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Octamethyltrisiloxane

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Octamethyltrisiloxane Basic information

Product Name:
Octamethyltrisiloxane
Synonyms:
  • METHYLPOLYSILOXANE
  • DIMETHYLBIS(TRIMETHYLSILYLOXY)SILANE
  • POLY(DIMETHYLSILOXANE), HYDROXY TERMINATED
  • POLY(DIMETHYLSILOXANE), 200(R) FLUID
  • OCTAMETHYLTRISILOXANE
  • [(CH3)3SiO]2Si(CH3)2
  • 1,1,1,3,3,5,5,5-Octamethyltrisiloxane
  • CO9816
CAS:
107-51-7
MF:
C8H24O2Si3
MW:
236.53
EINECS:
203-497-4
Product Categories:
  • Organometallic Reagents
  • Organosilicon
  • Intermediates & Fine Chemicals
  • Pharmaceuticals
  • Chemical Synthesis
  • Materials Science
  • Organics
  • Si (Classes of Silicon Compounds)
  • Siloxanes
  • Si-O Compounds
  • Organometallic Reagents
  • Polymer Science
  • Polysiloxanes
  • Silicones
Mol File:
107-51-7.mol
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Octamethyltrisiloxane Chemical Properties

Melting point:
-82 °C (lit.)
Boiling point:
153 °C (lit.)
Density 
0.82 g/mL at 25 °C (lit.)
vapor density 
>1 (vs air)
vapor pressure 
5.3hPa at 25℃
refractive index 
n20/D 1.384(lit.)
Flash point:
99 °F
storage temp. 
Inert atmosphere,Room Temperature
solubility 
Chloroform (Slightly), DMSO, Methanol (Slightly)
form 
liquid
Specific Gravity
0.82
color 
Colourless to Pale Yellow
Water Solubility 
34μg/L at 23℃
Hydrolytic Sensitivity
1: no significant reaction with aqueous systems
Merck 
14,6748
BRN 
1753063
Dielectric constant
2.3(20℃)
Stability:
Hygroscopic
LogP
6.6 at 25.3℃
CAS DataBase Reference
107-51-7(CAS DataBase Reference)
EPA Substance Registry System
Trisiloxane, octamethyl- (107-51-7)
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Safety Information

Risk Statements 
10
Safety Statements 
23-24/25
RIDADR 
UN 1993 3/PG 3
WGK Germany 
3
10-21
TSCA 
Yes
HazardClass 
3.2
PackingGroup 
III
HS Code 
29319090

MSDS

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Octamethyltrisiloxane Usage And Synthesis

Chemical Properties

Octamethyltrisiloxane is clear colourless liquid.

Uses

Octamethyltrisiloxane is a linear silicone oligomer. It is used as an excipient Dimethicones in pharmaceutical and cosmetic applications can provide long lasting lubricant, smooth feel and spreads easily. Studies demonstrate that it is able to maintain the conformational stability of certain adsorbed proteins such as bovine serum albumin (BSA). Used in the methylation of mercury(II) salts.

Application

As a basis for silicone oils or fluids designed to withstand extremes of temp; as a foam suppressant in petroleum lubricating oil.

Definition

ChEBI: Octamethyltrisiloxane is an organosiloxane that is trisiloxane in which all the hydrogens have been replaced by methyl groups.

General Description

Poly(dimethylsiloxane) (PDMS), also known as dimethicone, is an organosilicon compound that is widely used as a siloxane based elastomer. It is a hydrophobic material with attractive physical and chemical properties such as elasticity, optical transparency, tunable surface chemistry, and low electrical conductivity.

Flammability and Explosibility

Flammable

Purification Methods

Distil it twice, the middle fraction from the first distillation is again distilled, and the middle fraction of the second distillation is used. [Patnode & Wilcock J Am Chem Soc 68 358, Wolcock J Am Chem Soc 68 691 1946, Thompson J Chem Soc 1908 1953, Beilstein 4 IV 4115.]

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