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Aromatic hydrocarbons

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Aromatic hydrocarbon refers to the closed-chain hydrocarbon containing a benzene ring or having the basic characteristics of the aromatic compound. It can be divided into mono-cyclic aromatic hydrocarbon, polycyclic aromatic hydrocarbon and non-benzene aromatic hydrocarbons. For monocyclic aromatic hydrocarbon, its molecule contains only one benzene ring, such as toluene, xylene, ethylbenzene, styrene, benzene and acetylene.

Polycyclic aromatic hydrocarbon contains two or more benzene rings. According to the interconnected ways of benzene ring, it can be divided into:
1 polybenzo-aliphatic hydrocarbons including diphenylmethane, triphenylmethane, stilbene, styrene and so on;
2 Biphenyl and polybenzene, such as biphenyl, terphenyl and tetraphenyl, etc;
3 polycyclic aromatic hydrocarbons such as naphthalene, anthracene, phenanthrene, indene, fluorene, acenaphthene, pyrene, coronene and so on;

Non-aromatic hydrocarbon is the hydrocarbon containing certain aromatic property but containing no benzene ring such as azulene and annulene. It is easy to have substitution reaction while being not easy to have addition reaction with the ring being not easy to be broken.
The natural existing aromatic hydrocarbon is mainly is mainly obtained through from the distillate of coal tar and the aromatization product of oil. The main component of coal tar is aromatic hydrocarbon; the main component of various kinds of crude oil of petroleum is aliphatic hydrocarbons with aromatic hydrocarbons only accounting for only 0.2% to 7.4%, but the acute and chronic toxicity of oil is mainly aromatic hydrocarbons, in particular caused by the soluble aromatic hydrocarbons such as naphthalene, phenanthrene contained in it. It can be used as solvent and chemical raw materials.

Benzene is the basic structure of aromatic hydrocarbon, usually using the structure formula of six-membered ring containing three conjugated double bonds, which was proposed at 1865 by the German chemist F.A. Kekule, being called as Kekule formula. From the composition point of view, benzene is an unsaturated hydrocarbon, but it is not easy to be subject to oxidation and addition reaction while being easy to participate in substitution reaction, and there is also special toughness (see "aromatic"). According to the hybrid orbital theory, each carbon atoms contained in the benzene molecule is sp2 hybridized with each of them having two sp2 hybrid orbitals overlapped with the sp2 hybrid orbitals from two adjacent carbon atoms, forming a C-Cσ bond (see Fig. 1), and with a sp2 hybrid orbital overlapping with the 1s orbital of the hydrogen atom, forming a C-Hσ bond.

The simplest aromatic hydrocarbon is benzene. People originally discovered benzene and other aromatic compounds from coal tar, and thereby, coal tar, for quite a long time, had been the major source of aromatics. But the yield from coal tar is only 3% of that of the coal; moreover, the content of various kinds of aromatic compound contained in coal tar is only about 0.3% of that of the coal. Therefore, people have mainly manufactured aromatics from petroleum processing system since the 1940s. Aromatics are all liquid or solid. It is insoluble in water but soluble in organic solvents. It has aromaticity and is not easy to participate in the addition reaction, but is easily subject to substitution reaction, and is relatively stable to heat and oxidant. Aromatic hydrocarbons (especially single-ring aromatic hydrocarbon) are important chemical raw materials (for example, xylene is the raw material for the manufacturing of polyester), many kinds of liquid aromatic hydrocarbon can be used as solvents (for example, paint is easily soluble in aromatic hydrocarbons). However, when the liquid aromatic hydrocarbon has been in contact with the skin for several times, due to dehydration and degreasing, can cause dermatitis. The steam of the aromatic hydrocarbons has a stronger stimulation effect on the mucosa than the aliphatic hydrocarbon. In particular, benzene vapor has a special destroying effect on the hematopoietic function. However, animal tests have shown that alkylbenzene has no such damaging effects.

