2-Benzylaminopyridine Chemical Properties

Melting point:

95-97 °C (lit.)

Boiling point:

116-131 °C/0.6 mmHg (lit.)

Density 

1.1160 (rough estimate)

refractive index 

1.6266 (estimate)

Flash point:

182°C/12mm

storage temp. 

Sealed in dry,2-8°C

pka

6.61±0.10(Predicted)

form 

powder to crystal

color 

White to Light yellow to Light orange

BRN 

134309

CAS DataBase Reference

6935-27-9(CAS DataBase Reference)

EPA Substance Registry System

2-Pyridinamine, N-(phenylmethyl)- (6935-27-9)

Safety Information

Hazard Codes 

Xn,Xi

Risk Statements 

22-37/38-41-40-36/37/38-20/21/22

Safety Statements 

26-39-36-22

WGK Germany 

3

RTECS 

US2700000

TSCA 

Yes

HS Code 

29333999

MSDS

• Language:English Provider:2-Benzylaminopyridine
• Language:English Provider:ACROS
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2-Benzylaminopyridine Usage And Synthesis

Chemical Properties

white to off-white powder

Uses

2-(Benzylamino)pyridine is used as a reactant in the amination of aryl chlorides, bromides, and triflates catalyzed by palladium complexes.

Synthesis Reference(s)

Organic Syntheses, Coll. Vol. 4, p. 91, 1963
The Journal of Organic Chemistry, 67, p. 4965, 2002 DOI: 10.1021/jo020057z

General Description

2-Benzylaminopyridine on reaction with BBr₃ yields the corresponding amino or hydroxy substituted compounds. It forms 5- and 6-coordinated organometallic complexes of gallium(III) and indium(III).

2-Benzylaminopyridine(6935-27-9)Related Product Information

• Benzyl alcohol
• Benzoyl peroxide
• 3-Aminopyridine
• 2,6-Lutidine
• 2-Aminopyridine
• Benzyl chloride
• Benzyl butyrate
• Benzyl benzoate
• DIMETHYLAMINOPYRIDINE, POLYMER-BOUND
• 4-Dimethylaminopyridine
• Tris(hydroxymethyl)aminomethane
• 4-Methylpyridine
• Benzyl acetate
• 2-Aminobenzylchloride
• Benzyl
• 2-(4-Methoxybenzylamino)pyridine
• TRIPELENNAMINE HYDROCHLORIDE
• Chloropyramine