1,1'-Bis(di-tert-butylphosphino)ferrocene Chemical Properties

Melting point:

181-182°C (dec.)

storage temp. 

Inert atmosphere,Room Temperature

form 

crystal

color 

orange to red

Water Solubility 

Insoluble in water.

InChI

InChI=1S/2C13H22P.Fe/c2*1-12(2,3)14(13(4,5)6)11-9-7-8-10-11;/h2*7-10H,1-6H3;

InChIKey

FPLSJBJGQLJLSV-UHFFFAOYSA-N

SMILES

P(C(C)(C)C)(C(C)(C)C)[C]1[CH][CH][CH][CH]1.P(C(C)(C)C)(C(C)(C)C)[C]1[CH][CH][CH][CH]1.[Fe] |^1:9,10,11,12,13,23,24,25,26,27|

Safety Information

Hazard Codes 

Xi

Risk Statements 

36/37/38

Safety Statements 

22-24/25-36/37/39-26

WGK Germany 

3

TSCA 

No

HS Code 

29319090

MSDS

• Language:English Provider:ALFA

1,1'-Bis(di-tert-butylphosphino)ferrocene Usage And Synthesis

Reaction

1. Ligand for synthesis of polycyclic indoles via Pd-catalyzed intramolecular heteroannulation.
2. Ligand for the palladium-catalyzed intramolecular arylation of aryl bromides under mild conditions.
3. Ligand for cross-coupling reactions between bromoarenes and potassium allyltrifluoroborates promoted by a catalyst prepared from Pd(OAc)2 and DTBPF selectively providing γ-coupling products.
4. Ligand for the copper-catalyzed system for the ß-boration of of a variety of α,ß-unsaturated amides.
5. Ligand for the synthesis of Paucifloral F and related indanone analogues via palladium-catalyzed α-arylation.
6. Ligand for the Pd-carbon monoxide complex catalyzed hydroxycarbonylation of aryl halides.
7. Ligand for the palladium-catalyzed β-C-glycosylation by decarboxylative allylation to normal pyran systems,and cis-2,6-disubstituted tetrahydropyrans.
8. Pd-catalyzed dearomative indole bisfunctionalization via a diastereoselective arylcyanation.
9. Ligand for the copper- DTBPF catalyzed C–H activation and carboxylation of terminal alkynes.

1,1'-Bis(di-tert-butylphosphino)ferrocene(84680-95-5)Related Product Information

• 1,1'-BIS(DICYCLOHEXYLPHOSPHINO)FERROCENE
• 1,2,3,4,5-PENTAPHENYL-1'-(DI-TERT-BUTYLPHOSPHINO)FERROCENE
• 1,1'-Bis(diphenylphosphino)ferrocene
• 1,1'-BIS(DIISOPROPYLPHOSPHINO)FERROCENE
• TERT-BUTYLDIISOPROPYLPHOSPHINE
• 1,1'-Bis(di-tert-butylphosphino)ferrocene
• Ferrocene
• T-BUTYLPHOSPHINE
• 1,1''-BIS(DI-TERT-BUTYLPHOSPHINO)FERROCENE PALLADIUM DICHLORI
• 1,1'-BIS(DI-TERT-BUTYLPHOSPHINO)FERROCENE PALLADIUM DICHLORIDE
• DI-T-BUTYL(I-PROPYL)PHOSPHINE
• 1,1'-Bis (di-t-butylphosphino)ferrocene palladium dichloride,
• Di-tert-butylphosphine
• TRIISOPROPYLPHOSPHINE