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Ethyl myristate

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Ethyl myristate Basic information

Product Name:
Ethyl myristate
Synonyms:
  • Ethyl ester of tetradecanoic acid
  • Ethyl N-tetradecanoate
  • TETRADECANOIC ACID ETHYL ESTER
  • MYRISTIC ACID ETHYL ESTER
  • Ethylmyristat
  • ETHYL MYRISTATE, NATURAL
  • Ethyl tetradecanoate, Myristic acid ethyl ester
  • ETHYL TETRADECANOATE
CAS:
124-06-1
MF:
C16H32O2
MW:
256.42
EINECS:
204-675-4
Product Categories:
  • C12 to C63
  • Building Blocks
  • Carbonyl Compounds
  • Chemical Synthesis
  • Esters
  • Organic Building Blocks
  • Fatty Acid Derivatives & Lipids
  • Heterobifunctional PEGs
  • Materials Science
  • Nutrition Research
  • Phytochemicals by Plant (Food/Spice/Herb)
  • Poly(ethylene glycol) and Poly(ethylene oxide)
  • Polymer Science
  • Zingiber officinale (Ginger)
  • Glycerols
  • 124-06-1
Mol File:
124-06-1.mol
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Ethyl myristate Chemical Properties

Melting point:
11-12 °C(lit.)
Boiling point:
178-180 °C12 mm Hg(lit.)
Density 
0.86 g/mL at 25 °C(lit.)
refractive index 
n20/D 1.436(lit.)
FEMA 
2445 | ETHYL MYRISTATE
Flash point:
>230 °F
storage temp. 
Sealed in dry,Room Temperature
solubility 
Chloroform (Slightly), Methanol (Slightly)
form 
Liquid, Solidifying In The Cold
color 
Clear colorless
Odor
at 100.00 %. sweet waxy violet orris
Odor Type
waxy
Water Solubility 
Not miscible or difficult to mix with water.
Merck 
14,6333
JECFA Number
38
BRN 
1776382
LogP
7.09
CAS DataBase Reference
124-06-1(CAS DataBase Reference)
NIST Chemistry Reference
Tetradecanoic acid, ethyl ester(124-06-1)
EPA Substance Registry System
Tetradecanoic acid, ethyl ester (124-06-1)
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Safety Information

Safety Statements 
24/25
WGK Germany 
2
TSCA 
Yes
HS Code 
29189900

MSDS

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Ethyl myristate Usage And Synthesis

Description

Myristic acid is a saturated fatty acid commonly found in animal and vegetable fats that is frequently used in cosmetics, soaps, perfumes, and flavorings. It increases low density lipoprotein cholesterol making it one of the most hypercholesterolemic of the saturated fatty acids. Myristic acid ethyl ester (Ethyl myristate) is a more hydrophobic form of the free acid. It is a marker of excessive ethanol consumption that can be isolated from the hair of an individual.

Chemical Properties

Clear colorless liquid, solidifying in the cold

Chemical Properties

Ethyl myristate has a mild, waxy, soapy odor reminiscent of orris.

Occurrence

Reported found in apricot, grape, pear, capsicum, beef, beer, rum, tea, guava, Vitis vinifera, ginger, Gruyere cheese, blue cheese, boiled mutton, cognac, whiskey, sparkling wine, cocoa, coconut meat, mango, corn oil, elderberry and mastic gum leaf oil.

Uses

Ethyl myristate may be used as an analytical standard for the determination of the analyte as an alcohol biomarker in dried blood spots and hair samples by chromatography based techniques. Ethyl myristate may also be used as an analytical standard in the determination of the analyte in selected beer flavors by stir bar sorptive extraction and solvent back extraction.

Uses

Ethyl myristate is a labeled component from essential oil of natural hawthorn perfume. It is also frequently used in cosmetics, soaps, and flavorings.

Preparation

By esterification of the acid with ethyl alcohol in the presence of gaseous HCl.

Definition

ChEBI: A long-chain fatty acid ethyl ester resulting from the formal condensation of the carboxy group of myristic acid with the hydroxy group of ethanol.

Aroma threshold values

Detection: 4 ppm

Taste threshold values

Taste characteristics at 60 ppm: sweet, waxy and creamy.

General Description

Ethyl myristate is a fatty acid ethyl ester (FAEE) that can be formed in the body due to non-oxidative metabolism of ethanol. It also occurs in vegetable oils. Ethyl myristate, along with other FAEEs are used as alcohol markers in hair.

Safety Profile

Combustible liquid. When heated to decomposition it emits acrid smoke and irritating fumes.

Ethyl myristate Preparation Products And Raw materials

Raw materials

Ethyl myristateSupplier

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