Vanillin acetate
Vanillin acetate Basic information
- Product Name:
- Vanillin acetate
- Synonyms:
-
- 4-Acetoxy-m-anisaldehyde 4-Acetoxy-3-methoxybenzaldehyde
- Vanillin acetat
- Vanillin acetate SynonyMs 4-Acetoxy-3-Methoxybenzaldehyde
- (4-methanoyl-2-methoxy-phenyl) ethanoate
- 4-(Acetyloxy)-3-methoxybenzaldehyde
- 3-Methoxy-4-acetoxybenzaldehyde(Vanillinacetat,AcetylVanillin)
- Vanillin ace
- vanillyl acetate
- CAS:
- 881-68-5
- MF:
- C10H10O4
- MW:
- 194.18
- EINECS:
- 212-920-1
- Product Categories:
-
- Aldehydes
- Building Blocks
- C10 to C11
- C10-C12
- Carbonyl Compounds
- Chemical Synthesis
- Aromatic Aldehydes & Derivatives (substituted)
- Esters
- Organic Building Blocks
- Inhibitors
- Mol File:
- 881-68-5.mol
Vanillin acetate Chemical Properties
- Melting point:
- 77-79 °C (lit.)
- Boiling point:
- 288.5±25.0 °C(Predicted)
- Density
- 1.193±0.06 g/cm3(Predicted)
- FEMA
- 3108 | VANILLIN ACETATE
- storage temp.
- Refrigerator
- solubility
- Chloroform, DCM, Ethyl Acetate
- form
- Crystalline Powder
- color
- Beige
- Odor
- at 100.00 %. sweet creamy vanilla powdery heliotropin
- Odor Type
- vanilla
- biological source
- synthetic
- Water Solubility
- Very slightly soluble in water
- Sensitive
- Air Sensitive
- JECFA Number
- 890
- BRN
- 1963795
- LogP
- 1.10
- CAS DataBase Reference
- 881-68-5(CAS DataBase Reference)
- NIST Chemistry Reference
- Benzaldehyde, 4-(acetyloxy)-3-methoxy-(881-68-5)
- EPA Substance Registry System
- Benzaldehyde, 4-(acetyloxy)-3-methoxy- (881-68-5)
Safety Information
- Hazard Codes
- Xi
- Risk Statements
- 36/37/38
- Safety Statements
- 26-37-24/25
- WGK Germany
- 3
- TSCA
- Yes
- HazardClass
- IRRITANT
- HS Code
- 29124990
MSDS
- Language:English Provider:SigmaAldrich
- Language:English Provider:ALFA
Vanillin acetate Usage And Synthesis
Chemical Properties
Beige crystalline powder
Chemical Properties
Colorless needle-like or plate-like crystals. M.P. 77° c. Vanillin acetate has a mild, balsamic, floral odor with a nonvanillin flavor. Poorly soluble in water, soluble in alcohol and oils,
Occurrence
Reported found in shoyu (fermented soya hydrolysate).
Uses
Vanillin acetate has been used in preparation of:
- 2-nitrohomovanillic acid
- 2-nitrovanildin acetate
- 2-nitro-3,4-duimethoxybenzaldehyde
Uses
Vanillin Acetate is a synthetic flavoring agent that is moderately stable, white to yellow crystals of vanilla odor. it should be stored in glass or polyethylene-lined containers. it is used in flavors for vanilla note, with application in beverages, ice cream, candy, and baked goods at 11–28 ppm.
Definition
ChEBI: An acetate ester obtained by the formal condensation of phenolic group of vanillin with acetic acid.
Application
Vanillin acetate is used in spice flavor blends and in Vanilla flavor compositions as a modifier for Vanillin and related derivatives. lt tends to reduce the overall power of the flavor, but also improve the total picture in "freshening-up" the heavy aroma of Vanillin, Ethylvanillin, etc.
Preparation
By acetylation of vanillin or by oxidation of isoeugenyl acetate with chromic acid in the presence of sulfanilic acid; also by electrolytic reduction of vanillin, followed by acetylation of vanillyl alcohol.
Taste threshold values
Taste characteristics at 40 ppm: sweet, vanilla, creamy and powdery with a balsamic nuance.
General Description
Chemoselective reduction of vanillin acetate using sodium borohydride has been reported.
Synthesis
Vanillin acetate is synthesized by Vanillin by electrolytic reduction, followed by Acetylation of the Vanillyl alcohol.
Solubility in organics
Soluble in alcohoi and oils
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Vanillin acetate(881-68-5)Related Product Information
- p-Anisidine
- Isopropyl acetate
- 3-Methoxybenzaldehyde
- 4-(Trifluoromethoxy)aniline
- Ethyl acetate
- Benzyl acetate
- 3-Methoxysalicylaldehyde
- Cellulose acetate
- Anisole
- 2,6-Dimethoxybenzaldehyde
- o-Anisaldehyde
- 4-Methoxybenzylchloride
- Sodium acetate
- Vanillin
- Vinyl acetate
- Magnesium acetate
- p-Anisaldehyde
- Ammonium acetate