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Structure:
Chemical Name:
Iodosobenzene
CAS:
536-80-1
MF:
C6H5IO
Structure:
Chemical Name:
5,10,15,20-TETRAKIS(4-FLUOROPHENYL)-21H,23H-PORPHINE)
CAS:
37095-43-5
MF:
C44H26F4N4
Structure:
Chemical Name:
2-(Dicyclohexylphosphino)-3,6-dimethoxy-2'-4'-6'-tri-i-propyl-1,1'-biphenyl, min. 98% BrettPhos
CAS:
1070663-78-3
MF:
C35H53O2P
Structure:
Chemical Name:
1,3-Diiodotetrafluorobenzene
CAS:
67815-57-0
MF:
C6F4I2
Structure:
Chemical Name:
1,4-DIIODO-2-FLUOROBENZENE
CAS:
147808-02-4
MF:
C6H3FI2
Structure:
Chemical Name:
METHANONE, 1,1'-(1,4-PHENYLENE)BIS[1-(4-FLUOROPHENYL)-]
CAS:
68418-51-9
MF:
C20H12F2O2
Structure:
Chemical Name:
5-broMo-3-fluorobenzene-1,2-diol
CAS:
876861-29-9
MF:
C6H4BrFO2
Structure:
Chemical Name:
5,6-difluorobenzo[c][1,2,5]thiadiazole
CAS:
1293389-28-2
MF:
C6H2F2N2S
Structure:
Chemical Name:
Ethanesulfonamide,N-[5,6,7,8-tetrahydro-5-(1H-imidazol-4-yl)-1-naphthalenyl]-
CAS:
258526-42-0
MF:
C15H19N3O2S
Chemical Name:
methyl 4-(2-bromo-1-(trifluoromethoxy)ethyl)benzoate
Structure:
Chemical Name:
4-[(2-fluorophenyl)amino]benzonitrile
CAS:
1019502-17-0
MF:
C13H9FN2
Structure:
Chemical Name:
2-Fluoro-4-[(trans,trans)-4'-propyl[1,1'-bicyclohexyl]-4-yl]benzonitrile
CAS:
93743-04-5
MF:
C22H30FN
Structure:
Chemical Name:
methyl 3-formyl-2,6-dihydroxy-4-methoxy-5-methylbenzoate
CAS:
118093-03-1
MF:
C11H12O6
Structure:
Chemical Name:
4-(4-FLUORO-PHENYL)-PIPERIDINE
CAS:
37656-48-7
MF:
C11H14FN
Structure:
Chemical Name:
2-(3-Chloropropyl)-2-(4-fluorophenyl)-1,3-dioxolane
CAS:
3308-94-9
MF:
C12H14ClFO2
Structure:
Chemical Name:
4-[4-[(1-Oxo-2-propenyl)oxy]butoxy]benzoic acid [1,1'-biphenyl]-4-yl ester
CAS:
245760-39-8
MF:
C26H24O5
Structure:
Chemical Name:
2,4-dibromo-1,3,5-trifluorobenzene
CAS:
363-69-9
MF:
C6HBr2F3
Structure:
Chemical Name:
3-ethyl-4-fluorobenzonitrile
CAS:
869299-63-8
MF:
C9H8FN
Structure:
Chemical Name:
1,3-Bis(2,6-dibenzhydryl-4-methylphenyl)-1H-imidazol-3-ium chloride
CAS:
1218778-19-8
MF:
C69H57ClN2
Structure:
Chemical Name:
2,5-Difluoro-1,4-benzenedicarbonitrile
CAS:
1897-49-0
MF:
C8H2F2N2
Structure:
Chemical Name:
4'-[2-(3,4-Difluoro-phenyl)-ethyl]-4-propyl-bicyclohexyl
CAS:
107215-66-7
MF:
C23H34F2
Structure:
Chemical Name:
5,6-difluoro-4,7-diiodobenzo[c][1,2,5]thiadiazole
CAS:
1293389-29-3
MF:
C6F2I2N2S
Structure:
Chemical Name:
2,4-Dichloro-6-fluorobenzonitrile
CAS:
1349718-98-4
MF:
C7H2Cl2FN
Structure:
Chemical Name:
AC-262536
CAS:
870888-46-3
MF:
C18H18N2O
Structure:
Chemical Name:
methyl 2,6-dihydroxy-4-methoxy-3-methylbenzoate
