ChemicalBook > CAS DataBase List > 6-Bromo-2-methylquinoline

6-Bromo-2-methylquinoline

Product Name
6-Bromo-2-methylquinoline
CAS No.
877-42-9
Chemical Name
6-Bromo-2-methylquinoline
Synonyms
6-BROMOQUINALDINE;6-Bromo-2-methyL;6-BROMOQUINAIDINE;6-Bromoquildine, 98%;6-BROMO-2-METHYLQUINOLINE;Quinoline, 6-bromo-2-methyl-;6-Bromo-2-methylquinoline >6-BroMo-2-Methylquinoline, 97+%;6-Bromo-2-methylquinoline, 97%, OS-2039;6-Bromo-2-methylquinoline ISO 9001：2015 REACH
CBNumber
CB0156824
Molecular Formula
C10H8BrN
Formula Weight
222.08
MOL File
877-42-9.mol
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6-Bromo-2-methylquinoline Property

Melting point:
101-105 °C (lit.)
Boiling point:
299.7±20.0 °C(Predicted)
Density 
1.488±0.06 g/cm3(Predicted)
storage temp. 
Sealed in dry,Room Temperature
solubility 
soluble in Methanol
pka
5.02±0.43(Predicted)
form 
solid
color 
Grey
InChIKey
SQRYQSKJZVQJAY-UHFFFAOYSA-N
CAS DataBase Reference
877-42-9(CAS DataBase Reference)
NIST Chemistry Reference
6-Bromoquinaldine(877-42-9)
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Safety

Hazard Codes 
Xn,Xi
Risk Statements 
22-37/38-42-36/37/38-20/21/22
Safety Statements 
26-39-36/37/39-24/25-22
WGK Germany 
3
Hazard Note 
Irritant
HS Code 
29339900
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H302Harmful if swallowed

H315Causes skin irritation

H317May cause an allergic skin reaction

H318Causes serious eye damage

H334May cause allergy or asthma symptoms or breathing difficulties if inhaled

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P342+P311IF experiencing respiratory symptoms: call a POISON CENTER or doctor/physician.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
649279
Product name
6-Bromo-2-methylquinoline
Purity
97%
Packaging
5g
Price
$38.4
Updated
2025/07/31
Sigma-Aldrich
Product number
649279
Product name
6-Bromo-2-methylquinoline
Purity
97%
Packaging
25g
Price
$148
Updated
2024/03/01
TCI Chemical
Product number
B3039
Product name
6-Bromo-2-methylquinoline
Purity
>98.0%(GC)(T)
Packaging
5g
Price
$90
Updated
2025/07/31
TCI Chemical
Product number
B3039
Product name
6-Bromo-2-methylquinoline
Purity
>98.0%(GC)(T)
Packaging
25g
Price
$293
Updated
2025/07/31
TRC
Product number
B697693
Product name
6-Bromo-2-methylquinoline
Packaging
1g
Price
$60
Updated
2021/12/16
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6-Bromo-2-methylquinoline Chemical Properties,Usage,Production

Chemical Properties

white to light yellow crystal powder

Synthesis

106-40-1

123-73-9

877-42-9

GENERAL METHOD: 4-Bromoaniline (1.50 mmol) and trans-2-butenal (1.00 mmol) were dissolved in 1.5 mL of ether (Et2O) in a reaction flask fitted with a magnetic stir bar, followed by the addition of silver(I)-exchanged montmorillonite K10 (0.50 g). After stirring for 5 min, the solvent was removed under vacuum to obtain a dry powder. The reaction mixture was heated at 120 °C for 3 hours. After the reaction mixture was cooled to room temperature, it was filtered through a short silica gel plug and the solid residue was washed well with dichloromethane (CH2Cl2). After removal of the solvent under vacuum, the crude product was purified by silica gel column chromatography, eluting using a solvent mixture of hexane/ethyl acetate (EtOAc) to give the final 6-bromo-2-methylquinoline (3a-3k). Note: For recycling/reuse studies, the crude product is separated by gravity filtration and the clay material is washed several times with dichloromethane (CH2Cl2), air-dried and weighed. The process is repeated for successive recycling/reuse reactions.

References

[1] Advanced Functional Materials, 2012, vol. 22, # 2, p. 345 - 352
[2] Heterocycles, 2016, vol. 92, # 12, p. 2213 - 2224
[3] Tetrahedron Letters, 2011, vol. 52, # 22, p. 2840 - 2843
[4] Chemical Communications, 2012, vol. 48, # 35, p. 4196 - 4198
[5] Dalton Transactions, 2012, vol. 41, # 20, p. 6189 - 6194

6-Bromo-2-methylquinoline Preparation Products And Raw materials

Raw materials

Preparation Products

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6-Bromo-2-methylquinoline Suppliers

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View Lastest Price from 6-Bromo-2-methylquinoline manufacturers

R&D Scientific Inc.
Product
6-Bromo-2-methylquinoline 877-42-9
Price
US $1250.00/g
Min. Order
1g
Purity
98
Supply Ability
500 Kg
Release date
2024-02-19
Henan Bao Enluo International TradeCo.，LTD
Product
6-Bromo-2-methylquinoline 877-42-9
Price
US $10.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
500t/month
Release date
2023-08-17
Hebei Zhanyao Biotechnology Co. Ltd
Product
6-Bromo-2-methylquinoline 877-42-9
Price
US $10.00/Kg/Bag
Min. Order
1KG
Purity
99%
Supply Ability
20 tons
Release date
2021-10-12

877-42-9, 6-Bromo-2-methylquinolineRelated Search:

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