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Pyran compounds

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Pyrans refer to hexaheterocyclic compounds containing one oxygen atom, including two isomers- α-pyran and γ-pyran. Pyran without substituents has not been found, but pyran derivatives are widely found in nature. α-pyrone and γ-pyrone mainly exist in plants. Benzopyran (chromene), chromone, coumarin, flavonoid, isoflavone and anthocyanin can be regarded as pyran derivatives.

The electronic structure of pyran is similar to that of benzene. The oxygen atom in the hexaheterocyclic ring has a strong alkalinity. Pyran is stabilized after its salification. Many important natural substances such as pigments, sugars, antibiotics and alkaloids, contain the ring system of pyran or pyrylium salts. E.g. six-member ring hemiacetal structures in the form of pentose or hexose are called pyranose.

Pyrone can be considered as the product of oxidation methine part of pyran into carbonyl group. A-pyrone, as the lactone of 5-hydroxy-2,4-pentadienoic acid, can participate in the hydrolysis reaction under acid-base catalysis, also can be catalytically hydrogenated into 5-hydroxyvalerate lactone, although its carbonyl is not easy to reduced. A-pyrone can also participate in diene synthesis. Γ-pyrone is different, it has a significant aromaticity. Although it is an unsaturated ketone, it cannot form hydrazone with phenylhydrazine. Also its carbonyl is not prone to reduction reaction. Some important medicines such as erythromycin and dihydrostreptomycin contain a tetrahydropyran ring. Many carbohydrates contain tetrahydropyran ring structures.

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Structure:
Chemical Name:
Tetrahydro-4-pyranol
CAS:
2081-44-9
MF:
C5H10O2
Structure:
Chemical Name:
4-Hydroxycoumarin
CAS:
1076-38-6
MF:
C9H6O3
Structure:
Chemical Name:
METHYL-(TETRAHYDRO-PYRAN-4-YL)-AMINE HCL
CAS:
220641-87-2
MF:
C6H13NO
Structure:
Chemical Name:
Tetrahydropyran
CAS:
142-68-7
MF:
C5H10O
Structure:
Chemical Name:
4-(2-Tetrahydropyranyloxy)phenylboronic acid
CAS:
182281-01-2
MF:
C11H15BO4
Structure:
Chemical Name:
Methyl tetrahydropyran-4-carboxylate
CAS:
110238-91-0
MF:
C7H12O3
Structure:
Chemical Name:
6-Bromo-2,3-dihydro-4H-chromen-4-one
CAS:
49660-57-3
MF:
C9H7BrO2
Structure:
Chemical Name:
Tetrahydro-4H-pyran-4-one
CAS:
29943-42-8
MF:
C5H8O2
Structure:
Chemical Name:
4-Chromanone
CAS:
491-37-2
MF:
C9H8O2
Structure:
Chemical Name:
4-Aminotetrahydropyran
CAS:
38041-19-9
MF:
C5H11NO
Structure:
