N-(9-Fluorenylmethoxycarbonyloxy)succinimide CAS#: 82911-69-1

ChemicalBook > Product Catalog > Biochemical Engineering > Amino Acids and Derivatives > Other Amino Acid Protection > N-(9-Fluorenylmethoxycarbonyloxy)succinimide

N-(9-Fluorenylmethoxycarbonyloxy)succinimide

Basic information Safety Supplier Related

N-(9-Fluorenylmethoxycarbonyloxy)succinimide Basic information

Product Name:

N-(9-Fluorenylmethoxycarbonyloxy)succinimide

Synonyms:

1-[[(9h-fluoren-9-ylmethoxy)carbonyl]oxy]-5-pyrrolidinedione
9-fluorenylmethoxycarbonyloxysuccinimide
9-fluorenylmethyl-n-succinimide carbonate
N-(9-FluorenylmethoxyCarbonyloxy)Succinimide9-Fluorenylmethylsuccinimidylcarbonate
CARBONIC ACID 2,5-DIOXO-PYRROLIDIN-1-YL ESTER 9H-FLUOREN-9-YLMETHYL ESTER
CARBONIC ACID FLUORENYLMETHYL SUCCIN-N-YL-ESTER
FMOC-OSU
FMOC-ONSU

CAS:

82911-69-1

MF:

C19H15NO5

MW:

337.33

EINECS:

433-520-5

Product Categories:

Fmoc-OSU
peptides
Medical Intermediates
Benzocycles
Fluorenes, Flurenones
Pyrrolidines
Amino Acid Derivatives
N-Protecting Reagents
Biochemistry
Condensation & Active Esterification
Fluorenes
Fluorenes & Fluorenones
Heterocycles
Miscellaneous Reagents
N-Substituted Maleimides, Succinimides & Phthalimides
N-Substituted Succinimides
Peptide Synthesis
Protective Reagents (Peptide Synthesis)
Synthetic Organic Chemistry
Fmoc-Amino acid series
bc0001

Mol File:

82911-69-1.mol

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N-(9-Fluorenylmethoxycarbonyloxy)succinimide Chemical Properties

Melting point:: 150-153 °C(lit.)
Boiling point:: 150-153°C
Density: 1.3460 (rough estimate)
refractive index: 1.5000 (estimate)
storage temp.: 2-8°C
solubility: Soluble in dimethyl sulfoxide and dimethyl formamide.
form: Microfine Powder
color: White or almost white
Sensitive: Moisture Sensitive
BRN: 3569540
Stability:: Moisture Sensitive
CAS DataBase Reference: 82911-69-1(CAS DataBase Reference)

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Safety Information

Hazard Codes: Xi,N,Xn
Risk Statements: 36/37/38-51/53-43-22
Safety Statements: 22-24/25-26/37/39-26-61-37-24
RIDADR: UN 3077 9 / PGIII
WGK Germany: 3
F: 10-21
Hazard Note: Moisture Sensitive
HazardClass: 9
HS Code: 29251995

MSDS

Language:English Provider:SigmaAldrich
Language:English Provider:ACROS
Language:English Provider:ALFA

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N-(9-Fluorenylmethoxycarbonyloxy)succinimide Usage And Synthesis

Chemical Properties

White powder

Uses

N-protecting reagent for oligonucleotide and peptide syntheses

Uses

Reagent for the preparation of pure Fmoc amino acids free from contamination by Fmoc-dipeptides.

Uses

N-(9-Fluorenylmethoxycarbonyloxy)succinimide is used in conjunction with Isothiocyanate to conduct partial Edman Degradation on biologically active peptides.

Purification Methods

Recrystallise the carbonate from CHCl3/Et2O, or from pet ether (b 40-60o). [Pauet Can J Chem 60 976 1982, Lapatsaris et al. Synthesis 671 1983.]

N-(9-Fluorenylmethoxycarbonyloxy)succinimide Preparation Products And Raw materials

Preparation Products

[2-[2-(Fmoc-amino)ethoxy]ethoxy]acetic acid

N-(9-Fluorenylmethoxycarbonyloxy)succinimideSupplier

Suzhou Highfine Biotech Co., Ltd Gold

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Hubei Jingxiang Technology Co., Ltd. Gold

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Shanghai GL Peptide Ltd. Gold

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Shanghai Hanhong Scientific Co.,Ltd. Gold

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GL Biochem (Shanghai) Ltd Gold

Tel: 21-61263452 13641803416
Email: ymbetter@glbiochem.com

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