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4-Bromophenylboronic acid

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4-Bromophenylboronic acid Basic information

Product Name:
4-Bromophenylboronic acid
Synonyms:
  • AKOS BRN-0005
  • 4-BROMOPHENYLBORIC ACID ANHYDRIDE
  • 4-BROMOPHENYLBORONIC ACID
  • 4-BROMOBENZENEBORONIC ACID
  • 4-BROMOBENZENEBORONIC ACID/ANHYDRIDE
  • RARECHEM AH PB 0075
  • P-BROMO BENZENE BORONIC ACID
  • P-BROMOPHENYLBORONIC ACID
CAS:
5467-74-3
MF:
C6H6BBrO2
MW:
200.83
EINECS:
226-779-9
Product Categories:
  • Boronate Ester
  • Potassium Trifluoroborate
  • Boronic acids
  • Boronic Acid
  • B (Classes of Boron Compounds)
  • OLED materials,pharm chemical,electronic
  • blocks
  • BoronicAcids
  • Bromides
  • Boric Acid
  • Substituted Boronic Acids
  • Aryl
  • Halogenated
  • Organoborons
Mol File:
5467-74-3.mol
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4-Bromophenylboronic acid Chemical Properties

Melting point:
284-288 °C (lit.)
Boiling point:
315.0±44.0 °C(Predicted)
Density 
1.67±0.1 g/cm3(Predicted)
storage temp. 
Keep in dark place,Sealed in dry,Room Temperature
form 
Crystalline Powder
pka
8.32±0.10(Predicted)
color 
Off-white to light beige
Water Solubility 
Soluble in methanol. Insoluble in water.
BRN 
2936347
InChIKey
QBLFZIBJXUQVRF-UHFFFAOYSA-N
CAS DataBase Reference
5467-74-3(CAS DataBase Reference)
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Safety Information

Hazard Codes 
Xi
Risk Statements 
36/37/38-22
Safety Statements 
26-36-37/39
WGK Germany 
3
RTECS 
CY8650000
TSCA 
T
HazardClass 
IRRITANT
HS Code 
29319090

MSDS

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4-Bromophenylboronic acid Usage And Synthesis

Chemical Properties

white to light yellow crystal powde

Uses

suzuki reaction

Uses

4-Bromobenzeneboronic acid is a reagent used for Palladium catalyzed Suzuki-Miyaura cross-couplings, Tandem-type Pd(II)-catalyzed oxidative Heck reaction and intramolecular C-H amidation sequence. It is also used in the preparation of Protein modulators and enzymatic and kinase inhibitors, Gallate-based obovatol analogs with potential anti-tumor activity. It is used as a reagent for Copper-mediated ligandless aerobic fluoroalkylation of arylboronic acids with fluoroalkyl iodides, Pd-catalyzed arylative cyclization of alkyne-tethered enals or enones via carbopalladation of alkynes, Copper-catalyzed cross-couplings.

Uses

Labelled 4-Bromophenylboronic Acid (B686545). 4-Bromophenylboric acid is used in the preparation of arylboronates as inhibitors of fatty acid amide hydrolase.

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