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3-Amino-2-methylbenzyl alcohol

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3-Amino-2-methylbenzyl alcohol Basic information

Product Name:
3-Amino-2-methylbenzyl alcohol
Synonyms:
  • 3-AMINO-2-METHYLBENZYL ALCOHOL
  • 3-Amino-2-methylbenzyl alcohol 97%
  • (3-Amino-2-methylphenyl)
  • Oct-7-enylamine
  • (3-amino-2-methylphenyl)methanol
  • Benzenemethanol, 3-amino-2-methyl-
  • 3-Amino-2-methylbenzyl alcohol USP/EP/BP
  • (3-Amino-2-methylphenyl)methanol - [A89288]
CAS:
83647-42-1
MF:
C8H11NO
MW:
137.18
Product Categories:
  • Benzhydrols, Benzyl & Special Alcohols
  • Amino Alcohols
  • Organic Building Blocks
  • Oxygen Compounds
Mol File:
83647-42-1.mol
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3-Amino-2-methylbenzyl alcohol Chemical Properties

Melting point:
106-108 °C (lit.)
Boiling point:
300.8±27.0 °C(Predicted)
Density 
1.126±0.06 g/cm3(Predicted)
storage temp. 
Keep in dark place,Sealed in dry,Room Temperature
form 
Powder
pka
14.53±0.10(Predicted)
color 
Off-white to light orange/purple
InChI
1S/C8H11NO/c1-6-7(5-10)3-2-4-8(6)9/h2-4,10H,5,9H2,1H3
InChIKey
UVYZMJMDIMWDNJ-UHFFFAOYSA-N
SMILES
Cc1c(N)cccc1CO
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Safety Information

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
26-37/39
WGK Germany 
3
Storage Class
11 - Combustible Solids
Hazard Classifications
Eye Irrit. 2
Skin Irrit. 2
STOT SE 3

MSDS

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3-Amino-2-methylbenzyl alcohol Usage And Synthesis

Uses

3-Amino-2-methylbenzyl alcohol may be used in chemical synthesis.

Synthesis

To a stirred solution of (2-methyl-3-nitro-phenyl)-methanol (13) (100 mg, 0.598 mmol) in EtOH (5 mL) and water (1 mL) was added powdered iron (183 mg, 3.29 mmol) and ammonium chloride (22 mg, 0.419 mmol), and the resultant mixture was refluxed for 2 hours. The reaction mixture was then brought to room temperature and filtered through a bed of diatomite. The filtrate was diluted with EtOAc, washed with water, dried over sodium sulfate and concentrated under reduced pressure to give 3-amino-2-methylbenzenemethanol (70 mg, 85%) as a yellow gel.

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