CAS:
39828-28-9
MF:
C10H12O5
Structure:
Chemical Name:
methyl 4-ethynyl-2-hydroxybenzoate
CAS:
216443-97-9
MF:
C10H8O3
Structure:
Chemical Name:
1,2-DIBROMO-4-FLUOROBENZENE
CAS:
2369-37-1
MF:
C6H3Br2F
Structure:
Chemical Name:
Phosphonic dichloride, (4-fluorophenyl)-
CAS:
657-81-8
MF:
C6H4Cl2FOP
Structure:
Chemical Name:
HEPTAFLUORO-2-NAPHTHOL
CAS:
727-49-1
MF:
C10HF7O
Structure:
Chemical Name:
4,5-Diethoxy-1,2-benzoquinone
CAS:
21086-66-8
MF:
C10H12O4
Structure:
Chemical Name:
2-(4-broMo-2,6-difluorophenyl)acetonitrile
CAS:
537033-52-6
MF:
C8H4BrF2N
Structure:
Chemical Name:
BIS(2-(METHOXYCARBONYL)PHENYL) CARBONATE
CAS:
82091-12-1
MF:
C17H14O7
Structure:
Chemical Name:
N4,N4-di([1,1'-biphenyl]-4-yl)-N4'-(naphthalen-1-yl)-N4'-phenyl-[1,1'-biphenyl]-4,4'-diamine
MF:
C52H38N2
Structure:
Chemical Name:
2,6-DIHYDROXYANTHRAQUINONE
CAS:
572-93-0
MF:
C14H8O4
Structure:
Chemical Name:
1,1,4,4-Tetramethyl-1,2,3,4-tetrahydronaphthalene
CAS:
6683-46-1
MF:
C14H20
Structure:
Chemical Name:
2-FLUOROBENZAL CHLORIDE
CAS:
320-65-0
MF:
C7H5Cl2F
Structure:
Chemical Name:
6-BROMO-1,1,4,4,7-PENTAMETHYL-1,2,3,4-TETRAHYDRONAPHTHALENE
CAS:
119999-22-3
MF:
C15H21Br
Structure:
Chemical Name:
2,6-DICHLORO-1,4-BENZOQUINONE
CAS:
697-91-6
MF:
C6H2Cl2O2
Structure:
Chemical Name:
IN1606, 4,7-Bis(5-bromo-4-dodecylthiophen-2-yl)-5,6-difluorobenzo[c][1,2,5]thiadiazole
CAS:
1373834-88-8
MF:
C38H52Br2F2N2S3
Structure:
Chemical Name:
3,4-dihydro-3,4-dioxonaphthalene-1-sulphonic acid
CAS:
2066-93-5
MF:
C10H6O5S
Structure:
Chemical Name:
3-hydroxy-4-[(2-hydroxynaphthyl)azo]naphthalene-1-sulphonic acid
CAS:
2538-79-6
MF:
C20H14N2O5S
Structure:
Chemical Name:
sodium 1-hydroxynaphthalene-2-sulphonate
CAS:
832-50-8
MF:
C10H7NaO4S
Structure:
Chemical Name:
2,3,4,5,6-PENTAFLUOROPHENYLACETONITRILE
CAS:
653-30-5
MF:
C8H2F5N
Structure:
Chemical Name:
4,4,5,5-tetramethyl-2-[4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)naphthalen-1-yl]
CAS:
929103-36-6
MF:
C22H30B2O4
Structure:
Chemical Name:
p-Isobutylstyrene
CAS:
63444-56-4
MF:
C12H16
Structure:
Chemical Name:
6-(3,6-dichloropyridazine-4-carboxamido)-4-hydroxy-3-[(p-sulphophenyl)azo]naphthalene-2-sulphonic acid
CAS:
6694-64-0
MF:
C21H13Cl2N5O8S2
Structure:
Chemical Name:
1,1'-[(6-phenoxy-1,3,5-triazine-2,4-diyl)diimino]bisanthraquinone
CAS:
1965-81-7
MF:
C37H21N5O5
Structure:
Chemical Name:
1-[[(2-hydroxyphenyl)imino]methyl]-2-naphthol
CAS:
894-93-9
MF:
C17H13NO2
Structure:
Chemical Name:
trisodium 8-aminonaphthalene-1,3,6-trisulphonate
CAS:
901-79-1
MF:
C10H6NNa3O9S3
Structure:
