Diacetone-D-glucose Chemical Properties

Melting point:

110-111 °C(lit.)

alpha 

-11 º (c=5, EtOH)

Boiling point:

323.54°C (rough estimate)

Density 

1.1432 (rough estimate)

refractive index 

-18.5 ° (C=5, H2O)

storage temp. 

Inert atmosphere,Store in freezer, under -20°C

solubility 

Chloroform (Slightly), Methanol (Slightly), Water (Slightly, Sonicated)

pka

13.15±0.60(Predicted)

form 

Powder

color 

White to yellow

optical activity

[α]20/D 18°, c = 1% in H2O

Water Solubility 

slightly soluble

Merck 

14,2965

BRN 

84386

InChIKey

KEJGAYKWRDILTF-YENDLIOYSA-N

EPA Substance Registry System

Diacetone glucose (582-52-5)

Safety Information

Hazard Codes 

Xi

Risk Statements 

36/37/38

Safety Statements 

24/25-36/37-26

WGK Germany 

2

RTECS 

LZ4958000

F 

3-10

TSCA 

Yes

HS Code 

29329970

Toxicity

LD50 oral in mouse: 4gm/kg

MSDS

• Language:English Provider:Diacetone-D-glucose
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Diacetone-D-glucose Usage And Synthesis

Chemical Properties

white to light yellow crystal powde

Uses

It is mainly used in biochemical reaction and used as medicine intermediate. It is used in synthesize for below products: L-gulose;1,2:5,6-Di-O-isopropylidene-a-D-gulofuranose; Alllose; ;1,2:5,6-Double-O-Isopropylidene-3-C-(1-Methoxycarbonyl)Ethide-alfa-D-Furanose) ;1,2:5,6-Di-O-isopropylidene-a-D-ribo-hexofuranose-3-ulose;6-deoxy idose.

Uses

1,2:5,6-Di-O-isopropylidene-α-D-glucofuranose is a compound useful in organic synthesis.

Purification Methods

Diacetone-D-glucose crystallises from Et2O, (needles), pet ether or *C6H6 and sublimes in vacuo. It is soluble in 7 volumes of H2O and 200 volumes of pet ether at their boiling points. The solubility in H2O at 17.5o is 4.3%. It precipitates from aqueous solutions on basification with NaOH. [Schmid & Karrer Helv Chim Acta 32 1371 1949, Fischer & Rund Chem Ber 49 90, 93 1916, IR: Kuhn Anal Chem 22 276 1950, Beilstein 19/12 V 318.]

Diacetone-D-glucose(582-52-5)Related Product Information

• Acetylacetone
• 1,2-O-Isopropylidene-D-glucofuranose
• D-Glucose monohydrate
• Calcium pyruvate
• Pyruvic acid
• D(+)-Glucose
• Diacetone acrylamide
• CORN SYRUP
• 2,5-Hexanedione
• Diacetone Alcohol
• Glucose oxidase
• 1,2:5,6-Bis-O-(1-methylethylidene)-D-mannitol
• Propiophenone
• L-GLUCOSE
• DIACETONE-D-GLUCOSE
• Acetone
• Diacetin
• Phenylacetone