Hexamethylene diacrylate
Hexamethylene diacrylate Basic information
- Product Name:
- Hexamethylene diacrylate
- Synonyms:
-
- HDODA
- HEXAMETHYLENE GLYCOL DIACRYLATE
- Zinc02019846
- 1,6-BIS(ACRYLOYLOXY)HEXANE
- 1,6-HEXANEDIOL DIACRYLATE
- 1,6-HEXAMETHYLENE DIACRYLATE
- Bisacrylic acid 1,6-hexanediyl ester
- Bispropenoic acid 1,6-hexanediyl ester
- CAS:
- 13048-33-4
- MF:
- C12H18O4
- MW:
- 226.27
- EINECS:
- 235-921-9
- Product Categories:
-
- Industrial/Fine Chemicals
- Diacrylates & Dimethacrylates
- monomer
- Functional Materials
- Reagent for High-Performance Polymer Research
- Mol File:
- 13048-33-4.mol
Hexamethylene diacrylate Chemical Properties
- Melting point:
- 6°C
- Boiling point:
- 295°C
- Density
- 1.01 g/mL at 25 °C (lit.)
- vapor density
- >1 (vs air)
- vapor pressure
- <0.01 mm Hg ( 20 °C)
- refractive index
- n20/D 1.456(lit.)
- Flash point:
- >230 °F
- storage temp.
- under inert gas (nitrogen or Argon) at 2–8 °C
- solubility
- Chlroform (Slightly), DMSO (Slightly)
- form
- Liquid
- color
- Colourless
- Specific Gravity
- 1.01
- Water Solubility
- Slightly miscible with water.
- FreezingPoint
- 6
- Sensitive
- Hygroscopic
- Stability:
- Light Sensitive
- InChIKey
- FIHBHSQYSYVZQE-UHFFFAOYSA-N
- LogP
- 2.81 at 25℃
- CAS DataBase Reference
- 13048-33-4(CAS DataBase Reference)
- NIST Chemistry Reference
- Hexamethylene diacrylate(13048-33-4)
- EPA Substance Registry System
- 1,6-Hexanediol diacrylate (13048-33-4)
Safety Information
- Hazard Codes
- Xi
- Risk Statements
- 36/38-43
- Safety Statements
- 39
- RIDADR
- UN 3082 9/PG 3
- WGK Germany
- 2
- RTECS
- AT1430000
- TSCA
- Yes
- HazardClass
- 9
- PackingGroup
- III
- HS Code
- 29161290
- Hazardous Substances Data
- 13048-33-4(Hazardous Substances Data)
MSDS
- Language:English Provider:Hexane-1,6-diyl bisacrylate
- Language:English Provider:SigmaAldrich
- Language:English Provider:ALFA
Hexamethylene diacrylate Usage And Synthesis
Description
Hexamethylene diacrylate (also known as hexanediol diacrylate) is a di-functional acrylic monomer that can be polymerized by free radicals. It is used in ultra violet (UV) and electron beam (EB) applications as a reactive component in formulating coatings and inks, furniture and floor coatings, coatings on plastic substrates, varnishes for packing items and more1. The hexamethylene diacrylate cross-linked polystyrene resin can be used for the solid phase synthesis of hydrophobic peptides2-3.
Sources
- https://www.ashland.com/file_source/Ashland/Documents/Sustainability/rc_hexanediol_diacrylate.pdf
- Varkey, J. T., and V. N. Pillai. "Solid phase synthesis of hydrophobic peptides on 1,6-hexanediol diacrylate cross-linked polystyrene resin." Journal of Peptide Science 5.12(1999): 577-81.
- https://www.palmerholland.com/Assets/User/Documents/Product/40781/4988/MITM00481.pdf
Description
Sensitizaion occurred after accidental occupational exposure in an employee in the laboratory of a plastic paint factory.
Chemical Properties
Colorless transparent liquid
Uses
1,6-Hexandiol diacrylate is used in organic synthesis; common acrylic monomer in UV -cured inks, adhesives, coatings, photoresists, castings, artificial nails, etc.; monomer in dental composite materials.
Uses
1,6-Hexanediol diacrylate is used as a functional monomer for polymers. It acts as a cross linking agent between the molecular chains of polymers. Further, it is used in adhesives, sealants, alkyd coatings, elastomers, photopolymers, and inks for improved adhesion, hardness, abrasion and heat resistance.
General Description
Clear yellow liquid.
Air & Water Reactions
Insoluble in water.
Reactivity Profile
Hexamethylene diacrylate is temperature sensitive . May react vigorously with strong oxidizing agents. May react exothermically with reducing agents to release gaseous hydrogen. Can undergo very exothermic addition polymerization reactions. May undergo autoxidation upon exposure to the air to form explosive peroxides.
Fire Hazard
Hexamethylene diacrylate is probably combustible.
Flammability and Explosibility
Non flammable
Hexamethylene diacrylateSupplier
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- 512-83500002 13862111431
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Hexamethylene diacrylate(13048-33-4)Related Product Information
- 1-Naphthyl isocyanate
- Methyl propiolate
- 1,6-Hexanediol
- Hexane
- 2,5-Hexanediol
- 6-Benzylaminopurine
- Hydroxypropyl acrylate
- Poly(ethylene glycol) diacrylate
- Polyacrylate rubber
- Isochlorogenic Acid B
- cynaropicrin
- Isochlorogenic acid C
- 1,6-Hexanediol dimethacrylate
- 2,2',6,6'-TETRABROMO BISPHENOL ''A'' DIACRYLATE
- 1H,1H,2H,2H-PERFLUORO-1,6-HEXYLDIMETHACRYLATE
- 1,4-CYCLOHEXANEDIMETHYL 1,4-DIMETHACRYLATE
- 2,2,3,3,4,4,5,5-OCTAFLUORO-1,6-HEXYL DIMETHACRYLATE
- 2,2,3,3,4,4,5,5-OCTAFLUORO-1,6-HEXANEDIOL DIACRYLATE