ChemicalBook > CAS DataBase List > 4-Bromo-2-methylbenzoic acid

4-Bromo-2-methylbenzoic acid

Product Name
4-Bromo-2-methylbenzoic acid
CAS No.
68837-59-2
Chemical Name
4-Bromo-2-methylbenzoic acid
Synonyms
4-Bromo-2-methyL;Fluralaner-038;RARECHEM AL BO 0455;4-Bromo-2-methylbenz;4-Bromo-o-toluic acid;Fluralaner Impurity 58;4-Bromo-2-methylbenzoic;5-Bromo-2-carboxytoluene;4-Bromo-2-methylbenzoicaci;4-Brom-2-methylbenzoic acid
CBNumber
CB0188342
Molecular Formula
C8H7BrO2
Formula Weight
215.04
MOL File
68837-59-2.mol
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4-Bromo-2-methylbenzoic acid Property

Melting point:
180-184 °C
Boiling point:
310.1±30.0 °C(Predicted)
Density 
1.599±0.06 g/cm3(Predicted)
storage temp. 
Sealed in dry,Room Temperature
pka
3.63±0.25(Predicted)
form 
powder to crystal
color 
White to Almost white
Water Solubility 
Insoluble in water.
BRN 
2249816
InChI
InChI=1S/C8H7BrO2/c1-5-4-6(9)2-3-7(5)8(10)11/h2-4H,1H3,(H,10,11)
InChIKey
RVCJOGNLYVNRDN-UHFFFAOYSA-N
SMILES
C(O)(=O)C1=CC=C(Br)C=C1C
CAS DataBase Reference
68837-59-2(CAS DataBase Reference)
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Safety

Hazard Codes 
Xn,Xi
Risk Statements 
22-36/37/38
Safety Statements 
26-36/37/39-36
RIDADR 
UN 2811 6.1/PG 3
WGK Germany 
3
Hazard Note 
Harmful
HazardClass 
IRRITANT
PackingGroup 
Ⅲ
HS Code 
29163990
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

Precautionary statements

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P332+P313IF SKIN irritation occurs: Get medical advice/attention.

P337+P313IF eye irritation persists: Get medical advice/attention.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
665126
Product name
4-Bromo-2-methylbenzoic acid
Purity
97%
Packaging
5g
Price
$84
Updated
2023/06/20
Sigma-Aldrich
Product number
665126
Product name
4-Bromo-2-methylbenzoic acid
Purity
97%
Packaging
25g
Price
$268
Updated
2023/06/20
TCI Chemical
Product number
B3337
Product name
4-Bromo-2-methylbenzoic Acid
Purity
>98.0%(GC)(T)
Packaging
5g
Price
$129
Updated
2024/03/01
TCI Chemical
Product number
B3337
Product name
4-Bromo-2-methylbenzoic Acid
Purity
>98.0%(GC)(T)
Packaging
25g
Price
$643
Updated
2024/03/01
Alfa Aesar
Product number
L03071
Product name
4-Bromo-2-methylbenzoic acid, 98+%
Packaging
5g
Price
$73.65
Updated
2024/03/01
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4-Bromo-2-methylbenzoic acid Chemical Properties,Usage,Production

Chemical Properties

White to brown crystal powde

Uses

A building block which is used in preparation of anthranilic acids possessing antibacterial activity. 4-bromo-2-methylbenzoic acid could be used to synthesis 4-chloro-3'-(2-cyclopentyl-1-oxoisoindolin-5-yl)biphenyl-3-carboxylic acid through Suzuki couplings[1].

References

[1] Shyama Sidique. “Orally Active Metabotropic Glutamate Subtype 2 Receptor Positive Allosteric Modulators: Structure–Activity Relationships and Assessment in a Rat Model of Nicotine Dependence.” Journal of Medicinal Chemistry 55 22 (2012): 9434–9445.

4-Bromo-2-methylbenzoic acid Preparation Products And Raw materials

Raw materials

Preparation Products

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4-Bromo-2-methylbenzoic acid Suppliers

Americas 1 China 305 Europe 3 Germany 6 India 41 Japan 2 Switzerland 2 United Kingdom 9 United States 30 Global 399
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View Lastest Price from 4-Bromo-2-methylbenzoic acid manufacturers

Hebei Zhuanglai Chemical Trading Co Ltd
Product
4-Bromo-2-methylbenzoic acid 68837-59-2
Price
US $10.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
20 ton
Release date
2024-11-27
WUHAN FORTUNA CHEMICAL CO., LTD
Product
4-Bromo-2-methylbenzoic acid 68837-59-2
Price
US $0.00/Kg/Bag
Min. Order
1KG
Purity
98%min
Supply Ability
500KGS
Release date
2021-07-02
Suzhou Nordica Biopharma CO.,LTD
Product
4-bromo-2-methylbenzoic acid 68837-59-2
Price
US $0.00-0.00/kg
Min. Order
0.005kg
Purity
0.98
Supply Ability
2 tons
Release date
2024-11-15

68837-59-2, 4-Bromo-2-methylbenzoic acidRelated Search:

Methyl 2-bromobenzoate 3-BROMO-2-METHYLBENZOIC ACID 3-(Trifluoromethyl)benzoic acid m-Toluic acid 3-Bromoanisole p-Toluic acid o-Toluic acid 4-Bromobenzoic acid Methyl 4-(bromomethyl)benzoate 4-Bromomethylbenzoic acid 4-BROMO-3-METHYLBENZOIC ACID 2-BROMO-3-METHYLBENZOIC ACID 4-Bromoanisole 4-BROMOCINNAMIC ACID Methyl 4-methylbenzoate bis(2-ethylhexyl) tetrabromophthalate 4-HYDROXY-2-METHYLBENZOIC ACID 98 3-Amino-4-methylbenzoic acid

  • RARECHEM AL BO 0455
  • 2-METHYL-4-BROMOBENZOIC ACID
  • 4-BROMO-2-METHYLBENZOIC ACID
  • 4-Bromo-o-toluic acid
  • 4-Bromo-2-methylbenzoic acid, 98+%
  • 4-Bromo-2-Methylbenzoic Acid 2-Methyl-4-Bromobenzoic Acid
  • 4-Bromo-2-methyL
  • 4-Bromo-2-methylbenz
  • 5-Bromo-2-carboxytoluene
  • 4-BroMo-2-Methylbenzoic Acid, 97+%
  • 4-Brom-2-methylbenzoic acid
  • Benzoicacid, 4-bromo-2-methyl-
  • 5-Bromo-2-carboxytoluene, 4-Bromo-o-toluic acid
  • 4-Bromo-2-methylbenzoic Acid &gt
  • 4-Bromo-2-methylbenzoicaci
  • 4-Bromo-2-methylbenzoic
  • Fluralaner-038
  • 4-bromo-2-methylbezoic acid
  • Fluralaner Impurity 58
  • 68837-59-2
  • 68838-59-2
  • Building Blocks
  • C8
  • Carbonyl Compounds
  • Carboxylic Acids
  • Organic Building Blocks
  • C8
  • Carbonyl Compounds
  • Carboxylic Acids
  • Aromatic Carboxylic Acids, Amides, Anilides, Anhydrides & Salts
  • Benzoic acid
  • bc0001