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Polysaccharide

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Polysaccharides are the sugars that can be hydrolyzed into many monosaccharide sugar molecules or its derivative, which are macromolecular compounds formed by the condensation and dehydration of 20 to tens of thousands of monosaccharide molecules. Some polysaccharides may be made by the condensation of one monosaccharide, such as starch, cellulose, which are called homopolysaccharide; Others may be formed by the condensation of different monosaccharides or derivatives thereof, such as hemicellulose, which are called hetero polysaccharides. The plants, animals and microorganisms in nature all contain polysaccharides. In addition to the free state, polysaccharide can also exist in the form combined with the protein. The common characters of plant polysaccharide include natural, health value and unique characteristics of the water-soluble colloids, which make the food have higher nutritional value, stable and palatable organizational structure, exquisite appearance, distinctive taste and extended shelf life. Natural plant polysaccharides are more secure, easily-absorbed, highly-utilized for human body. Water-soluble plant polysaccharides have excellent health value, such as konjac glucomannan that have the highest hydrated viscosity of soluble dietary fiber and have the healthy functions of full belly, reducing blood fat, lowering blood sugar and constipation. Plant polysaccharides do not provide calories, but have the balanced nutrition role for high-calorie, high-fat and high-protein diet. For hydrophilic plant polysaccharides, people used to call them the plant gum. Their hydrophilic colloid characteristics make the food production appear thickener, a gel (excipients), film formers, emulsifiers and other food stabilizers. The effective development and utilization of plant polysaccharides will help to improve the quality of human life and the level of human health, and enrich human food resources to create more economic value to the world food industry.

Starch is the polysaccharide stored in plants, and it is composed of two components, namely amylose and amylopectin. In the starch granules, amylose often only make up 20 to 28%, and the rest is amylopectin.250-300 D-glucose molecules link to a linear and then curl into a spiral via α-1,4-glycosidic bond to form the amylose, in which  there is a non-reducing end and a reducing end. The molecular weight of amylose exist big difference, even from thousands to 150,000. Amylose can reacts with iodine to appear blue because the amylose is suspended in water, and its internal helical crimp of molecular is occupied by iodine (I2) .

Amylopectin structure is composed of 24-30 D-glucose molecules, which form short-chains viaα-1,4 glycosidic bond and then link short-chains into to bushes-like  structure via α-1,6- glycosidic bond. The α-amylase in digestive tract of animals ,which present in saliva and pancreatic juice, can optionally be applied to work on α-1,4 glycosidic bond to hydrolyze linear amylose and form maltose and glucose. The β- amylase in plants can act on the non-reducing end of amylose to form maltose. Amylopectin can also be acted by α and β-amylase, but the α-1,4 glycosidic bond and α-1,6 glycosidic bond close to the branching point can’t be hydrolyzed by these enzymes. In the combined effect of amylase and α-1,6glucosidase, pullulan can be completely hydrolyzed to glucose and maltose.

Agarose is an important component of agar, which formed by the repeating condensation of D-galactose and 3,6 -anhydrogalactose. Agarose can dissolve in boiling water in large numbers, but when the temperature drop to below 40 ℃, agarose changes into insoluble gel. This agarose gel is commonly used as a support for the chromatography, but it is unstable in acid environment due to the cross-linked galactosidase is formed via hydrogen bonds but not the coordinate bonds.