Chemical Name:
Tetrahydro-2H-pyran-4-carboxylic acid
CAS:
5337-03-1
MF:
C6H10O3
Structure:
Chemical Name:
3,4-Dihydro-2H-pyran
CAS:
110-87-2
MF:
C5H8O
Structure:
Chemical Name:
(TETRAHYDRO-2H-PYRAN-4-YL)METHANOL
CAS:
14774-37-9
MF:
C6H12O2
Structure:
Chemical Name:
6-CHLORO-9-(TETRAHYDRO-2-PYRANYL)-PURINE
CAS:
7306-68-5
MF:
C10H11ClN4O
Structure:
Chemical Name:
2,3,4,6-Tetra-O-benzyl-D-glucopyranose
CAS:
4132-28-9
MF:
C34H36O6
Structure:
Chemical Name:
Kojic acid
CAS:
501-30-4
MF:
C6H6O4
Structure:
Chemical Name:
Tetrahydrothiopyran-4-one
CAS:
1072-72-6
MF:
C5H8OS
Structure:
Chemical Name:
O-(Tetrahydro-2H-pyran-2-yl)hydroxylamine
CAS:
6723-30-4
MF:
C5H11NO2
Structure:
Chemical Name:
2H-PYRAN-3(4H)-ONE, DIHYDRO-
CAS:
23462-75-1
MF:
C5H8O2
Structure:
Chemical Name:
8-Amino-4-oxo-2-(tetrazol-5-yl)-4H-1-benzopyran
CAS:
110683-22-2
MF:
C10H7N5O2
Structure:
Chemical Name:
Tetrahydropyran-4-carbaldehyde
CAS:
50675-18-8
MF:
C6H10O2
Structure:
Chemical Name:
7,8-Dihydroxycoumarin
CAS:
486-35-1
MF:
C9H6O4
Structure:
Chemical Name:
4-(Bromomethyl)tetrahydropyran
CAS:
125552-89-8
MF:
C6H11BrO
Structure:
Chemical Name:
Coumarin 6
CAS:
38215-36-0
MF:
C20H18N2O2S
Structure:
Chemical Name:
2-(CHLOROMETHYL)TETRAHYDROPYRAN
CAS:
18420-41-2
MF:
C6H11ClO
Structure:
Chemical Name:
2-methyloxan-4-one
CAS:
1193-20-0
MF:
C6H10O2
Structure:
Chemical Name:
2-Methyl-tetrahydro-pyran-4-ol
CAS:
89791-47-9
MF:
C6H12O2
Structure:
Chemical Name:
3,4-Dihydro-2H-pyran-2-methanol
CAS:
3749-36-8
MF:
C6H10O2
Structure:
Chemical Name:
SCOPARONE
CAS:
120-08-1
MF:
C11H10O4
Structure:
Chemical Name:
4-Aminotetrahydropyran hydrochloride
CAS:
33024-60-1
MF:
C5H12ClNO
Structure:
Chemical Name:
bk-DMBDB (hydrochloride)
CAS:
17763-12-1
MF:
C13H18ClNO3
Structure:
Chemical Name:
4-(DICYANOMETHYLENE)-2-METHYL-6-(4-DIMETHYLAMINOSTYRYL)-4H-PYRAN
CAS:
51325-91-8
MF:
C19H17N3O
Structure:
Chemical Name:
tert-Butyl 2-cyanopiperidine-1-carboxylate
CAS:
153749-89-4
MF:
C11H18N2O2
Structure:
Chemical Name:
2-(2-BROMOETHOXY)TETRAHYDRO-2H-PYRAN
CAS:
17739-45-6
MF:
C7H13BrO2
Structure:
Chemical Name:
Centchroman
CAS:
31477-60-8
MF:
C30H35NO3
Structure:
Chemical Name:
TETRAHYDROPYRAN-2-METHANOL
CAS:
100-72-1
MF:
C6H12O2
Structure:
Chemical Name:
4-Oxo-4H-1-benzopyran-2-carboxylic acid
CAS:
4940-39-0
MF:
C10H6O4
Structure:
Chemical Name:
4-Bromomethyl-7-methoxycoumarin
CAS:
35231-44-8
MF:
C11H9BrO3
Structure:
Chemical Name:
4,6-DICHLORO-2H-BENZOPYRAN-3-CARBOXALDEHYDE
CAS:
175205-58-0
MF:
C10H6Cl2O2
Structure:
Chemical Name:
2-(3-CHLOROPROPOXY)TETRAHYDRO-2H-PYRAN
