ChemicalBook > Product Catalog > Chemical Reagents > Organic reagents > Phosphine ligand > 1,1'-Bis(diisopropylphosphino)ferrocene
1,1'-Bis(diisopropylphosphino)ferrocene
1,1'-Bis(diisopropylphosphino)ferrocene Basic information
- Product Name:
- 1,1'-Bis(diisopropylphosphino)ferrocene
- Synonyms:
-
- BIS[(DIISOPROPYLPHOSPHINO)CYCLOPENTADIENYL]IRON
- 1,1'-BIS(DIISOPROPYLPHOSPHINO)FERROCENE
- -BIS(DIISOPROPYLPHOSPHINO)FERROCENE
- 1,1'-Bis(di-i-propylphosphino)ferrocene, min. 98%
- 1,1'-Bis(diisopropylphosphino)ferrocene,98%
- 1,1'-Bis(di-i-propylphosphino)ferrocene,min.98%
- 1,1'-Bis[bis(1-methylethyl)phosphino]ferrocene
- Ferrocene,1,1'-bis[bis(1-Methylethyl)phosphino]-
- CAS:
- 97239-80-0
- MF:
- C22H36FeP210*
- MW:
- 418.31
- EINECS:
- 677-500-6
- Product Categories:
-
- Achiral Phosphine
- Aryl Phosphine
- Ligand
- Ferrocenes
- Metallocenes
- Phosphine Ligands
- Synthetic Organic Chemistry
- Catalysis and Inorganic Chemistry
- Phosphorus Compounds
- Polydentate Phosphine Ligands
- Mol File:
- 97239-80-0.mol
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1,1'-Bis(diisopropylphosphino)ferrocene Chemical Properties
- Melting point:
- 50-52 °C(lit.)
- Flash point:
- >230 °F
- storage temp.
- under inert gas (nitrogen or Argon) at 2-8°C
- form
- Powder
- color
- orange-yellow
- Water Solubility
- Insoluble in water.
- InChI
- InChI=1S/2C11H18P.Fe/c2*1-9(2)12(10(3)4)11-7-5-6-8-11;/h2*5-10H,1-4H3;
- InChIKey
- LPBBEMRSRONKMN-UHFFFAOYSA-N
- SMILES
- P(C(C)C)(C(C)C)[C]1[CH][CH][CH][CH]1.P(C(C)C)(C(C)C)[C]1[CH][CH][CH][CH]1.[Fe] |^1:7,8,9,10,11,19,20,21,22,23|
- CAS DataBase Reference
- 97239-80-0(CAS DataBase Reference)
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MSDS
- Language:English Provider:SigmaAldrich
- Language:English Provider:ACROS
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1,1'-Bis(diisopropylphosphino)ferrocene Usage And Synthesis
Reaction
- Ruthenium- catalyzed hydrohydroxyalkylation of 1,1-disubstituted allenes
- Ligand for palladium-catalyzed aminocarbonylation of Pyridyl Tosylates by means of ex situ generation of CO.
- Pd-catalyzed carbonylative ɑ-arylation of ketones with aryl iodides
- Ligand for palladium-catalyzed alkoxycarbonylation of aryl bromides for the preparation of tertiary esters
- Ligand for stereoselective palladium-catalyzed decarboxylative allylation ß-C-glycosylation
- Ligand for ruthenium-catalyzed C—C coupling reactions of fluorinated alcohols with allenes.
- Ligand for cobalt-catalyzed intermolecular formal hydroacylation reaction of olefins using N-3-picolin-2-yl aldimines as aldehyde equivalents.
Description
1,1′-Bis(diisopropylphosphino)ferrocene (DiPPF) is a ferrocene-based phosphine ligand frequently is used in electrochemical reaction studies. DiPPF can help support high oxidation states of metal atoms by forming iron interactions and donating electrons via low-energy charge transfer from iron to nickel atoms.
Chemical Properties
orange crystalline powder
Uses
The general and efficient cross-coupling of thiols with aryl halides was developed utilizing Pd(OAc) 2 /1,1?-bis(diisopropylphosphino)ferrocene as the catalyst. The oxidative electrochemistry of dippf was examined, and it was found to follow an ECDim mechanism. Seven new compounds containing dippf were prepared and characterized spectroscopically. The crystal structures of [MCl2(dippf)] (M = Pt and Zn) were determined.
reaction suitability
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: ligand
1,1'-Bis(diisopropylphosphino)ferrocene Preparation Products And Raw materials
Raw materials
1,1'-Bis(diisopropylphosphino)ferroceneSupplier
Shaanxi Rock New Materials Co., Ltd. Gold
- Tel
- 0917-8888777, 3380777,18691786767; 15619786767
- xuya@bjrock.com
Henan Research New Material Co., Ltd. Gold
- Tel
- 1890-3931531 18903931628
- sales036@researchvip.com
BeiJing Greenchem Technology Co.,Ltd. Gold
- Tel
- 131-21959385 18804271668
- chemrocking@bjgreenchem.com
Xinxiang Runyu Material Co., Ltd. Gold
- Tel
- 166-166-37336996 15690792173
- chenxi.song@runvmat.com
J & K SCIENTIFIC LTD.
- Tel
- 18210857532; 18210857532
- jkinfo@jkchemical.com
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1,1'-Bis(diisopropylphosphino)ferrocene(97239-80-0)Related Product Information
- 1,1'-Bis(di-tert-butylphosphino)ferrocene
- 1,1'-BIS(DICYCLOHEXYLPHOSPHINO)FERROCENE
- 1,2,3,4,5-PENTAPHENYL-1'-(DI-TERT-BUTYLPHOSPHINO)FERROCENE
- 1,1'-Bis(diphenylphosphino)ferrocene
- Ferrocene
- 1,1'-Bis (di-t-butylphosphino)ferrocene palladium dichloride,
- 1,1'-BIS(DI-I-PROPYLPHOSPHINO)FERROCENE(1,5-CYCLOOCTADIENE)RHODIUM (I) TETRAFLUOROBORATE
- 1,1'-BIS(DIISOPROPYLPHOSPHINO)FERROCENE
- (ALPHAR,ALPHAR)-1,1'-BIS[ALPHA-(DIMETHYLAMINO)BENZYL]-(S,S)-2,2'-BIS(DICYCLOHEXYLPHOSPHINO)FERROCENE
- 1,1-Bis[(2S,3S,4S,5S)-2,5-dimethyl-3,4-O-isopropylidene-3,4-dihydroxyphospholanyl]ferrocene
- 1,1μ-Bis[(2S,5S)-2,5-diisopropylphospholano]ferrocene
- S,S-Me-FerrocelaneTM
- 1,1μ-Bis(diisopropylphosphino)ferrocene(cod)Rh-phosphotungstic acid on alumox
- (ALPHAS,ALPHAS)-1,1'-BIS[ALPHA-(DIMETHYLAMINO)BENZYL]-(R,R)-2,2'-BIS(DICYCLOHEXYLPHOSPHINO)FERROCENE
- 1,1-BIS(DIISOPROPYLPHOSPHINO)FERROCENE(COD)RH-PHOSPHOTUNGSTIC ACID
- 1,1μ-Bis[(2R,5R)-2,5-diisopropylphospholano]ferrocene
- 1,1'-BIS[(2R,5R)-2,5-DIMETHYLPHOSPHOLANO]FERROCENE