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ChemicalBook >  Product Catalog >  Organic Chemistry >  Hydrocarbons and derivatives >  Aromatic hydrocarbons >  2-(Dicyclohexylphosphino)-3,6-dimethoxy-2'-4'-6'-tri-i-propyl-1,1'-biphenyl, min. 98% BrettPhos

2-(Dicyclohexylphosphino)-3,6-dimethoxy-2'-4'-6'-tri-i-propyl-1,1'-biphenyl, min. 98% BrettPhos

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2-(Dicyclohexylphosphino)-3,6-dimethoxy-2'-4'-6'-tri-i-propyl-1,1'-biphenyl, min. 98% BrettPhos Basic information

Product Name:
2-(Dicyclohexylphosphino)-3,6-dimethoxy-2'-4'-6'-tri-i-propyl-1,1'-biphenyl, min. 98% BrettPhos
Synonyms:
  • 2-(Dicyclohexylphosphino)-3,6-diMethoxy-2'-4' -6'-tri-i-propyl-1,1'-biphenyl
  • 2-Dicyclohexylphosphino-2',4',6'-triisopropyl-3,6-diMethoxybiphenyl, 97+%
  • 2-Dicyclohexylphosphino-2',4',6'-tri-i-propyl-3,6-diMethoxy-1,1'-biphenyl, 98% (BrettPhos)
  • BrettPhos 96%
  • 2-(Dicyclohexylphosphino)-3,6-dimethoxy-2'-4'-6'-tri-i-propyl-1,1'-biphenyl, min. 98% BrettPhos
  • 2-(Dicyclohexylphosphino)3,6-dimethoxy-2′,4′,6′-triisopropyl-1,1′-biphenyl
  • BRETTPHOS
  • Dicyclohexyl(2',4',6'-triisopropyl-3,6-diMethoxy-[1,1'-biphenyl]-2-yl)phosphine
CAS:
1070663-78-3
MF:
C35H53O2P
MW:
536.77
Product Categories:
  • Achiral Phosphine
  • Aryl Phosphine
  • Buchwald Ligands Series
  • Buchwald Ligands&Precatalysts
Mol File:
1070663-78-3.mol
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2-(Dicyclohexylphosphino)-3,6-dimethoxy-2'-4'-6'-tri-i-propyl-1,1'-biphenyl, min. 98% BrettPhos Chemical Properties

Melting point:
191-193℃
Boiling point:
607.7±55.0 °C(Predicted)
storage temp. 
Refrigerator, under inert atmosphere
solubility 
Chloroform (Slightly), Methanol (Slightly, Sonicated)
form 
crystal
color 
white
InChI
InChI=1S/C35H53O2P/c1-23(2)26-21-29(24(3)4)33(30(22-26)25(5)6)34-31(36-7)19-20-32(37-8)35(34)38(27-15-11-9-12-16-27)28-17-13-10-14-18-28/h19-25,27-28H,9-18H2,1-8H3
InChIKey
WDVGNXKCFBOKDF-UHFFFAOYSA-N
SMILES
P(C1CCCCC1)(C1CCCCC1)C1=C(OC)C=CC(OC)=C1C1=C(C(C)C)C=C(C(C)C)C=C1C(C)C
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Safety Information

Risk Statements 
36/37/38
Safety Statements 
26-37-60
WGK Germany 
nwg
TSCA 
No
HS Code 
2931499090
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2-(Dicyclohexylphosphino)-3,6-dimethoxy-2'-4'-6'-tri-i-propyl-1,1'-biphenyl, min. 98% BrettPhos Usage And Synthesis

Reactions

  1. Ligand for palladium-catalyzed cross-coupling reactions using aryl mesylates with electron-deficient anilines.
  2. Ligand for palladium-catalyzed cross-coupling of primary arylamines at low catalyst loading.
  3. Ligand for palladium-catalyzed cross-coupling of aryl iodides and primary amines.
  4. Ligand for the Suziki-Miyaura coupling of tosylates and mesylates.
  5. Ligand for the palladium-catalyzed trifluoromethylation of aryl chlorides.
  6. Ligand for the palladium-catalyzed formation of aryl-SCF3 compounds from aryl bromides.
  7. Ligand for the nickel-catalyzed cross-coupling of styrenyl epoxides with boronic acids.
  8. Ligand for the palladium-catalyzed intramolecular CH difluoroalkylation.

Uses

Ligand for the Suziki-Miyaura coupling of tosylates and mesylates.

Uses

Buchwald Phosphine Ligands for chemical Synthesis

reaction suitability

reagent type: catalyst
reaction type: Cross Couplings

2-(Dicyclohexylphosphino)-3,6-dimethoxy-2'-4'-6'-tri-i-propyl-1,1'-biphenyl, min. 98% BrettPhosSupplier

Xinxiang Runyu Material Co., Ltd. Gold
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166-166-37336996 15690792173
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chenxi.song@runvmat.com
Sinocompound Catalysts Co., Ltd. Gold
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0512-67216630 67216634
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Zhengzhou HQ Material Co., Ltd. Gold
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0371-67759225 13526468238
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Aikon International Limited Gold
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025-66028182 18112977050
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Zhengzhou Kingorgchem Chemical Technology Co., Ltd.gy Co., Ltd. Gold
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0371-65511006 18625597674
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sales@kingorgchem.com
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2-(Dicyclohexylphosphino)-3,6-dimethoxy-2'-4'-6'-tri-i-propyl-1,1'-biphenyl, min. 98% BrettPhos(1070663-78-3)Related Product Information