Chemical Name:
sodium 4-[[4-[(2,4-diaminophenyl)azo]naphthyl]azo]naphthalene-1-sulphonate
CAS:
10115-25-0
MF:
C26H21N6NaO3S
Structure:
Chemical Name:
1-BROMO-2-CHLORO-4,5-DIFLUOROBENZENE
CAS:
59447-06-2
MF:
C6H2BrClF2
Structure:
Chemical Name:
9,10-Anthracenedione, 1,4,4a,9a-tetrahydro-5-nitro-
CAS:
56281-39-1
MF:
C14H11NO4
Structure:
Chemical Name:
colutehydroquinone
CAS:
181311-16-0
MF:
C18H20O6
Structure:
Chemical Name:
DELTA7-AVENASTEROL
CAS:
23290-26-8
MF:
C29H48O
Structure:
Chemical Name:
Methyl 3-(aminomethyl)-5-bromobenzoate HCl
CAS:
1393540-29-8
MF:
C9H10BrNO2
Structure:
Chemical Name:
4-FLUOROBENZENESULFONYL FLUORIDE
CAS:
368-85-4
MF:
C6H4F2O2S
Structure:
Chemical Name:
(-)-Corey aldehyde benzoate
CAS:
39746-01-5
MF:
C15H14O5
Structure:
Chemical Name:
2-BROMO-5-FLUOROPHENYLACETONITRILE
CAS:
886761-96-2
MF:
C8H5BrFN
Structure:
Chemical Name:
BIS(PENTAFLUOROPHENYL)ZINC 97
CAS:
1799-90-2
MF:
C12F10Zn
Structure:
Chemical Name:
4-BROMO-3-FLUOROPHENYLZINC IODIDE 0.5M&
CAS:
352525-65-6
MF:
C6H3BrFIZn
Structure:
Chemical Name:
N-(2-(((1s,3R,5S)-3,5-dimethylcyclohexyl)oxy)-6-((S)-4-isopropyl-4,5-dihydrooxazol-2-yl)phenyl)naphthalene-2-sulfonamide
CAS:
1192815-32-9
MF:
C30H36N2O4S
Structure:
Chemical Name:
1,1,2,2,3,3,4,4,4A,5,5,6,6,7,7,8,8A-HEPTADECAFLUORODECAHYDRO-8-(TRIFLUOROMETHYL)-NAPHTHALENE
CAS:
89591-63-9
MF:
C11F20
Structure:
Chemical Name:
2-(2-hydroperoxypropan-2-yl)-6-propan-2-ylnaphthalene
CAS:
105443-43-4
MF:
C16H20O2
Structure:
Chemical Name:
4-FLUOROBENZAMIDOXIME
CAS:
22179-78-8
MF:
C7H7FN2O
Structure:
Chemical Name:
FLUOROBENZENE-D5
CAS:
1423-10-5
MF:
C6D5F
Structure:
Chemical Name:
1,3,4-Oxadiazole, 2-[4-(bromomethyl)-3-fluorophenyl]-5-(difluoromethyl)-
CAS:
2071227-85-3
MF:
C10H6BrF3N2O
Structure:
Chemical Name:
Benzoic acid, 4-bromo-2-(bromomethyl)-6-fluoro-, methyl ester
CAS:
1935921-64-4
MF:
C9H7Br2FO2
Structure:
Chemical Name:
1-(2,3-Dimethylphenyl)ethyl chloride
CAS:
60907-88-2
MF:
C10H13Cl
Structure:
Chemical Name:
2,7-Naphthalenedisulfonic acid, 4-hydroxy-5-[[4-[[5-hydroxy-6-[(4-methoxy-2-sulfophenyl)azo]-7-sulfo-2-naphthalenyl]amino]-6-(4-morpholinyl)-1,3,5-triazin-2-yl]amino]-3-[(2-sulfophenyl)azo]-, pentasodium salt
CAS:
2184-15-8
MF:
C40H29N10Na5O19S5
Structure:
Chemical Name:
2,5-di(2-naphthyl)-1,3,4-oxadiazole
CAS:
802-51-7
MF:
C22H14N2O
Structure:
Chemical Name:
1,5-bis[[4-(dimethylamino)phenyl]amino]anthraquinone
CAS:
3008-76-2
MF:
C30H28N4O2
Chemical Name:
poly[(9,9-bis(3′-(N,N-dimethylamino)propyl)-2,7-f l uorene)-alt-5,5′-bis(2,2′-thiophene)-2,6-naphthalene-1,4,5,8-tetracaboxylic-N,N′-di(2-ethylhexyl)imide]
