SINIGRIN MONOHYDRATE Chemical Properties

Melting point:

128 (dec.)(lit.)

storage temp. 

Hygroscopic, -20°C Freezer, Under inert atmosphere

solubility 

DMSO (Slightly), Methanol (Slightly), Water (Slightly)

form 

Solid

color 

White to Off-White

Stability:

Hygroscopic

InChIKey

IUBVMJHASFBYGW-VEAGVKSPNA-M

SMILES

[C@H]1(S/C(/CC=C)=N/OS([O-])(=O)=O)[C@H](O)[C@H]([C@H](O)[C@@H](CO)O1)O.O.[K+] |&1:0,12,14,15,17,r|

Safety Information

Safety Statements 

24/25

WGK Germany 

3

RTECS 

LZ5778000

MSDS

• Language:English Provider:SigmaAldrich
• Language:English Provider:ACROS

SINIGRIN MONOHYDRATE Usage And Synthesis

Chemical Properties

white fine crystalline powder

Uses

Sinigrin (hydrate) is a natural aliphatic glucosinolate present in plants of the Brassicaceae family. Sinigrin (hydrate) exhibits anti-cancer, antibacterial, antifungal, antioxidant and anti-inflammatory activities[1].

Purification Methods

Purify sinigrin by recrystallising it three times from EtOH and once from MeOH. The tetraacetate has m 193-195o, [] D 20 -16o (c 0.14, H2O). [Benn et al. J Chem Soc, Chem Commun 445 1965, Kjaer et al. Acta Chem Scand 10 432 1956, Marsh et al. Acta Cryst (Sect B ) 26 1030 1970.] It is a -D-thioglucopyranoside substrate for thiogluconidase [MacLeod & Rossiter Phytochem 25 1047 1986]. [Beilstein 31 H 476, 17 III/IV 3738.]

References

[1] Mazumder A, et, al. Sinigrin and Its Therapeutic Benefits. Molecules. 2016 Mar 29;21(4):416. DOI:10.3390/molecules21040416

SINIGRIN MONOHYDRATE(64550-88-5)Related Product Information

• 1-Octacosanol
• TRANS-11-OCTADECENOIC ACID
• Sinapine thiocyanate
• 4-Hydroxy-3,5-dimethoxycinnamic acid
• Linolenic acid
• Valeric acid
• GLUCOTROPAEOLIN
• gamma-Linolenic acid
• METHYL LINOLENATE
• MONOMYRISTIN
• Brassicasterol
• LINOLENIC ACID ETHYL ESTER
• SINIGRIN MONOHYDRATE
• SINIGRIN
• Hydroxylamine-O-sulfonic acid
• ETHYL BETA-D-THIOGLUCOSIDE
• METHYL-BETA-D-THIOGLUCOPYRANOSIDE
• DESULFOSINIGRIN