6-Bromo-2-methylquinoline
- Product Name
- 6-Bromo-2-methylquinoline
- CAS No.
- 877-42-9
- Chemical Name
- 6-Bromo-2-methylquinoline
- Synonyms
- 6-BROMOQUINALDINE;6-Bromo-2-methyL;6-BROMOQUINAIDINE;6-Bromoquildine, 98%;6-BROMO-2-METHYLQUINOLINE;Quinoline, 6-bromo-2-methyl-;6-Bromo-2-methylquinoline >6-BroMo-2-Methylquinoline, 97+%;6-Bromo-2-methylquinoline, 97%, OS-2039;6-Bromo-2-methylquinoline ISO 9001：2015 REACH
- CBNumber
- CB0156824
- Molecular Formula
- C10H8BrN
- Formula Weight
- 222.08
- MOL File
- 877-42-9.mol
6-Bromo-2-methylquinoline Property
- Melting point:
- 101-105 °C (lit.)
- Boiling point:
- 299.7±20.0 °C(Predicted)
- Density
- 1.488±0.06 g/cm3(Predicted)
- storage temp.
- Sealed in dry,Room Temperature
- solubility
- soluble in Methanol
- pka
- 5.02±0.43(Predicted)
- form
- solid
- color
- Grey
- InChIKey
- SQRYQSKJZVQJAY-UHFFFAOYSA-N
- CAS DataBase Reference
- 877-42-9(CAS DataBase Reference)
- NIST Chemistry Reference
- 6-Bromoquinaldine(877-42-9)
Safety
- Hazard Codes
- Xn,Xi
- Risk Statements
- 22-37/38-42-36/37/38-20/21/22
- Safety Statements
- 26-39-36/37/39-24/25-22
- WGK Germany
- 3
- Hazard Note
- Irritant
- HS Code
- 29339900
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Danger
- Hazard statements
-
H302Harmful if swallowed
H315Causes skin irritation
H317May cause an allergic skin reaction
H318Causes serious eye damage
H334May cause allergy or asthma symptoms or breathing difficulties if inhaled
H335May cause respiratory irritation
- Precautionary statements
-
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P342+P311IF experiencing respiratory symptoms: call a POISON CENTER or doctor/physician.
N-Bromosuccinimide Price
- Product number
- 649279
- Product name
- 6-Bromo-2-methylquinoline
- Purity
- 97%
- Packaging
- 5g
- Price
- $38.4
- Updated
- 2025/07/31
- Product number
- 649279
- Product name
- 6-Bromo-2-methylquinoline
- Purity
- 97%
- Packaging
- 25g
- Price
- $148
- Updated
- 2024/03/01
- Product number
- B3039
- Product name
- 6-Bromo-2-methylquinoline
- Purity
- >98.0%(GC)(T)
- Packaging
- 5g
- Price
- $90
- Updated
- 2025/07/31
- Product number
- B3039
- Product name
- 6-Bromo-2-methylquinoline
- Purity
- >98.0%(GC)(T)
- Packaging
- 25g
- Price
- $293
- Updated
- 2025/07/31
- Product number
- B697693
- Product name
- 6-Bromo-2-methylquinoline
- Packaging
- 1g
- Price
- $60
- Updated
- 2021/12/16
6-Bromo-2-methylquinoline Chemical Properties,Usage,Production
Chemical Properties
white to light yellow crystal powder
Synthesis
106-40-1
123-73-9
877-42-9
GENERAL METHOD: 4-Bromoaniline (1.50 mmol) and trans-2-butenal (1.00 mmol) were dissolved in 1.5 mL of ether (Et2O) in a reaction flask fitted with a magnetic stir bar, followed by the addition of silver(I)-exchanged montmorillonite K10 (0.50 g). After stirring for 5 min, the solvent was removed under vacuum to obtain a dry powder. The reaction mixture was heated at 120 °C for 3 hours. After the reaction mixture was cooled to room temperature, it was filtered through a short silica gel plug and the solid residue was washed well with dichloromethane (CH2Cl2). After removal of the solvent under vacuum, the crude product was purified by silica gel column chromatography, eluting using a solvent mixture of hexane/ethyl acetate (EtOAc) to give the final 6-bromo-2-methylquinoline (3a-3k). Note: For recycling/reuse studies, the crude product is separated by gravity filtration and the clay material is washed several times with dichloromethane (CH2Cl2), air-dried and weighed. The process is repeated for successive recycling/reuse reactions.
References
[1] Advanced Functional Materials, 2012, vol. 22, # 2, p. 345 - 352
[2] Heterocycles, 2016, vol. 92, # 12, p. 2213 - 2224
[3] Tetrahedron Letters, 2011, vol. 52, # 22, p. 2840 - 2843
[4] Chemical Communications, 2012, vol. 48, # 35, p. 4196 - 4198
[5] Dalton Transactions, 2012, vol. 41, # 20, p. 6189 - 6194
6-Bromo-2-methylquinoline Preparation Products And Raw materials
Raw materials
Preparation Products
6-Bromo-2-methylquinoline Suppliers
- Tel
- +49 3493/605464
- Fax
- +49 3493/605470
- sales@intatrade.de
- Country
- Germany
- ProdList
- 3572
- Advantage
- 66
- Tel
- --
- Fax
- --
- sales@chemos-group.com
- Country
- Germany
- ProdList
- 6350
- Advantage
- 71
- Tel
- --
- Fax
- --
- info@abcr.de
- Country
- Germany
- ProdList
- 6831
- Advantage
- 75
View Lastest Price from 6-Bromo-2-methylquinoline manufacturers
- Product
- 6-Bromo-2-methylquinoline 877-42-9
- Price
- US $1250.00/g
- Min. Order
- 1g
- Purity
- 98
- Supply Ability
- 500 Kg
- Release date
- 2024-02-19
- Product
- 6-Bromo-2-methylquinoline 877-42-9
- Price
- US $10.00/kg
- Min. Order
- 1kg
- Purity
- 99%
- Supply Ability
- 500t/month
- Release date
- 2023-08-17
- Product
- 6-Bromo-2-methylquinoline 877-42-9
- Price
- US $10.00/Kg/Bag
- Min. Order
- 1KG
- Purity
- 99%
- Supply Ability
- 20 tons
- Release date
- 2021-10-12