Structure:
Chemical Name:
sodium 2-naphtholate
CAS:
875-83-2
MF:
C10H7NaO
Structure:
Chemical Name:
4-Amino-3-bromo-5-fluorobenzonitrile
CAS:
874880-58-7
MF:
C7H4BrFN2
Structure:
Chemical Name:
3,4-Dichloro-5-fluorobromobenzene
CAS:
1000572-93-9
MF:
C6H2BrCl2F
Structure:
Chemical Name:
1,4-DIBROMO-2,3-DIFLUOROBENZENE
CAS:
156682-52-9
MF:
C6H2Br2F2
Structure:
Chemical Name:
toddacoumaquinone
CAS:
142878-03-3
MF:
C23H18O7
Structure:
Chemical Name:
2-benzoquinone
CAS:
583-63-1
MF:
C6H4O2
Chemical Name:
Sodium Naphthalene Formaldehyde
Structure:
Chemical Name:
SHB
CAS:
70074-31-6
MF:
C11H9NO5
Structure:
Chemical Name:
1-((DIMETHYLAMINO)(PHENYL)METHYL)NAPHTHALEN-2-OL
CAS:
39487-54-2
MF:
C19H19NO
Structure:
Chemical Name:
4P-NPB , N,N'-di-(1-naphthalenyl)-N,N'-diphenyl-[1,1':4',1'':4
CAS:
948552-24-7
MF:
C56H40N2
Structure:
Chemical Name:
4-broMo-3,5-difluorobenzonitrile
CAS:
123688-59-5
MF:
C7H2BrF2N
Structure:
Chemical Name:
5-Bromo-2-chloro-4-fluorobenzyl cyanide
CAS:
1426290-08-5
MF:
C8H4BrClFN
Structure:
Chemical Name:
METHANONE, 1,1'-(1,4-PHENYLENE)BIS[1-(4-FLUOROPHENYL)-]
MF:
C20H12F2O2
Structure:
Chemical Name:
Methylenedihydrotanshinquinone
CAS:
126979-81-5
MF:
C18H16O3
Structure:
Chemical Name:
1,3-BIS(4-FLUOROBENZOYL)BENZENE
CAS:
108464-88-6
MF:
C20H12F2O2
Structure:
Chemical Name:
4-(BROMOMETHYL)-2-FLUOROBENZONITRILE
CAS:
222978-03-2
MF:
C8H5BrFN
Structure:
Chemical Name:
2-(CHLOROMETHYL)ANTHRAQUINONE
CAS:
6374-87-4
MF:
C15H9ClO2
Structure:
Chemical Name:
1-BROMO-2-CHLORO-3,4,5-TRIFLUOROBENZENE
CAS:
122375-83-1
MF:
C6HBrClF3
Structure:
Chemical Name:
N-(naphthalen-1-yl)picolinamide
CAS:
75358-95-1
MF:
C16H12N2O
Structure:
Chemical Name:
2,3-Naphthalenedicarbonitrile, 6-(butylthio)-
CAS:
129204-90-6
MF:
C16H14N2S
Structure:
Chemical Name:
1,3-DICHLORO-2,5-DIFLUOROBENZENE
CAS:
2367-80-8
MF:
C6H2Cl2F2
Structure:
Chemical Name:
2-BROMO-5-METHYL-1,4-BENZOQUINONE
CAS:
13070-25-2
MF:
C7H5BrO2
Structure:
Chemical Name:
2,5-DICHLOROFLUOROBENZENE
CAS:
348-59-4
MF:
C6H3Cl2F
Structure:
Chemical Name:
1,1'-(bromomethylene)bis(4-fluorobenzene)
CAS:
345-90-4
MF:
C13H9BrF2
Structure:
Chemical Name:
1,8-dimethoxyanthraquinone
CAS:
6407-55-2
MF:
C16H12O4
Structure:
Chemical Name:
6-amino-5-hydroxynaphthalene-1-sulphonic acid
CAS:
573-07-9
MF:
C10H9NO4S
Structure:
Chemical Name:
1,1'-(bromomethylene)bis[2,3,4,5,6-pentafluorobenzene]
CAS:
5736-49-2
MF:
C13HBrF10
Chemical Name:
((2R,3R,5R)-5-(2,4-dioxo-3,4-dihydropyrimidin-1(2H)-yl)-4,4-difluoro-3-hydroxytetrahydrofuran-2-yl)methyl benzoate