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Structure:
Chemical Name:
Chitosan
CAS:
9012-76-4
MF:
C6H11NO4X2
Structure:
Chemical Name:
beta-(1,3)-D-Glucan
CAS:
9012-72-0
MF:
C18H30O14X2
Chemical Name:
Pectin
CAS:
9000-69-5
MF:
C6H12O6
Structure:
Chemical Name:
2-Hydroxypropyl-β-cyclodextrin
CAS:
128446-35-5
MF:
C63H112O42
Structure:
Chemical Name:
INULIN
CAS:
9005-80-5
MF:
C18H32O16
Structure:
Chemical Name:
Agar
CAS:
9002-18-0
MF:
C14H24O9
Structure:
Chemical Name:
Chitin
CAS:
1398-61-4
MF:
C6H11NO4X2
Structure:
Chemical Name:
Hydroxypropyl cellulose
CAS:
9004-64-2
MF:
C3H7O*
Structure:
Chemical Name:
Xanthan gum
CAS:
11138-66-2
MF:
C8H14Cl2N2O2
Structure:
Chemical Name:
Microcrystalline cellulose
CAS:
9004-34-6
MF:
(C12H20O10)n
Structure:
Chemical Name:
Sodium carboxymethyl cellulose
CAS:
9004-32-4
MF:
C6H7O2(OH)2CH2COONa
Structure:
Chemical Name:
XYLAN
CAS:
9014-63-5
MF:
C5H10O5
Structure:
Chemical Name:
Ethyl cellulose
CAS:
9004-57-3
MF:
C23H24N6O4
Chemical Name:
CARBOXYMETHYL BETA-CYCLODEXTRIN
Structure:
Chemical Name:
β-Cyclodextrin
CAS:
7585-39-9
MF:
C42H70O35
Chemical Name:
Starch
CAS:
9005-25-8
MF:
(C6H10O5)n
Structure:
Chemical Name:
AMYLOPECTIN
CAS:
9037-22-3
MF:
C30H52O26
Structure:
Chemical Name:
AMYLOSE
CAS:
9005-82-7
MF:
C18H30O16X2
Chemical Name:
HEPARIN LITHIUM SALT
CAS:
9045-22-1
MF:
n.a.
Structure:
Chemical Name:
Maltodextrin
CAS:
9050-36-6
MF:
C12H22O11
Chemical Name:
SEPHADEX(R) G-200 SUPERFINE, FOR CHROMAT OGRAPHY
Chemical Name:
LIPOPOLYSACCHARIDE FROM ESCHERICHIA COLI
Structure:
Chemical Name:
LIPOPHILIC SEPHADEX
CAS:
9041-37-6
MF:
C9H8N2O3S
Chemical Name:
SEPHADEX G-15
CAS:
11081-40-6
MF:
NULL
Structure:
Chemical Name:
CELLULOSE TRIACETATE
CAS:
9012-09-3
MF:
C40H54O27
Chemical Name:
AGAROSE
CAS:
9012-36-6
MF:
C10H15N3O3
Chemical Name:
Starch soluble
CAS:
9005-84-9
MF:
(C6H10O5)n
Chemical Name:
Methyl 2-hydroxyethyl cellulose
CAS:
9032-42-2
MF:
C2H6O2·xCH4O·x
Structure:
Chemical Name:
Carboxymethyl cellulose
CAS:
9000-11-7
MF:
C6H12O6
Structure:
Chemical Name:
Dextrin
CAS:
9004-53-9
MF:
C18H32O16
Chemical Name:
GLYCOPROTEIN, ALPHA1-ACID HUMAN
CAS:
66455-27-4
MF:
NULL
Structure:
Chemical Name:
CITRATE SYNTHASE
CAS:
9027-96-7
MF:
C6H5O7-3
Structure:
Chemical Name:
GLYCOGEN
CAS:
9005-79-2
MF:
(C6H10O5)n
Chemical Name:
CELLULOSE ACETATE BUTYRATE
CAS:
9004-36-8
MF:
N/A
Chemical Name:
CAROB GALACTOMANNAN
CAS:
11078-30-1
Structure:
Chemical Name:
κ-Carrageenan
CAS:
11114-20-8
MF:
C24H36O25S2-2
Chemical Name:
Sulglycotide
CAS:
54182-59-1
Chemical Name:
DEAE-cellulose
CAS:
9013-34-7
MF:
C20H23NO5
Chemical Name:
Cellulose acetate
CAS:
9004-35-7
MF:
[C6H7O2(OH)3-m(OOCCH3)m],m=0~3
Chemical Name:
AGAROSE
CAS:
39346-81-1
MF:
C24H38O19
Chemical Name:
SEPHADEX G-75
CAS:
37224-29-6
MF:
NULL
Structure:
Chemical Name:
IRISH MOSS
CAS:
9062-07-1
MF:
C24H34O31S4-4
Chemical Name:
Pullulan
Chemical Name:
CARBOXYMETHYL SEPHADEX
CAS:
62886-59-3
Structure:
Chemical Name:
CYANOETHYL CELLULOSE
CAS:
9004-41-5
MF:
C6H8N2O
Chemical Name:
CARRAGEENAN
CAS:
9000-07-1
MF:
NULL
Structure:
Chemical Name:
Pullulan
CAS:
9057-02-7
MF:
C20H36O16
Chemical Name:
SP SEPHADEX
CAS:
61840-62-8
MF:
N/A
Chemical Name:
CARBOXYMETHYL SEPHADEX
CAS:
9047-08-9
Chemical Name:
CELLULOSE ACETATE PROPIONATE
CAS:
9004-39-1
MF:
C76H114O49
Structure:
Chemical Name:
Hydroxypropyl methylcellulose phthalate
CAS:
9050-31-1
MF:
C14H16N4
Chemical Name:
Dextran Sulfate Sodium Salt
CAS:
9011-18-1
MF:
(C6H7Na3O14S3)n
Structure:
Chemical Name:
6-IODONORDIHYDROCAPSAICIN
CAS:
859171-97-4
MF:
C17H26INO3
Structure:
Chemical Name:
GAMMA-CYCLODEXTRIN HYDRATE
CAS:
91464-90-3
MF:
C48H82O41
Chemical Name:
SEPHADEX G-100
CAS:
9050-94-6
MF:
NULL
Structure:
Chemical Name:
DEXTRIN PALMITATE
CAS:
83271-10-7
MF:
C34H64O18