1,3,5-Trifluoro-2,4,6-triiodobenzene
- Product Name
- 1,3,5-Trifluoro-2,4,6-triiodobenzene
- CAS No.
- 84322-56-5
- Chemical Name
- 1,3,5-Trifluoro-2,4,6-triiodobenzene
- Synonyms
- 1,3,5-Trifluoro-2,4;1,3,5-Trifluoro-2,4,6-Triiodob;1,3,5-TRIFLUORO-2,4,6-TRIIODOBENZENE;1,3,5-TRILFLUORO-2,4,6-TRIIODOBENZENE;Benzene,1,3,5-trifluoro-2,4,6-triiodo-
- CBNumber
- CB0180452
- Molecular Formula
- C6F3I3
- Formula Weight
- 509.77
- MOL File
- 84322-56-5.mol
1,3,5-Trifluoro-2,4,6-triiodobenzene Property
- Melting point:
- 152℃
- Boiling point:
- 352.4±37.0 °C(Predicted)
- Density
- 3.029±0.06 g/cm3(Predicted)
- storage temp.
- 2-8°C(protect from light)
- form
- Solid
- Appearance
- Off-white to light brown Solid
- Water Solubility
- Slightly soluble in water.
- Sensitive
- Light Sensitive
- InChI
- InChI=1S/C6F3I3/c7-1-4(10)2(8)6(12)3(9)5(1)11
- InChIKey
- NTAZOPPTLZSXQH-UHFFFAOYSA-N
- SMILES
- C1(F)=C(I)C(F)=C(I)C(F)=C1I
- CAS DataBase Reference
- 84322-56-5(CAS DataBase Reference)
Safety
- Hazard Codes
- Xi
- HazardClass
- IRRITANT
- HS Code
- 2903998090
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H315Causes skin irritation
H319Causes serious eye irritation
H335May cause respiratory irritation
- Precautionary statements
-
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P405Store locked up.
N-Bromosuccinimide Price
- Product number
- T895660
- Product name
- 1,3,5-Trifluoro-2,4,6-triiodobenzene
- Packaging
- 50mg
- Price
- $45
- Updated
- 2021/12/16
- Product number
- 1600-J-X0
- Product name
- 1,3,5-Trifluoro-2,4,6-triiodobenzene
- Packaging
- 5G
- Price
- $65
- Updated
- 2021/12/16
- Product number
- AK-87133
- Product name
- 1,3,5-Trifluoro-2,4,6-triiodobenzene
- Purity
- 98%
- Packaging
- 10g
- Price
- $70
- Updated
- 2021/12/16
- Product number
- PC1493
- Product name
- 1,3,5-Trifluoro-2,4,6-triiodobenzene
- Packaging
- 1g
- Price
- $73
- Updated
- 2021/12/16
- Product number
- J53616
- Product name
- 1,3,5-Trifluoro-2,4,6-triiodobenzene
- Packaging
- 5g
- Price
- $80
- Updated
- 2021/12/16
1,3,5-Trifluoro-2,4,6-triiodobenzene Chemical Properties,Usage,Production
Uses
1,3,5-Trifluoro-2,4,6-triiodobenzene is useful for biological applications. Further, it is used as an intermediate in organic synthesis.
Synthesis
372-38-3
84322-56-5
The general procedure for the synthesis of 1,3,5-trifluoro-2,4,6-triiodobenzene from 1,3,5-trifluorobenzene was as follows: potassium iodide (KI, 7.14 g, 43.56 mmol) was slowly added to a stirring mixture of periodate (3.30 g, 14.50 mmol) and concentrated sulfuric acid (20 mL) at 0 °C. The resulting dark-colored mixture was cooled in an ice bath while 1,3,5-trifluorobenzene (1.0 mL, 9.68 mmol) was added dropwise over 25 min. Subsequently, the reaction mixture was heated to 70 °C and maintained at this temperature for 4 hours. After completion of the reaction, the mixture was cooled to room temperature and poured into ice water. Extraction was carried out with ether (3 x 50 mL) and the organic phases were combined. The organic phase was washed sequentially with saturated aqueous sodium bicarbonate (NaHCO3), aqueous sodium thiosulfate (Na2S2O3) and distilled water, and then dried with anhydrous sodium sulfate (Na2SO4). After evaporation to remove the solvent, the pure white powdery product 1,3,5-trifluoro-2,4,6-triiodobenzene was obtained in 80% yield. The product was characterized as follows: 19F NMR (CDCl3, 235MHz): δ-69.90ppm; melting point: 158-159°C; FT-IR (KBr pressed sheet, cm-1): 1561, 1401, 1325, 1048, 704, 652.
References
[1] Chemistry - A European Journal, 2018, vol. 24, # 56, p. 15003 - 15012
[2] European Journal of Organic Chemistry, 2002, # 23, p. 3927 - 3935
[3] Chemical Communications, 2008, # 14, p. 1635 - 1637
[4] Chemical Communications, 2017, vol. 53, # 69, p. 9590 - 9593
[5] Molecules, 2017, vol. 22, # 12,
1,3,5-Trifluoro-2,4,6-triiodobenzene Preparation Products And Raw materials
Raw materials
Preparation Products
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View Lastest Price from 1,3,5-Trifluoro-2,4,6-triiodobenzene manufacturers
- Product
- 1,3,5-Trifluoro-2,4,6-triiodobenzene 84322-56-5
- Price
- US $0.00-0.00/KG
- Min. Order
- 1KG
- Purity
- 98%
- Supply Ability
- 2000
- Release date
- 2025-04-17
- Product
- 1,3,5-Trifluoro-2,4,6-triiodobenzene 84322-56-5
- Price
- US $15.00-10.00/KG
- Min. Order
- 1KG
- Purity
- 99%+ HPLC
- Supply Ability
- Monthly supply of 1 ton
- Release date
- 2021-08-11
- Product
- 1,3,5-Trifluoro-2,4,6-triiodobenzene 84322-56-5
- Price
- US $1.00/KG
- Min. Order
- 1KG
- Purity
- 98% HPLC
- Supply Ability
- 10 tons/month
- Release date
- 2020-01-08