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3-Fluoro-4-methoxyacetophenone

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3-Fluoro-4-methoxyacetophenone Basic information

Product Name:
3-Fluoro-4-methoxyacetophenone
Synonyms:
  • BUTTPARK 153\33-60
  • 3'-FLUORO-4'-METHOXYACETOPHENONE
  • 3'-FLUORO-4-METHOXYACETOPHENONE
  • 3-FLUORO-4-METHOXYACETOPHENONE
  • 1-(3-FLUORO-4-METHOXY-PHENYL)-ETHANONE
  • 1-(3-FLUORO-4-METHOXYPHENYL)-1-ETHANONE
  • 3’-Fluoro-4’-methyoxyacetophenone
  • Ethanone, 1-(3-fluoro-4-methoxyphenyl)-
CAS:
455-91-4
MF:
C9H9FO2
MW:
168.16
EINECS:
207-253-8
Product Categories:
  • Fluorine series
  • Adehydes, Acetals & Ketones
  • Anisoles, Alkyloxy Compounds & Phenylacetates
  • Fluorine Compounds
  • C9
  • Carbonyl Compounds
  • Aromatic Acetophenones & Derivatives (substituted)
  • ketone
  • Ketones
Mol File:
455-91-4.mol
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3-Fluoro-4-methoxyacetophenone Chemical Properties

Melting point:
92-94 °C(lit.)
Boiling point:
147-148 °C20 mm Hg(lit.)
Density 
1.1410 (estimate)
Flash point:
147-148°C/20mm
storage temp. 
Sealed in dry,Room Temperature
form 
powder to crystal
color 
White to Almost white
BRN 
2084062
CAS DataBase Reference
455-91-4(CAS DataBase Reference)
NIST Chemistry Reference
Acetophenone, 3'-fluoro-4'-methoxy-(455-91-4)
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Safety Information

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
26-37/39-36
WGK Germany 
3
HazardClass 
IRRITANT
HS Code 
2914790090

MSDS

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3-Fluoro-4-methoxyacetophenone Usage And Synthesis

Uses

3’-Fluoro-4’methoxyacetophenone is used in the synthesis chalcones,

Preparation

Obtained by fluorination of 4-methoxyacetophenone with manganese (IV) tetrafluoride formed in situ using manganese (IV) dioxide and pyridinium polyhydrogenofluoride under very mild conditions.

General Description

3′-Fluoro-4′-methoxyacetophenone can be prepared by Friedel-Crafts reaction of o-fluoroanisole with acetic anhydride.

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