Email: xchl@hualun-chem.com
Country: China
ProdList: 6
Advantage: 58

Gansu Gefu Chemical Technology Co.,Ltd

Tel: 13951998329
Fax: 0571-56059825 (fandachem@gmail.com)
Email: sjg9988@126.com
Country: China
ProdList: 21
Advantage: 55

Shaoxing youli biology science and technology co., ltd

Tel: 0575-82148339 15967563458
Email: 704090688@qq.com
Country: China
ProdList: 28
Advantage: 58

Nanjing Freehoo Chemical Technology Co., Ltd.

Tel: 025-57798086 13951998329
Fax: 025-57798086
Email: sjg9988@126.com
Country: China
ProdList: 37
Advantage: 58

Nanjing Habo Medical Technology Co., Ltd.

Tel: 025-85760892 13376090521
Fax: 025-85766769
Email: sales@habotech.com
Country: China
ProdList: 973
Advantage: 60

Shanghai Weiji Environmental Protection Technology Co., LTD

Tel: 13817380975 13391095697
Email: info@wjscientific.cn
Country: China
ProdList: 17
Advantage: 58

J & K SCIENTIFIC LTD.

Tel: 010-82848833 400-666-7788
Fax: 86-10-82849933
Email: jkinfo@jkchemical.com
Country: China
ProdList: 96815
Advantage: 76

Meryer (Shanghai) Chemical Technology Co., Ltd.

Tel: 021-61259108 18621169109
Fax: 86-21-61259102
Email: market03@meryer.com
Country: China
ProdList: 40228
Advantage: 62

Alfa Aesar

Tel: 400-6106006
Fax: 021-67582001/03/05
Email: saleschina@alfa-asia.com
Country: China
ProdList: 30123
Advantage: 84

Beijing HwrkChemical Technology Co., Ltd

Tel: 010-89508211 18501085097
Fax: 010-89508210
Email: sales.bj@hwrkchemical.com
Country: China
ProdList: 8418
Advantage: 55

More

Less

View Lastest Price from Methylmagnesium chloride manufacturers

HEBEI SHENGSUAN CHEMICAL INDUSTRY CO.,LTD

Product: Methylmagnesium chloride 676-58-4
Price: US $110.00-70.00/kg
Min. Order: 1kg
Purity: 99%
Supply Ability: 5000
Release date: 2024-08-14

Hebei Weibang Biotechnology Co., Ltd

Product: Methylmagnesium chloride 676-58-4
Price: US $10.00-8.00/kg
Min. Order: 1kg
Purity: 99%
Supply Ability: 10 mt
Release date: 2024-12-04

Hebei Chuanghai Biotechnology Co,.LTD

Product: Methylmagnesium chloride 676-58-4
Price: US $5.00-2.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 10000kg
Release date: 2024-08-14

676-58-4, Methylmagnesium chloride Related Search:

Polyvinyl chloride 2-Methylbenzyl chloride Chlorodimethylphenylsilane Chloromethane TERT-BUTYLMAGNESIUM CHLORIDE Vinylmagnesium chloride Calcium chloride Magnesium chloride Ammonium chloride Choline chloride Pivaloyl chloride Acetyl chloride Magnesium chloride Magnesium chloride hexahydrate Potassium chloride Methylmagnesium Bromide Chloromethyl isopropyl carbonate PHENYLMAGNESIUM CHLORIDE

chloromethyl-magnesiu

METHYLMAGNESIUM CHLORIDE

METHYLMAGNESIUM CHLORIDE, 2.5M SOLUTIONIN BUTYL DIGLYME

METHYLMAGNESIUM CHLORIDE, 3.0M SOLUTION IN TETRAHYDROFURAN

METHYLMAGNESIUM CHLORIDE SOLUTION, ~3 M IN THF

METHYLMAGNESIUM CHLORIDE, 3.0M SOLUTION

Methylmagnesium chloride solution technical, ~3 M in THF

Methylmagnesium chloride, 22 wt% solution in tetrahydrofuran, AcroSeal

MethylMagnesiuM chloride, 3M (22 wt.%) solution in THF, AcroSeal

Methylmagnesium chloride solution, 3.0 M solution in THF, HySeal

METHYL MAGNESIUM CHLORIDE 22% in THF or 3M in THF

Methylmagnesium chloride 1M solution in 2-MeTHF

Methylmagnesium chloride 1M solution in Cyclopentyl methyl ether

Methylmagnesium chloride 1M solution in Di-n-butyl ether

Methylmagnesium chloride 3M solution in THF

MethylMagnesiuM chloride, 3.0 M solution in THF, J&KSeal

MethylMagnesiuM chloride, 3.0 M solution in THF, SpcSeal

Methylmagnesium chloride, 22 wt% solution in tetrahydrofuran

METHYLMAGNESIUM CHLORIDE IN TFE

Magnesium, chloromethyl-

methylmagnesium chloride solution

methylmagnesium chloride, 3m in thf, packaged under argon in resealable chemseal

Methylmagnesium Chloride 1.5 M In Butyl Diglyme

Methylmagnesium Chloride 1.5 M in n-Butyl Ether

Methylmagnesium Chloride 2.0 M In Diethyl Ether

Methylmagnesium Chloride 2.0 M In Tetrahydrofuran

Methylmagnesium Chloride 2.2 M In Butyl Diglyme

Methylmagnesium Chloride 3.0 M In Tetrahydrofuran

Methylmagnesiumchloride,3MinTHF

Methylmagnesium chloride, 3M in THF, packaged under Argon in resealable ChemSealTM bottles

Methylmagnesium chloride, 3M in THF, packaged under Argon in resealable ChemSeal bottles

Magnesium carbanide chloride

Methylmagnesium chloride22 wt% solution in tetrahydrofuranAcroSeal§3

Methyl(chloro) magnesium

Methylchloromagnesium

Methylmagnesium chloride, 3M in THF, packaged under Argon in resealable ChemSeal^t bottles

METHYLMAGNESIUM CHLORIDE, 3 M in TETRAHYDROFURAN

Methulmagnesium chloride solution

Methylmagnesium chloride [3.0 M sulution in THF]

Methylmagnesium chloride solution 3.0 M in THF

M**METHYLMAGNESIUM CHLORIDE 3.0M SOLUTION THF

CH3MgClinTHF

Methylmagnesium chloride 3.0 M

Methylmagnesium chloride solution( 3.0 M solution in THF)

Methylmagnesium chloride, 2.5 M solution in THF, J&amp

Methylmagnesium chloride(3M THF)

Methylmagnesium chloride 3.0 M solution in THF

Methyl Magnesium Chloride (3.0 M in THF)

Methylmagnesium Chloride 3.0M In THF / 3.2M In 2METHF

METHYLMAGNESIUM CHLORIDE 3.0M THF/3.2M 2MeTHF

METHYL MAGNESIUM CHLORIDE 3 MOLAR IN THF

Methyl Magnesium Chloride 3 Molar Solution in Tetrahydrofuran

Methyl magnesium chloride solution (3 M THF)

Methyl Magnesium Chloride (1.0 M in THF)

676-58-4

676-85-4

CH3ClMg

CH3MgCl