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Hexamethylene diacrylate

Basic information Description Sources Safety Supplier Related

Hexamethylene diacrylate Basic information

Product Name:
Hexamethylene diacrylate
Synonyms:
  • HDODA
  • HEXAMETHYLENE GLYCOL DIACRYLATE
  • Zinc02019846
  • 1,6-BIS(ACRYLOYLOXY)HEXANE
  • 1,6-HEXANEDIOL DIACRYLATE
  • 1,6-HEXAMETHYLENE DIACRYLATE
  • Bisacrylic acid 1,6-hexanediyl ester
  • Bispropenoic acid 1,6-hexanediyl ester
CAS:
13048-33-4
MF:
C12H18O4
MW:
226.27
EINECS:
235-921-9
Product Categories:
  • Industrial/Fine Chemicals
  • Diacrylates & Dimethacrylates
  • monomer
  • Functional Materials
  • Reagent for High-Performance Polymer Research
Mol File:
13048-33-4.mol
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Hexamethylene diacrylate Chemical Properties

Melting point:
6°C
Boiling point:
295°C
Density 
1.01 g/mL at 25 °C (lit.)
vapor density 
>1 (vs air)
vapor pressure 
<0.01 mm Hg ( 20 °C)
refractive index 
n20/D 1.456(lit.)
Flash point:
>230 °F
storage temp. 
under inert gas (nitrogen or Argon) at 2–8 °C
solubility 
Chlroform (Slightly), DMSO (Slightly)
form 
Liquid
color 
Colourless
Specific Gravity
1.01
Water Solubility 
Slightly miscible with water.
FreezingPoint 
6
Sensitive 
Hygroscopic
Stability:
Light Sensitive
InChIKey
FIHBHSQYSYVZQE-UHFFFAOYSA-N
LogP
2.81 at 25℃
CAS DataBase Reference
13048-33-4(CAS DataBase Reference)
NIST Chemistry Reference
Hexamethylene diacrylate(13048-33-4)
EPA Substance Registry System
1,6-Hexanediol diacrylate (13048-33-4)
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Safety Information

Hazard Codes 
Xi
Risk Statements 
36/38-43
Safety Statements 
39
RIDADR 
UN 3082 9/PG 3
WGK Germany 
2
RTECS 
AT1430000
TSCA 
Yes
HazardClass 
9
PackingGroup 
III
HS Code 
29161290
Hazardous Substances Data
13048-33-4(Hazardous Substances Data)

MSDS

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Hexamethylene diacrylate Usage And Synthesis

Description

Hexamethylene diacrylate (also known as hexanediol diacrylate) is a di-functional acrylic monomer that can be polymerized by free radicals. It is used in ultra violet (UV) and electron beam (EB) applications as a reactive component in formulating coatings and inks, furniture and floor coatings, coatings on plastic substrates, varnishes for packing items and more1. The hexamethylene diacrylate cross-linked polystyrene resin can be used for the solid phase synthesis of hydrophobic peptides2-3.

Sources

  1. https://www.ashland.com/file_source/Ashland/Documents/Sustainability/rc_hexanediol_diacrylate.pdf
  2. Varkey, J. T., and V. N. Pillai. "Solid phase synthesis of hydrophobic peptides on 1,6-hexanediol diacrylate cross-linked polystyrene resin." Journal of Peptide Science 5.12(1999): 577-81.
  3. https://www.palmerholland.com/Assets/User/Documents/Product/40781/4988/MITM00481.pdf

Description

Sensitizaion occurred after accidental occupational exposure in an employee in the laboratory of a plastic paint factory.

Chemical Properties

Colorless transparent liquid

Uses

1,6-Hexandiol diacrylate is used in organic synthesis; common acrylic monomer in UV -cured inks, adhesives, coatings, photoresists, castings, artificial nails, etc.; monomer in dental composite materials.

Uses

1,6-Hexanediol diacrylate is used as a functional monomer for polymers. It acts as a cross linking agent between the molecular chains of polymers. Further, it is used in adhesives, sealants, alkyd coatings, elastomers, photopolymers, and inks for improved adhesion, hardness, abrasion and heat resistance.

General Description

Clear yellow liquid.

Air & Water Reactions

Insoluble in water.

Reactivity Profile

Hexamethylene diacrylate is temperature sensitive . May react vigorously with strong oxidizing agents. May react exothermically with reducing agents to release gaseous hydrogen. Can undergo very exothermic addition polymerization reactions. May undergo autoxidation upon exposure to the air to form explosive peroxides.

Fire Hazard

Hexamethylene diacrylate is probably combustible.

Flammability and Explosibility

Non flammable

Hexamethylene diacrylateSupplier

Suzhou Senfeida Chemical Material Co., Ltd. Gold
Tel
512-83500002 13862111431
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sales2@senfeida.com
Hubei Xingyan New Material Technology Co., Ltd Gold
Tel
13129948835
Email
2756772312@qq.com
Guangzhou Shanghe Chemical Technology Co., Ltd Gold
Tel
13352869970
Email
272907493@qq.com
IGM RESINS
Tel
021-52080993 13917193189
Email
selene.wu@igmresins.com
J & K SCIENTIFIC LTD.
Tel
010-82848833 400-666-7788
Email
jkinfo@jkchemical.com