CAS:
42330-88-1
MF:
C8H15ClO2
Structure:
Chemical Name:
2,2-DIMETHYLTETRAHYDROPYRAN-4-ONE
CAS:
1194-16-7
MF:
C7H12O2
Structure:
Chemical Name:
ALPHA-PYRONE
CAS:
504-31-4
MF:
C5H4O2
Structure:
Chemical Name:
Bergapten
CAS:
484-20-8
MF:
C12H8O4
Structure:
Chemical Name:
2-(3-BROMOPHENOXY)TETRAHYDRO-2H-PYRAN
CAS:
57999-49-2
MF:
C11H13BrO2
Structure:
Chemical Name:
4-Cyanotetrahydro-4H-pyran
CAS:
4295-99-2
MF:
C6H9NO
Structure:
Chemical Name:
3,4-DIHYDRO-2-METHOXY-2H-PYRAN
CAS:
4454-05-1
MF:
C6H10O2
Structure:
Chemical Name:
2-(3-BUTYNYLOXY)TETRAHYDRO-2 H-PYRAN
CAS:
40365-61-5
MF:
C9H14O2
Structure:
Chemical Name:
4-Methoxy-6-methyl-2H-pyran-2-one
CAS:
672-89-9
MF:
C7H8O3
Structure:
Chemical Name:
1,1-Dioxo-tetrahydro-thiopyran-4-one
CAS:
17396-35-9
MF:
C5H8O3S
Structure:
Chemical Name:
Dimethyl Furan-2,5-dicarboxylate
CAS:
4282-32-0
MF:
C8H8O5
Structure:
Chemical Name:
4-Hydroxy-6-methyl-2-pyrone
CAS:
675-10-5
MF:
C6H6O3
Structure:
Chemical Name:
4-CHLOROTETRAHYDROPYRAN
CAS:
1768-64-5
MF:
C5H9ClO
Structure:
Chemical Name:
4-CHLORO-6-FLUORO-2H-BENZOPYRAN-3-CARBOXALDEHYDE
CAS:
105799-69-7
MF:
C10H6ClFO2
Structure:
Chemical Name:
4-(Aminomethyl)tetrahydro-2H-pyran
CAS:
130290-79-8
MF:
C6H13NO
Structure:
Chemical Name:
4-Aminotetrahydro-2H-pyran acetate
CAS:
1005498-91-8
MF:
C7H15NO3
Structure:
Chemical Name:
4-METHYLUMBELLIFERYL PHOSPHATE DISODIUM SALT
CAS:
22919-26-2
MF:
C10H10NaO6P
Structure:
Chemical Name:
4-BROMO-TETRAHYDROPYRAN
CAS:
25637-16-5
MF:
C5H9BrO
Structure:
Chemical Name:
4H-PYRAN-4-ONE
CAS:
108-97-4
MF:
C5H4O2
Structure:
Chemical Name:
2-(4-BROMOPHENOXY)TETRAHYDRO-2H-PYRAN
CAS:
36603-49-3
MF:
C11H13BrO2
Structure:
Chemical Name:
Tetrahydro-2H-pyran-4-carbonyl chloride
CAS:
40191-32-0
MF:
C6H9ClO2
Structure:
Chemical Name:
2-Formyl-3,4-dihydro-2H-pyran
CAS:
100-73-2
MF:
C6H8O2
Structure:
Chemical Name:
2-(4-PENTYNYLOXY)TETRAHYDRO-2H-PYRAN 9&
CAS:
62992-46-5
MF:
C10H16O2
Structure:
Chemical Name:
2-(3-Bromopropoxy)tetrahydro-2H-pyran
CAS:
33821-94-2
MF:
C8H15BrO2
Structure:
Chemical Name:
Coumarin-6-carboxylic acid
CAS:
7734-80-7
MF:
C10H6O4
Structure:
Chemical Name:
7-HYDROXY-4-(TRIFLUOROMETHYL)COUMARIN
CAS:
575-03-1
MF:
C10H5F3O3
Structure:
Chemical Name:
4-(2-AMINOETHYL)TETRAHYDROPYRAN
CAS:
65412-03-5
MF:
C7H15NO
Structure:
Chemical Name:
5,6-DIHYDRO-2H-PYRAN-2-ONE
CAS:
3393-45-1
MF:
C5H6O2
Structure:
Chemical Name:
Tetrahydropyranyl-4-acetic acid
CAS:
85064-61-5
MF:
C7H12O3
Structure:
Chemical Name:
TRIOXSALEN
CAS:
3902-71-4
MF:
C14H12O3
Structure:
Chemical Name:
4-METHYLUMBELLIFERYL PHOSPHATE
