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7,8-DIHYDROXY-6-METHOXYCOUMARIN

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7,8-DIHYDROXY-6-METHOXYCOUMARIN Basic information

Product Name:
7,8-DIHYDROXY-6-METHOXYCOUMARIN
Synonyms:
  • Fraxetin (6-OMe, 7,8-OH)
  • 7,8-Dihydroxy-6-MethoxycouMarin 98%
  • 2H-1-Benzopyran-2-one, 7,8-dihydroxy-6-methoxy-
  • 7,8-Dihydroxy-6-methoxy-2H-chromen-2-one
  • 7,8-DIHYDROXY-6-METHOXYCOUMARIN
  • Fratexin
  • FRAXETIN
  • 7,8-dihydroxy-6-methoxy-2-benzopyrone
CAS:
574-84-5
MF:
C10H8O5
MW:
208.17
EINECS:
209-376-2
Product Categories:
  • chemical reagent
  • pharmaceutical intermediate
  • phytochemical
  • reference standards from Chinese medicinal herbs (TCM).
  • standardized herbal extract
  • Inhibitors
  • Coumarins
Mol File:
574-84-5.mol
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7,8-DIHYDROXY-6-METHOXYCOUMARIN Chemical Properties

Melting point:
230-231 °C (lit.)
Boiling point:
307.35°C (rough estimate)
Density 
1.3844 (rough estimate)
refractive index 
1.4717 (estimate)
storage temp. 
under inert gas (nitrogen or Argon) at 2-8°C
solubility 
DMSO : 250 mg/mL (1200.94 mM; Need ultrasonic)
pka
7.22±0.20(Predicted)
form 
Solid
color 
White
Merck 
13,4288
Stability:
Hygroscopic
InChI
InChI=1S/C10H8O5/c1-14-6-4-5-2-3-7(11)15-10(5)9(13)8(6)12/h2-4,12-13H,1H3
InChIKey
HAVWRBANWNTOJX-UHFFFAOYSA-N
SMILES
C1(=O)OC2=C(O)C(O)=C(OC)C=C2C=C1
LogP
0.590 (est)
CAS DataBase Reference
574-84-5(CAS DataBase Reference)
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Safety Information

Hazard Codes 
Xn
Risk Statements 
20/21/22-36/37/38
Safety Statements 
26-36
WGK Germany 
3
HS Code 
29322090
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7,8-DIHYDROXY-6-METHOXYCOUMARIN Usage And Synthesis

Chemical Properties

Pale yellow crystalline powder, easily soluble in methanol and acetone, derived from the bark of Fraxinus chinensis, the bark of Fraxinus microphylla, and the leaves of Fraxinus himachicola.

Uses

Fraxetin is a coumarin compound with anti-oxidant and anti-inflammatory activity. Also acts as a protective agent against hyperuricemia and renal dysfunction.

Definition

ChEBI: Fraxetin is a hydroxycoumarin that is 6-methoxycoumarin in which the hydrogens at positions 7 and 8 have been replaced by hydroxy groups. It has a role as an Arabidopsis thaliana metabolite, an antimicrobial agent, an apoptosis inhibitor, an apoptosis inducer, an antioxidant, an anti-inflammatory agent, a hepatoprotective agent, an antibacterial agent and a hypoglycemic agent. It is a hydroxycoumarin and an aromatic ether.

in vivo

Fraxetin (20-50 mg/kg, gavage, once daily, 24 weeks) has a hepatoprotective effect in mice and also has antioxidant and anti-inflammatory activities[3].

Animal Model:Ethanol-induced liver fibrosis model in rats [3]
Dosage:20, 50 mg/kg; daily; 24 weeks
Administration:i.g.
Result:Reduced serum ALT and AST, weakened tissue pathological changes, upregulated heme oxygenase-1 (HO-1) protein, reduced lipid peroxidation, enhanced liver antioxidant capacity, inhibited CYP2E1 activity, and reduced inflammatory mediators such as TNF-α and IL-1β.

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