Hexamethylene diacrylate Chemical Properties

Melting point:

6°C

Boiling point:

295°C

Density 

1.01 g/mL at 25 °C (lit.)

vapor density 

>1 (vs air)

vapor pressure 

<0.01 mm Hg ( 20 °C)

refractive index 

n20/D 1.456(lit.)

Flash point:

>230 °F

storage temp. 

under inert gas (nitrogen or Argon) at 2–8 °C

solubility 

Chlroform (Slightly), DMSO (Slightly)

form 

Liquid

color 

Colourless

Specific Gravity

1.01

Water Solubility 

Slightly miscible with water.

Sensitive 

Hygroscopic

Stability:

Light Sensitive

InChIKey

FIHBHSQYSYVZQE-UHFFFAOYSA-N

LogP

2.81 at 25℃

CAS DataBase Reference

13048-33-4(CAS DataBase Reference)

NIST Chemistry Reference

Hexamethylene diacrylate(13048-33-4)

EPA Substance Registry System

1,6-Hexanediol diacrylate (13048-33-4)

Safety Information

Hazard Codes 

Xi

Risk Statements 

36/38-43

Safety Statements 

39

RIDADR 

UN 3082 9/PG 3

WGK Germany 

2

RTECS 

AT1430000

TSCA 

Yes

HazardClass 

9

PackingGroup 

III

HS Code 

29161290

Hazardous Substances Data

13048-33-4(Hazardous Substances Data)

MSDS

• Language:English Provider:Hexane-1,6-diyl bisacrylate
• Language:English Provider:SigmaAldrich
• Language:English Provider:ALFA

Hexamethylene diacrylate Usage And Synthesis

Description

Hexamethylene diacrylate (also known as hexanediol diacrylate) is a di-functional acrylic monomer that can be polymerized by free radicals. It is used in ultra violet (UV) and electron beam (EB) applications as a reactive component in formulating coatings and inks, furniture and floor coatings, coatings on plastic substrates, varnishes for packing items and more¹. The hexamethylene diacrylate cross-linked polystyrene resin can be used for the solid phase synthesis of hydrophobic peptides^2-3.

Sources

1. https://www.ashland.com/file_source/Ashland/Documents/Sustainability/rc_hexanediol_diacrylate.pdf
2. Varkey, J. T., and V. N. Pillai. "Solid phase synthesis of hydrophobic peptides on 1,6-hexanediol diacrylate cross-linked polystyrene resin." Journal of Peptide Science 5.12(1999): 577-81.
3. https://www.palmerholland.com/Assets/User/Documents/Product/40781/4988/MITM00481.pdf

Description

Sensitizaion occurred after accidental occupational exposure in an employee in the laboratory of a plastic paint factory.

Chemical Properties

Colorless transparent liquid

Uses

1,6-Hexandiol diacrylate is used in organic synthesis; common acrylic monomer in UV -cured inks, adhesives, coatings, photoresists, castings, artificial nails, etc.; monomer in dental composite materials.

Uses

1,6-Hexanediol diacrylate is used as a functional monomer for polymers. It acts as a cross linking agent between the molecular chains of polymers. Further, it is used in adhesives, sealants, alkyd coatings, elastomers, photopolymers, and inks for improved adhesion, hardness, abrasion and heat resistance.

General Description

Clear yellow liquid.

Air & Water Reactions

Insoluble in water.

Reactivity Profile

Hexamethylene diacrylate is temperature sensitive . May react vigorously with strong oxidizing agents. May react exothermically with reducing agents to release gaseous hydrogen. Can undergo very exothermic addition polymerization reactions. May undergo autoxidation upon exposure to the air to form explosive peroxides.

Fire Hazard

Hexamethylene diacrylate is probably combustible.

Flammability and Explosibility

Non flammable

Hexamethylene diacrylate(13048-33-4)Related Product Information

• 1-Naphthyl isocyanate
• Methyl propiolate
• 1,6-Hexanediol
• Hexane
• 2,5-Hexanediol
• 6-Benzylaminopurine
• Hydroxypropyl acrylate
• Poly(ethylene glycol) diacrylate
• Polyacrylate rubber
• Isochlorogenic Acid B
• cynaropicrin
• Isochlorogenic acid C
• 1,6-Hexanediol dimethacrylate
• 2,2',6,6'-TETRABROMO BISPHENOL ''A'' DIACRYLATE
• 1H,1H,2H,2H-PERFLUORO-1,6-HEXYLDIMETHACRYLATE
• 1,4-CYCLOHEXANEDIMETHYL 1,4-DIMETHACRYLATE
• 2,2,3,3,4,4,5,5-OCTAFLUORO-1,6-HEXYL DIMETHACRYLATE
• 2,2,3,3,4,4,5,5-OCTAFLUORO-1,6-HEXANEDIOL DIACRYLATE