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ChemicalBook >  Product Catalog >  Organic Chemistry >  Phosphines >  1,1'-Bis(di-tert-butylphosphino)ferrocene

1,1'-Bis(di-tert-butylphosphino)ferrocene

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1,1'-Bis(di-tert-butylphosphino)ferrocene Basic information

Product Name:
1,1'-Bis(di-tert-butylphosphino)ferrocene
Synonyms:
  • BIS[(DI-TERT-BUTYLPHOSPHINO)CYCLOPENTADIENYL]IRON
  • 1,1'-Bis(di-t-butylphosphino)ferrocene,min.98%
  • 1,1'-BIS(DI-T-BUTYLPHOSPHINO)FERROCENE
  • 1,1'-BIS(DI-TERT-BUTYLPHOSPHINO)FERROCENE
  • 1,1'-Bis(di-tert-butylphosphino)ferrocene,min. 98%
  • 1,1'-Bis(di-tert-butylphosphino)ferrocene ,98%
  • 1,1'-Bis(di-tert-butylphosphin
  • 98% DtBPF
CAS:
84680-95-5
MF:
C26H44FeP210*
MW:
474.42
EINECS:
626-167-5
Product Categories:
  • Achiral Phosphine
  • Aryl Phosphine
  • Classes of Metal Compounds
  • Fe (Iron) Compounds
  • Ferrocenes
  • Metallocenes
  • Phosphine Ligands
  • Synthetic Organic Chemistry
  • Transition Metal Compounds
  • Catalysis and Inorganic Chemistry
  • Phosphorus Compounds
  • Polydentate Phosphine Ligands
Mol File:
84680-95-5.mol
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1,1'-Bis(di-tert-butylphosphino)ferrocene Chemical Properties

Melting point:
181-182°C (dec.)
storage temp. 
Inert atmosphere,Room Temperature
form 
crystal
color 
orange to red
Water Solubility 
Insoluble in water.
InChIKey
FPLSJBJGQLJLSV-UHFFFAOYSA-N
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Safety Information

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
22-24/25-36/37/39-26
WGK Germany 
3
TSCA 
No
HS Code 
29319090

MSDS

  • Language:English Provider:ALFA
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1,1'-Bis(di-tert-butylphosphino)ferrocene Usage And Synthesis

Reaction

  1. Ligand for synthesis of polycyclic indoles via Pd-catalyzed intramolecular heteroannulation.
  2. Ligand for the palladium-catalyzed intramolecular arylation of aryl bromides under mild conditions.
  3. Ligand for cross-coupling reactions between bromoarenes and potassium allyltrifluoroborates promoted by a catalyst prepared from Pd(OAc)2 and DTBPF selectively providing γ-coupling products.
  4. Ligand for the copper-catalyzed system for the ß-boration of of a variety of α,ß-unsaturated amides.
  5. Ligand for the synthesis of Paucifloral F and related indanone analogues via palladium-catalyzed α-arylation.
  6. Ligand for the Pd-carbon monoxide complex catalyzed hydroxycarbonylation of aryl halides.
  7. Ligand for the palladium-catalyzed β-C-glycosylation by decarboxylative allylation to normal pyran systems,and cis-2,6-disubstituted tetrahydropyrans.
  8. Pd-catalyzed dearomative indole bisfunctionalization via a diastereoselective arylcyanation.
  9. Ligand for the copper- DTBPF catalyzed C–H activation and carboxylation of terminal alkynes.

Uses

1,1'-BIS(DI-TERT-BUTYLPHOSPHINO)FERROCENE is an organophosphine compound and can be used as an organometallic ligand.

Uses

The rate of palladium-catalyzed amination of unactivated aryl chlorides is accelerated by sterically hindered chelating alkyl phosphines, ie, 1,1'-bis(di-tert-butylphosphino)ferrocene.

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