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TETRAHYDRO-2-(2-PROPYNYLOXY)-2H-PYRAN

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TETRAHYDRO-2-(2-PROPYNYLOXY)-2H-PYRAN Basic information

Product Name:
TETRAHYDRO-2-(2-PROPYNYLOXY)-2H-PYRAN
Synonyms:
  • 2-(2-Propynyloxy)tetrahydro-2H-pyran
  • pent-4-ynoic acid
  • TETRAHYDRO-2-(2-PROPYNYLOXY)-2H-PYRAN, 9 8%
  • 2-(Propargyloxy)tetrahydropyran
  • 2-Propargyloxane
  • 2-Propynyl 2-pyranyl ether
  • 2-Propynyl tetrahydro-2H-pyran-2-yl ether
  • 3-(2'-Tetrahydropyranyloxy)propyne
CAS:
6089-04-9
MF:
C8H12O2
MW:
140.18
EINECS:
228-027-5
Product Categories:
  • API intermediates
  • Boronic ester
  • Organoborons
  • Pyran
  • Acetylenes
  • Functionalized Acetylenes
  • Building Blocks
  • Heterocyclic Building Blocks
  • Pyrans
  • Alphabetic
  • TA - TE
Mol File:
6089-04-9.mol
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TETRAHYDRO-2-(2-PROPYNYLOXY)-2H-PYRAN Chemical Properties

Boiling point:
63-65 °C9 mm Hg(lit.)
Density 
0.997 g/mL at 25 °C(lit.)
refractive index 
n20/D 1.458(lit.)
Flash point:
139 °F
storage temp. 
2-8°C
form 
Liquid
color 
Clear colorless to light yellow
Specific Gravity
0.997
InChIKey
RNRIMDSCBRDPLC-UHFFFAOYSA-N
CAS DataBase Reference
6089-04-9
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Safety Information

Hazard Codes 
Xi,F
Risk Statements 
11
Safety Statements 
26-27-28-36/37/39-16
RIDADR 
UN 1993 3/PG 3
WGK Germany 
3
HazardClass 
3.2
PackingGroup 
III
HS Code 
29329900

MSDS

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TETRAHYDRO-2-(2-PROPYNYLOXY)-2H-PYRAN Usage And Synthesis

Chemical Properties

Clear colorless to light yellow liquid

Uses

Tetrahydro-2-(2-propynyloxy)-2H-pyran was used in preparation of 1,3-dienyl acetal.

Synthesis Reference(s)

Chemistry Letters, 6, p. 817, 1977
Organic Syntheses, Coll. Vol. 7, p. 334, 1990
Synthetic Communications, 19, p. 901, 1989 DOI: 10.1080/00397918908051010

General Description

The anion formed by metalation at the acetylenic carbon reacts with a variety of electrophiles.

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