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1,1'-Bis(diisopropylphosphino)ferrocene

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1,1'-Bis(diisopropylphosphino)ferrocene Basic information

Product Name:
1,1'-Bis(diisopropylphosphino)ferrocene
Synonyms:
  • BIS[(DIISOPROPYLPHOSPHINO)CYCLOPENTADIENYL]IRON
  • 1,1'-BIS(DI-I-PROPYLPHOSPHINO)FERROCENE
  • 1,1'-BIS(DIISOPROPYLPHOSPHINO)FERROCENE
  • -BIS(DIISOPROPYLPHOSPHINO)FERROCENE
  • 1,1'-Bis(di-i-propylphosphino)ferrocene, min. 98%
  • 1,1'-Bis(diisopropylphosphino)ferrocene,98%
  • 1,1'-Bis(di-i-propylphosphino)ferrocene,min.98%
  • 1,1'-Bis[bis(1-methylethyl)phosphino]ferrocene
CAS:
97239-80-0
MF:
C22H36FeP210*
MW:
418.31
EINECS:
677-500-6
Product Categories:
  • Achiral Phosphine
  • Aryl Phosphine
  • Ligand
  • Ferrocenes
  • Metallocenes
  • Phosphine Ligands
  • Synthetic Organic Chemistry
  • Catalysis and Inorganic Chemistry
  • Phosphorus Compounds
  • Polydentate Phosphine Ligands
Mol File:
97239-80-0.mol
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1,1'-Bis(diisopropylphosphino)ferrocene Chemical Properties

Melting point:
50-52 °C(lit.)
Flash point:
>230 °F
storage temp. 
under inert gas (nitrogen or Argon) at 2-8°C
form 
Powder
color 
orange-yellow
Water Solubility 
Insoluble in water.
InChI
InChI=1S/2C11H18P.Fe/c2*1-9(2)12(10(3)4)11-7-5-6-8-11;/h2*5-10H,1-4H3;
InChIKey
LPBBEMRSRONKMN-UHFFFAOYSA-N
SMILES
P(C(C)C)(C(C)C)[C]1[CH][CH][CH][CH]1.P(C(C)C)(C(C)C)[C]1[CH][CH][CH][CH]1.[Fe] |^1:7,8,9,10,11,19,20,21,22,23|
CAS DataBase Reference
97239-80-0(CAS DataBase Reference)
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Safety Information

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
37/39-26
WGK Germany 
3
TSCA 
No
HS Code 
29319090

MSDS

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1,1'-Bis(diisopropylphosphino)ferrocene Usage And Synthesis

Reaction

  1. Ruthenium- catalyzed hydrohydroxyalkylation of 1,1-disubstituted allenes
  2. Ligand for palladium-catalyzed aminocarbonylation of Pyridyl Tosylates by means of ex situ generation of CO.
  3. Pd-catalyzed carbonylative ɑ-arylation of ketones with aryl iodides
  4. Ligand for palladium-catalyzed alkoxycarbonylation of aryl bromides for the preparation of tertiary esters
  5. Ligand for stereoselective palladium-catalyzed decarboxylative allylation ß-C-glycosylation
  6. Ligand for ruthenium-catalyzed C—C coupling reactions of fluorinated alcohols with allenes.
  7. Ligand for cobalt-catalyzed intermolecular formal hydroacylation reaction of olefins using N-3-picolin-2-yl aldimines as aldehyde equivalents.





Chemical Properties

orange crystalline powder

Uses

The general and efficient cross-coupling of thiols with aryl halides was developed utilizing Pd(OAc) 2 /1,1?-bis(diisopropylphosphino)ferrocene as the catalyst. The oxidative electrochemistry of dippf was examined, and it was found to follow an ECDim mechanism. Seven new compounds containing dippf were prepared and characterized spectroscopically. The crystal structures of [MCl2(dippf)] (M = Pt and Zn) were determined.

1,1'-Bis(diisopropylphosphino)ferrocene Preparation Products And Raw materials

Raw materials

n-ButyllithiumHexaneN,N,N',N'-TetramethylethylenediamineFerroceneCHLORODIISOPROPYLPHOSPHINE

1,1'-Bis(diisopropylphosphino)ferroceneSupplier

Shaanxi Rock New Materials Co., Ltd. Gold
Tel
0917-8888777, 3380777,18691786767; 15619786767
Email
xuya@bjrock.com
Henan Research New Material Co., Ltd. Gold
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1890-3931531 18903931628
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sales036@researchvip.com
BeiJing Greenchem Technology Co.,Ltd. Gold
Tel
131-21959385 15640741633
Email
chemrocking@bjgreenchem.com
Xinxiang Runyu Material Co., Ltd. Gold
Tel
166-166-37336996 15690792173
Email
chenxi.song@runvmat.com
J & K SCIENTIFIC LTD.
Tel
010-82848833 400-666-7788
Email
jkinfo@jkchemical.com
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