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DIMETHYLAMINOPYRIDINE, POLYMER-BOUND

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DIMETHYLAMINOPYRIDINE, POLYMER-BOUND Basic information

Product Name:
DIMETHYLAMINOPYRIDINE, POLYMER-BOUND
Synonyms:
  • POLYMER SUPPORTED DIMETHYLAMINOPYRIDINE
  • PL-DMAP RESIN
  • N-METHYL-N-(4-PYRIDYL)AMINOMETHYL-POLYSTYRENE CROSSLINKED WITH DIVINYLBENZENE
  • N-BENZYLMETHYLAMINOPYRIDINE POLYMER BOUND
  • DIMETHYLAMINOPYRIDINE ON POLYSTYRENE
  • DIMETHYLAMINOPYRIDINE, POLYMER-BOUND
  • 4-(Dimethylamino)pyridine, polymer-bound 200-400 mesh, extent of labeling: ~6.0 mmol/g loading, 2 % cross-linked
  • loading, matrix crosslinked with 2% DVB
CAS:
82942-26-5
MF:
C8H8
MW:
0
Product Categories:
  • BasesChemical Synthesis
  • Organic Bases
  • Supported Reagents
  • Supported Synthesis
  • Synthetic Reagents
Mol File:
Mol File
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DIMETHYLAMINOPYRIDINE, POLYMER-BOUND Chemical Properties

Flash point:
4 °C
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Safety Information

Hazard Codes 
Xi,T
Risk Statements 
36/37/38-23/24/25
Safety Statements 
26-37/39-45-36/37/39-28-16
RIDADR 
UN 3175 4.1/PG 2
WGK Germany 
3

MSDS

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DIMETHYLAMINOPYRIDINE, POLYMER-BOUND Usage And Synthesis

Uses

Polymer-bound 4-(dimethylamino)pyridine is used as a supported base in the Michael addition and nitrous acid elimination process step involved in the synthesis of thiophene-2-carboxylates using β-nitroacrylates as starting materials, under a general and efficient continuous flow-based protocol. It also serves as a supported catalyst in the preparation of ω-nitro esters starting from cyclic 2-nitro ketones under solid heterogeneous catalysis.(5)

General Description

Polymer-bound 4-(dimethylamino)pyridine is used for improved derivatization of chiral and achiral aliphatic amines, amino alcohols and amino acids.

DIMETHYLAMINOPYRIDINE, POLYMER-BOUND Preparation Products And Raw materials

Preparation Products

DIMETHYLAMINOPYRIDINE, POLYMER-BOUNDSupplier

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