Thianaphthene
- Product Name
- Thianaphthene
- CAS No.
- 95-15-8
- Chemical Name
- Thianaphthene
- Synonyms
- BENZO[B]THIOPHENE;BENZOTHIOPHENE;BBT;THIONAPHTHENE;BZT;1-BENZOTHIOPHENE;Thiaphthene;1-Thiaindene;Thianaphtene;Thianaphthen
- CBNumber
- CB0683988
- Molecular Formula
- C8H6S
- Formula Weight
- 134.2
- MOL File
- 95-15-8.mol
Thianaphthene Property
- Melting point:
- 30-33 °C
- Boiling point:
- 221-222 °C(lit.)
- Density
- 1.149 g/mL at 25 °C(lit.)
- refractive index
- 1.6332 (estimate)
- Flash point:
- >230 °F
- storage temp.
- Store below +30°C.
- solubility
- 0.13g/l
- form
- Crystalline Solid
- pka
- 32.4
- Specific Gravity
- 1.149
- color
- White to pink or yellow
- Water Solubility
- insoluble
- Merck
- 14,9303
- BRN
- 80580
- InChIKey
- FCEHBMOGCRZNNI-UHFFFAOYSA-N
- LogP
- 3.120
- CAS DataBase Reference
- 95-15-8(CAS DataBase Reference)
- NIST Chemistry Reference
- Benzo[b]thiophene(95-15-8)
- EPA Substance Registry System
- Benzo[b]thiophene (95-15-8)
Safety
- Hazard Codes
- Xn,Xi,N
- Risk Statements
- 22-36/37/38-20/21/22-51/53
- Safety Statements
- 22-24/25-36-26-61
- RIDADR
- UN3077
- WGK Germany
- 3
- Hazard Note
- Irritant
- TSCA
- Yes
- HazardClass
- 9
- PackingGroup
- III
- HS Code
- 29349990
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H302Harmful if swallowed
H412Harmful to aquatic life with long lasting effects
- Precautionary statements
-
P264Wash hands thoroughly after handling.
P264Wash skin thouroughly after handling.
P270Do not eat, drink or smoke when using this product.
P273Avoid release to the environment.
P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.
P501Dispose of contents/container to..…
N-Bromosuccinimide Price
- Product number
- 357790
- Product name
- Thianaphthene
- Purity
- 98%
- Packaging
- 5g
- Price
- $21.66
- Updated
- 2024/03/01
- Product number
- 357790
- Product name
- Thianaphthene
- Purity
- 98%
- Packaging
- 25g
- Price
- $86.2
- Updated
- 2024/03/01
- Product number
- B0093
- Product name
- Benzo[b]thiophene
- Purity
- >97.0%(GC)
- Packaging
- 5g
- Price
- $19
- Updated
- 2024/03/01
- Product number
- B0093
- Product name
- Benzo[b]thiophene
- Purity
- >97.0%(GC)
- Packaging
- 25g
- Price
- $54
- Updated
- 2024/03/01
- Product number
- A12328
- Product name
- Benzo[b]thiophene, 98+%
- Packaging
- 5g
- Price
- $31.65
- Updated
- 2024/03/01
Thianaphthene Chemical Properties,Usage,Production
Chemical Properties
WHITE TO RED CRYSTALLINE LOW MELTING SOLID
Uses
Benzo[b]thiophene has application in organic as well as pharmaceutical industry as a component in the synthesis of Raloxifene, a breast cancer therapeutic, or hydrodesulfurization reactions.
Uses
Benzo[b]thiophene is used in the preparation of 2-thianapthenylphenyllithium, via metalation by n-butyllithium. It is used in organic as well as pharmaceutical industry as a component in the synthesis of raloxifene, a breast cancer therapeutic, or hydrodesulfurization reactions.
Uses
Thianaphthene may be used in the preparation of 2-thianapthenylphenyllithium, via metalation by n-butyllithium.
Uses
manufacture of pharmaceuticals, thioindigo.
Definition
ChEBI: 1-benzothiophene is a benzothiophene and a member of 1-benzothiophenes.
Application
Thianaphthene may be used in the preparation of 2-thianapthenylphenyllithium, via metalation by n-butyllithium.
Reaction of ethyl diazoacetate with thianaphthene has been reported.
Synthesis Reference(s)
Journal of the American Chemical Society, 69, p. 2008, 1947 DOI: 10.1021/ja01200a053
Tetrahedron, 27, p. 1253, 1971 DOI: 10.1016/S0040-4020(01)90874-9
General Description
Reaction of ethyl diazoacetate with thianaphthene has been reported.
Purification Methods
1-Benzothiophene has the odour of naphthalene. If the IR spectrum is not very good, then suspend it in a faintly alkaline aqueous solution and steam distil it. Extract the distillate with Et2O, dry the extract (CaCl2), filter, evaporate the solvent and fractionate the residue. The distillate sets solid. The sulfoxide has m 142o, the picrate has m 148-149o (yellow crystals from EtOH) and the styphnate has m 136-137o. [Hansch & Lindwall J Org Chem 10, 381 1945, Meyer & Meyer Chem Ber 52B 1249 1919, Weisgerber & Kruber 53 1551 1920, Iddon & Scrowston Adv Heterocycl Chem 11 177 1970, Beilstein 17/2 V 6.]
Thianaphthene Preparation Products And Raw materials
Raw materials
Preparation Products
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View Lastest Price from Thianaphthene manufacturers
- Product
- thianaphthene 95-15-8
- Price
- US $0.00-0.00/Kg
- Min. Order
- 1Kg
- Purity
- 99.9%
- Supply Ability
- 200tons
- Release date
- 2024-04-08
- Product
- Thianaphthene 95-15-8
- Price
- US $50.00-1.00/KG
- Min. Order
- 1KG
- Purity
- 99%
- Supply Ability
- g-kg-tons, free sample is available
- Release date
- 2023-12-22
- Product
- Thianaphthene 95-15-8
- Price
- US $0.00/KG
- Min. Order
- 100g
- Purity
- 98%+
- Supply Ability
- 100kg
- Release date
- 2020-10-14