ChemicalBook > CAS DataBase List > 3-Bromobenzoic acid

3-Bromobenzoic acid

Product Name
3-Bromobenzoic acid
CAS No.
585-76-2
Chemical Name
3-Bromobenzoic acid
Synonyms
QVR CE;NSC 83519;Brombenzoesaure;Brombenzoicacid;3-BROMBENZOIC ACID;3-bromo-benzoicaci;M-BROMOBENZOIC ACID;3-BroMobenzoic aicd;3-BROMOBENZOIC ACID;RARECHEM AL BO 0037
CBNumber
CB0441823
Molecular Formula
C7H5BrO2
Formula Weight
201.02
MOL File
585-76-2.mol
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3-Bromobenzoic acid Property

Melting point:
155-158 °C(lit.)
Boiling point:
>280 °C
Density 
1,948 g/cm3
refractive index 
1.6080 (estimate)
storage temp. 
Sealed in dry,Room Temperature
solubility 
methanol: soluble50mg/mL, clear, colorless
pka
3.86(at 25℃)
form 
Powder
color 
White to light beige
Water Solubility 
0.54 g/L (32 ºC)
BRN 
2041792
InChIKey
VOIZNVUXCQLQHS-UHFFFAOYSA-N
CAS DataBase Reference
585-76-2(CAS DataBase Reference)
NIST Chemistry Reference
Benzoic acid, 3-bromo-(585-76-2)
EPA Substance Registry System
m-Bromobenzoic acid (585-76-2)
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Safety

Hazard Codes 
Xi
Risk Statements 
36/37/38-37/38-36
Safety Statements 
26-36-37/39
WGK Germany 
3
Hazard Note 
Irritant
TSCA 
Yes
HS Code 
29163990
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
186295
Product name
3-Bromobenzoic acid
Purity
98%
Packaging
25g
Price
$64.4
Updated
2024/03/01
TCI Chemical
Product number
B0551
Product name
3-Bromobenzoic Acid
Purity
>98.0%(GC)(T)
Packaging
25g
Price
$57
Updated
2024/03/01
TCI Chemical
Product number
B0551
Product name
3-Bromobenzoic Acid
Purity
>98.0%(GC)(T)
Packaging
250g
Price
$317
Updated
2024/03/01
Alfa Aesar
Product number
A12606
Product name
3-Bromobenzoic acid, 98+%
Packaging
25g
Price
$52.65
Updated
2024/03/01
Alfa Aesar
Product number
A12606
Product name
3-Bromobenzoic acid, 98+%
Packaging
100g
Price
$186.65
Updated
2024/03/01
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3-Bromobenzoic acid Chemical Properties,Usage,Production

Chemical Properties

white to light yellow crystal powder. soluble in alcohols and ethers, insoluble in water.Used as organic synthesis reagent.

Uses

3-Bromobenzoic acid was used as test solute in the determination of acidity constants by capillary zone electrophoresis. It was used as internal standard to study the retention mechanisms of an unmodified and a hydroxylated polystyrene-divinylbenzene polymer by solid-phase extraction. It was also used in synthesis of N-(1,1-dimethyl-2-hydroxyethyl)-3-bromobenzamide.

Preparation

3-Bromobenzoic acid is synthesized from 3-bromotoluene by oxidation of potassium permanganate. Mix m-bromotoluene, potassium hydroxide and water, heat to boiling, slowly add potassium permanganate, and reflux for 4 hours after adding. After acidification by filtration, the crude product was obtained by filtration. Then it is dissolved in ethanol with ammonia water, acidified with hydrochloric acid, filtered and washed with water to obtain 3-bromobenzoic acid.

Definition

ChEBI: 3-bromobenzoic acid is a bromobenzoic acid carrying a single bromo subsituent at the 3-position.

Synthesis Reference(s)

The Journal of Organic Chemistry, 15, p. 481, 1950 DOI: 10.1021/jo01149a007

Purification Methods

Crystallise the acid from acetone/water, MeOH or acetic acid. The anilide has m 137o (from EtOH/H2O). [Beilstein 9 IV 1013.]

3-Bromobenzoic acid Preparation Products And Raw materials

Raw materials

Potassium permanganate 3-Bromotoluene

Preparation Products

3-PYRIDIN-4-YL-BENZOIC ACID 3-BROMO-2-((CYCLOPROPYLAMINO)METHYL)BENZALDEHYDE 6-BROMOISOBENZOFURAN-1(3H)-ONE ETHYL 3-BROMOBENZOATE
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3-Bromobenzoic acid Suppliers

Americas 1 Belgium 1 Canada 2 China 329 Europe 3 France 1 Germany 6 India 19 Japan 4 Slovakia 1 Switzerland 2 Ukraine 1 United Kingdom 14 United States 44 Global 428
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View Lastest Price from 3-Bromobenzoic acid manufacturers

Hebei Zhuanglai Chemical Trading Co.,Ltd
Product
3-Bromobenzoic acid 585-76-2
Price
US $180.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
20ton
Release date
2024-06-05
Zibo Hangyu Biotechnology Development Co., Ltd
Product
3-Bromobenzoic acid 585-76-2
Price
US $80.00-800.00/kg
Min. Order
10kg
Purity
0.99
Supply Ability
20tons
Release date
2023-11-08
Hebei Weibang Biotechnology Co., Ltd
Product
3-Bromobenzoic acid 585-76-2
Price
US $0.00-0.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
20 mt
Release date
2022-12-08

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  • C7H5BrO2
  • Carbonyl Compounds
  • Carboxylic Acids
  • C7
  • Building Blocks
  • Organic Building Blocks
  • Building Blocks
  • Carbonyl Compounds
  • Carboxylic Acids
  • Chemical Synthesis
  • Organic Building Blocks
  • alkyl bromide| carboxylic acid
  • Carboxylic Acids
  • blocks
  • Carboxes
  • Aromatic Carboxylic Acids, Amides, Anilides, Anhydrides & Salts
  • BenzoicAcidDerivative
  • Benzoic acid
  • Acids & Esters
  • Bromine Compounds
  • C7
  • Carbonyl Compounds
  • bc0001