CAS:
3368-04-5
MF:
C10H9O6P
Structure:
Chemical Name:
6-HYDROXYFLAVANONE
CAS:
4250-77-5
MF:
C15H12O3
Structure:
Chemical Name:
5,7-Dihydroxy-4-methylcoumarin
CAS:
2107-76-8
MF:
C10H8O4
Structure:
Chemical Name:
TETRAHYDRO-2-(2-PROPYNYLOXY)-2H-PYRAN
CAS:
6089-04-9
MF:
C8H12O2
Structure:
Chemical Name:
2-(TETRAHYDRO-2H-PYRAN-2-YLOXY)ETHANOL
CAS:
2162-31-4
MF:
C7H14O3
Structure:
Chemical Name:
5,7-Dimethoxycoumarin
CAS:
487-06-9
MF:
C11H10O4
Structure:
Chemical Name:
3-CARBOMETHOXY-2-PYRONE
CAS:
25991-27-9
MF:
C7H6O4
Structure:
Chemical Name:
6-BROMOCOUMARIN-3-CARBOXYLIC ACID
CAS:
2199-87-3
MF:
C10H5BrO4
Structure:
Chemical Name:
3-BROMOCHROMONE
CAS:
49619-82-1
MF:
C9H5BrO2
Structure:
Chemical Name:
2-(2-NITROETHOXY)TETRAHYDROPYRAN
CAS:
75233-61-3
MF:
C7H13NO4
Structure:
Chemical Name:
3,4-DIHYDRO-6-METHYL-2H-PYRAN-2-ONE
CAS:
3740-59-8
MF:
C6H8O2
Structure:
Chemical Name:
7-ACETOXY-4-BROMOMETHYLCOUMARIN
CAS:
2747-04-8
MF:
C12H9BrO4
Structure:
Chemical Name:
2,4,6-TRIPHENYLPYRYLIUM TETRAFLUOROBORATE
CAS:
448-61-3
MF:
C23H17BF4O
Structure:
Chemical Name:
2-(2-CHLOROETHOXY)TETRAHYDRO-2H-PYRAN
CAS:
5631-96-9
MF:
C7H13ClO2
Structure:
Chemical Name:
6-BROMO-3-FORMYLCHROMONE
CAS:
52817-12-6
MF:
C10H5BrO3
Structure:
Chemical Name:
7-Ethoxycoumarin
CAS:
31005-02-4
MF:
C11H10O3
Structure:
Chemical Name:
(TETRAHYDRO-PYRAN-4-YL)-ACETONITRILE
CAS:
850429-50-4
MF:
C7H11NO
Structure:
Chemical Name:
3-CHLORO-7-HYDROXY-4-METHYLCOUMARIN
CAS:
6174-86-3
MF:
C10H7ClO3
Structure:
Chemical Name:
2-(ALLYLOXY)TETRAHYDROPYRAN
CAS:
4203-49-0
MF:
C8H14O2
Structure:
Chemical Name:
2-(2-BROMOETHOXY)TETRAHYDRO-2H-PYRAN
CAS:
59146-56-4
MF:
C7H13BrO2
Structure:
Chemical Name:
7-Methoxycoumarin-4-acetic acid
CAS:
62935-72-2
MF:
C12H10O5
Structure:
Chemical Name:
ISOPIMPINELLIN
CAS:
482-27-9
MF:
C13H10O5
Structure:
Chemical Name:
Ethyl Tetrahydropyran-4-Carboxylate
CAS:
96835-17-5
MF:
C8H14O3
Structure:
Chemical Name:
CHROMONE-3-CARBOXALDEHYDE
CAS:
17422-74-1
MF:
C10H6O3
Structure:
Chemical Name:
7,8-DIHYDROXY-6-METHOXYCOUMARIN
CAS:
574-84-5
MF:
C10H8O5
Structure:
Chemical Name:
3,4-DIHYDRO-2,2-DIMETHYL-4-OXO-2H-PYRAN-6-CARBOXYLIC ACID
CAS:
80866-93-9
MF:
C8H10O4
Structure:
Chemical Name:
6-BROMOCHROMONE
CAS:
51483-92-2
MF:
C9H5BrO2
Structure:
Chemical Name:
7-Methoxy-4-methylcoumarin
CAS:
2555-28-4
MF:
C11H10O3
Structure:
Chemical Name:
XANTHOTOXOL
CAS:
2009-24-7
MF:
C11H6O4
Structure:
Chemical Name:
COUMARIN 152
CAS:
53518-14-2
MF:
C12H10F3NO2
Structure:
Chemical Name:
2-(TETRAHYDROFURFURYLOXY)TETRAHYDROPYRAN
CAS:
710-14-5
MF:
C10H18O3