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dendrobine

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dendrobine Basic information

Product Name:
dendrobine
Synonyms:
  • (3α,6α,7R,8S,9R,10α,11α)-Dendrobane-12-one
  • Dendroban-12-one
  • 12-Oxodendrobane
  • 7,5-(EpoxyMethano)-1H-cyclopent[cd]indol-9-one,decahydro-1,7b-diMethyl-6-(1-Methylethyl)-, (2aS,4aS,5R,6S,7R,7aS,7bR)-
  • Dendrobine Dendroban-12-one
  • Dendrobine 1%
  • Dendrobine, 98%, from Dendrobium nobile Lindl
  • Dendrobine 2115-91-5
CAS:
2115-91-5
MF:
C16H25NO2
MW:
263.38
Product Categories:
  • chemical reagent
  • pharmaceutical intermediate
  • phytochemical
  • reference standards from Chinese medicinal herbs (TCM).
  • standardized herbal extract
Mol File:
2115-91-5.mol
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dendrobine Chemical Properties

Melting point:
135-136℃
Boiling point:
375℃
Density 
1.101
Flash point:
133℃
storage temp. 
4°C, protect from light
solubility 
≥60mg/ml in MeOH
form 
Powder
pka
9.49±0.60(Predicted)
color 
White to yellow
InChI
InChI=1S/C16H25NO2/c1-8(2)11-12-10-6-5-9-7-17(4)14(16(9,10)3)13(11)19-15(12)18/h8-14H,5-7H2,1-4H3/t9-,10+,11+,12-,13-,14-,16+/m1/s1
InChIKey
RYAHJFGVOCZDEI-UFFNCVEVSA-N
SMILES
N1(C)[C@@]2([H])[C@]3(C)[C@@]([H])(CC[C@]3([H])C1)[C@@]1([H])C(=O)O[C@]2([H])[C@H]1C(C)C
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Safety Information

HS Code 
29399990
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dendrobine Usage And Synthesis

Description

Dendrobine is a sesquiterpenoid that has been found in D. nobile and has anticancer activity. It decreases viability of A549 cells when used at concentrations ranging from 2.5 to 15 μg/ml. It induces apoptosis in A549 cells when used at concentrations ranging from 1 to 10 μg/ml, as well as increases JNK phosphorylation and sensitizes A549 cells to cisplatin at 10 μg/ml. Dendrobine (50 mg/kg per day) reduces tumor growth in an A549 mouse xenograft model with an additive effect when used in combination with cisplatin.

Chemical Properties

It is easily soluble in ether and chloroform, but hardly soluble in ethanol and water. It is an active ingredient extracted from Dendrobium and its bark.

Uses

Dendrobine is an alkaloid isolated from Dendrobium nobile and is an antagonist of β-alanine, taurine and of presynaptic inhibition in the frog spinal cord.

Definition

ChEBI: Dendrobine is a member of indoles.

in vivo

Dendrobine (25 mg/kg, ip for 14 days) exhibits antitumor efficacy in A549 xenograft mouse models[2].
Dendrobine (20 mg/kg, po for 20 days) ameliorates gestational diabetes mellitus (GDM) in mouse models[5].

Animal Model:A549 xenograft BALB/c mouse models[2]
Dosage:25 mg/kg
Administration:ip for 14 days
Result:Inhibited tumor growth.
Animal Model:GDM mouse models[5]
Dosage:20 mg/kg
Administration:po for 20 days
Result:Improved glucose and insulin tolerance, reduced Th17 cells in the spleen of GDM mice.

References

[1] CHUN-WANG MENG. Picrotoxane sesquiterpenoids from the stems of Dendrobium nobile and their absolute configurations and angiogenesis effect[J]. Fitoterapia, 2017, 121: Pages 206-211. DOI: 10.1016/j.fitote.2017.07.017
[2] TIAN-HE SONG . Dendrobine targeting JNK stress signaling to sensitize chemotoxicity of cisplatin against non-small cell lung cancer cells in vitro and in vivo[J]. Phytomedicine, 2019, 53: Pages 18-27. DOI: 10.1016/j.phymed.2018.06.018

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