2-Methoxy-5-methylaniline
2-Methoxy-5-methylaniline Basic information
- Product Name:
- 2-Methoxy-5-methylaniline
- Synonyms:
-
- 2-Amino-4-methylphenolmethylether
- 2-Amino-p-cresol methyl ether
- 2-Amino-p-cresolmethylether
- m-amino-p-cresol,methylester
- meta-amino-para-cresol,methylether
- NCI-C02982
- o-Anisidine, 5-methyl-
- o-anisidine,5-methyl-(8ci)
- CAS:
- 120-71-8
- MF:
- C8H11NO
- MW:
- 137.18
- EINECS:
- 204-419-1
- Product Categories:
-
- Anilines, Aromatic Amines and Nitro Compounds
- Intermediates of Dyes and Pigments
- Mol File:
- 120-71-8.mol
2-Methoxy-5-methylaniline Chemical Properties
- Melting point:
- 50-52 °C (lit.)
- Boiling point:
- 235 °C (lit.)
- Density
- 1.0252 (rough estimate)
- vapor density
- 4.7 (vs air)
- refractive index
- 1.5647 (estimate)
- Flash point:
- >230 °F
- storage temp.
- Room Temperature, under inert atmosphere
- solubility
- Chloroform (Slightly), Ethyl Acetate, Methanol (Slightly)
- form
- Crystalline Chunks
- pka
- 4.66±0.10(Predicted)
- color
- Brown to black
- Water Solubility
- Slightly soluble in hot water.
- BRN
- 637071
- Stability:
- Air Sensitive
- InChIKey
- WXWCDTXEKCVRRO-UHFFFAOYSA-N
- CAS DataBase Reference
- 120-71-8(CAS DataBase Reference)
- NIST Chemistry Reference
- Benzenamine, 2-methoxy-5-methyl-(120-71-8)
- IARC
- 2B (Vol. 27, Sup 7) 1987
- EPA Substance Registry System
- p-Cresidine (120-71-8)
Safety Information
- Hazard Codes
- T,Xi
- Risk Statements
- 45-22
- Safety Statements
- 53-45
- WGK Germany
- 3
- RTECS
- BZ6720000
- F
- 9
- HazardClass
- IRRITANT
- HS Code
- 29222990
- Hazardous Substances Data
- 120-71-8(Hazardous Substances Data)
MSDS
- Language:English Provider:2-Methoxy-5-methylaniline
- Language:English Provider:SigmaAldrich
- Language:English Provider:ACROS
2-Methoxy-5-methylaniline Usage And Synthesis
Chemical Properties
brown to black crystalline chunks
Chemical Properties
p-Cresidine is a white crystalline solid.
Uses
p-Cresidine is a reagent used in the preparation of enaminones acting as anticonvulsants. Also used in the preparation of crescent oligoamides. Dyes and metabolites, Environmental Testing.
Uses
2-Methoxy-5-methylaniline was used in the synthesis of 4-(4-Amino-5-methoxy-2-methylphenylazo)-5-hydroxy-naphthalene-2,7-disulfonic acid. 2-Methoxy-5-methylaniline was used to analyse the application of polymeric ionic liquids as selective solid-phase microextraction sorbent coatings for the analysis of genotoxic impurities and structurally alerting compounds such as alkyl halides and aromatics. 2-Methoxy-5-methylaniline was used in a study to develop a sensitive analytical method for the determination of aromatic amines found in commercial hair dyes using high liquid chromatography coupled to an electrochemical detector by using the ionic liquid 1-butyl-3-methylimidazolium bis(trifluoromethanesulfonyl)imide in the mobile phase.
Uses
p-Cresidine is a reagent used in the preparation of enaminones acting as anticonvulsants. Also used in the preparation of crescent oligoamides.
General Description
White to silver-gray odorless crystals.
Air & Water Reactions
Insoluble in water.
Reactivity Profile
2-Methoxy-5-methylaniline is sensitive to moisture and temperatures greater than 104°F. Incompatible with strong oxidizing agents .
Hazard
A possible carcinogen.
Fire Hazard
2-Methoxy-5-methylaniline is nonflammable.
Safety Profile
Confirmed carcinogen with experimental carcinogenic and neoplastigenic data. Moderately toxic by ingestion. A skin and eye irritant. Mutation data reported. When heated to decomposition it emits toxic fumes of NOx. See also ESTERS.
Potential Exposure
p-Cresidine is used as an intermediate in the production of various azodyes, printing inks, and pigments; including 11 dyes that are produced commercially in the United States. Human exposure to p-Cresidine occurs primarily through inhalation of
Carcinogenicity
p-Cresidine is reasonably anticipated to be a human carcinogen based on sufficient evidence of carcinogenicity from studies in experimental animals.
Shipping
UN2811 Toxic solids, organic, n.o.s., Hazard Class: 6.1; Labels: 6.1-Poisonous materials, Technical Name Required
Incompatibilities
Incompatible with oxidizers (chlorates, nitrates, peroxides, permanganates, perchlorates, chlorine, bromine, fluorine, etc.); contact may cause fires or explosions. Keep away from alkaline materials, strong bases, strong acids, oxoacids, epoxides.
2-Methoxy-5-methylaniline Preparation Products And Raw materials
Raw materials
Preparation Products
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2-Methoxy-5-methylaniline(120-71-8)Related Product Information
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