DIMETHYLAMINOPYRIDINE, POLYMER-BOUND Chemical Properties

Flash point:

4 °C

form 

powder

Safety Information

Hazard Codes 

Xi,T

Risk Statements 

36/37/38-23/24/25

Safety Statements 

26-37/39-45-36/37/39-28-16

RIDADR 

UN 3175 4.1/PG 2

WGK Germany 

3

MSDS

• Language:English Provider:SigmaAldrich

DIMETHYLAMINOPYRIDINE, POLYMER-BOUND Usage And Synthesis

Uses

Polymer-bound 4-(dimethylamino)pyridine is used as a supported base in the Michael addition and nitrous acid elimination process step involved in the synthesis of thiophene-2-carboxylates using β-nitroacrylates as starting materials, under a general and efficient continuous flow-based protocol. It also serves as a supported catalyst in the preparation of ω-nitro esters starting from cyclic 2-nitro ketones under solid heterogeneous catalysis.(5)

General Description

Polymer-bound 4-(dimethylamino)pyridine is used for improved derivatization of chiral and achiral aliphatic amines, amino alcohols and amino acids.

reaction suitability

reaction type: solution phase peptide synthesis

DIMETHYLAMINOPYRIDINE, POLYMER-BOUND(82942-26-5)Related Product Information

• TERT-BUTYL ISOCYANIDE
• TRIS(2,2,6,6-TETRAMETHYL-3,5-HEPTANEDIONATO)DYSPROSIUM(III)
• COBALT(II) ACETYLACETONATE
• Tris(2,4-pentanedionato)chroMiuM(III)
• METHYL ISOCYANOACETATE
• N-BUTYLISOCYANIDE
• Ethyl isocyanoacetate
• SALCOMINE
• Benzyl isocyanide
• Ferric acetylacetonate
• Tosylmethyl isocyanide
• 1,1,3,3-TETRAMETHYLBUTYL ISOCYANIDE
• DICHLORO(ETHYLENEDIAMINE)PLATINUM(II)
• TRIS(2,2,6,6-TETRAMETHYL-3,5-HEPTANEDIONATO)EUROPIUM(III)
• PHENYLSELENOL
• Aluminum acetylacetonate
• 2,4-PENTANEDIONE, SILVER DERIVATIVE
• Cupric acetylacetonate