ChemicalBook > CAS DataBase List > Thianaphthene

Thianaphthene

Product Name
Thianaphthene
CAS No.
95-15-8
Chemical Name
Thianaphthene
Synonyms
BENZO[B]THIOPHENE;BENZOTHIOPHENE;BBT;THIONAPHTHENE;BZT;1-BENZOTHIOPHENE;Thiaphthene;ianaphthene;1-Thiaindene;Thianaphtene
CBNumber
CB0683988
Molecular Formula
C8H6S
Formula Weight
134.2
MOL File
95-15-8.mol
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Thianaphthene Property

Melting point:
30-33 °C
Boiling point:
221-222 °C(lit.)
Density 
1.149 g/mL at 25 °C(lit.)
vapor pressure 
1.33 hPa ( 20 °C)
refractive index 
1.6332 (estimate)
Flash point:
>230 °F
storage temp. 
Store below +30°C.
solubility 
0.13g/l
form 
Crystalline Solid
pka
32.4
Specific Gravity
1.149
color 
White to pink or yellow
Water Solubility 
insoluble
Merck 
14,9303
BRN 
80580
InChIKey
FCEHBMOGCRZNNI-UHFFFAOYSA-N
LogP
3.120
CAS DataBase Reference
95-15-8(CAS DataBase Reference)
NIST Chemistry Reference
Benzo[b]thiophene(95-15-8)
EPA Substance Registry System
Benzo[b]thiophene (95-15-8)
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Safety

Hazard Codes 
Xn,Xi,N
Risk Statements 
22-36/37/38-20/21/22-51/53
Safety Statements 
22-24/25-36-26-61
RIDADR 
UN3077
WGK Germany 
3
Autoignition Temperature
510°C
Hazard Note 
Irritant
TSCA 
Yes
HazardClass 
9
PackingGroup 
III
HS Code 
29349990
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H302Harmful if swallowed

H412Harmful to aquatic life with long lasting effects

Precautionary statements

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P270Do not eat, drink or smoke when using this product.

P273Avoid release to the environment.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

P501Dispose of contents/container to..…

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
357790
Product name
Thianaphthene
Purity
98%
Packaging
5g
Price
$21.66
Updated
2024/03/01
Sigma-Aldrich
Product number
357790
Product name
Thianaphthene
Purity
98%
Packaging
25g
Price
$86.2
Updated
2024/03/01
TCI Chemical
Product number
B0093
Product name
Benzo[b]thiophene
Purity
>97.0%(GC)
Packaging
5g
Price
$19
Updated
2024/03/01
TCI Chemical
Product number
B0093
Product name
Benzo[b]thiophene
Purity
>97.0%(GC)
Packaging
25g
Price
$54
Updated
2024/03/01
Alfa Aesar
Product number
A12328
Product name
Benzo[b]thiophene, 98+%
Packaging
5g
Price
$31.65
Updated
2024/03/01
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Thianaphthene Chemical Properties,Usage,Production

Chemical Properties

WHITE TO RED CRYSTALLINE LOW MELTING SOLID

Uses

Benzo[b]thiophene has application in organic as well as pharmaceutical industry as a component in the synthesis of Raloxifene, a breast cancer therapeutic, or hydrodesulfurization reactions.

Uses

Benzo[b]thiophene is used in the preparation of 2-thianapthenylphenyllithium, via metalation by n-butyllithium. It is used in organic as well as pharmaceutical industry as a component in the synthesis of raloxifene, a breast cancer therapeutic, or hydrodesulfurization reactions.

Uses

Thianaphthene may be used in the preparation of 2-thianapthenylphenyllithium, via metalation by n-butyllithium.

Uses

manufacture of pharmaceuticals, thioindigo.

Definition

ChEBI: 1-benzothiophene is a benzothiophene and a member of 1-benzothiophenes.

Application

Thianaphthene may be used in the preparation of 2-thianapthenylphenyllithium, via metalation by n-butyllithium.
Reaction of ethyl diazoacetate with thianaphthene has been reported.

Synthesis Reference(s)

Journal of the American Chemical Society, 69, p. 2008, 1947 DOI: 10.1021/ja01200a053
Tetrahedron, 27, p. 1253, 1971 DOI: 10.1016/S0040-4020(01)90874-9

General Description

Reaction of ethyl diazoacetate with thianaphthene has been reported.

Purification Methods

1-Benzothiophene has the odour of naphthalene. If the IR spectrum is not very good, then suspend it in a faintly alkaline aqueous solution and steam distil it. Extract the distillate with Et2O, dry the extract (CaCl2), filter, evaporate the solvent and fractionate the residue. The distillate sets solid. The sulfoxide has m 142o, the picrate has m 148-149o (yellow crystals from EtOH) and the styphnate has m 136-137o. [Hansch & Lindwall J Org Chem 10, 381 1945, Meyer & Meyer Chem Ber 52B 1249 1919, Weisgerber & Kruber 53 1551 1920, Iddon & Scrowston Adv Heterocycl Chem 11 177 1970, Beilstein 17/2 V 6.]

Thianaphthene Preparation Products And Raw materials

Raw materials

Ethyl acetoacetate Acetylacetone Tetrabutylammonium bromide Thiophenol Bromoacetaldehyde diethyl acetal Sodium borohydride Thiosalicylic acid Aluminum chloride Tetrahydrofuran Bromoacetic acid Methanol Sodium hydroxide Thionyl chloride Sulfuric acid

Preparation Products

1-Benzo[b]thiophen-3-yl-2-bromoethan-1-one 2-(HYDROXYMETHYL)BENZO[B]THIOPHENE Raloxifene 2-(1-HYDROXYLAMINOETHYL)-BENZOTHIOPHENE 2-Acetylbenzo[b]thiophene 1-BENZOTHIOPHENE-3-SULFONYL CHLORIDE BENZO[B]THIOPHENE-3-CARBONITRILE Benzothiophene-3-boronic acid 3-Acetylthianaphthene [2-[4-(dihexylamino)-2-methylbenzylidene]benzo[b]thien-3(2H)-ylidene]malononitrile S,S-dioxide METHYL BENZO[B]THIOPHENE-2-CARBOXYLATE Benzo[b]thien-2-ylboronic acid BENZO[B]THIOPHENE-2-CARBOXALDEHYDE 1-BENZOTHIOPHENE-2-SULFONYL CHLORIDE 1-Benzothiophene-3-carbaldehyde 1-Benzothiophene-3-carboxylic acid Sertaconazole nitrate THIANAPHTHENE-2-CARBOXAMIDE 3-Bromo-1-benzothiophene BENZO[B]THIOPHENE-3-ACETIC ACID Thianaphthene-2-carboxylic acid 1-BENZOTHIOPHENE-3-CARBONYL CHLORIDE BENZO[B]THIOPHENE-2-CARBONYL CHLORIDE
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View Lastest Price from Thianaphthene manufacturers

Hebei Zhuanglai Chemical Trading Co Ltd
Product
Thianaphthene 95-15-8
Price
US $10.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
20 ton
Release date
2024-12-12
Hebei Chuanghai Biotechnology Co., Ltd
Product
Thianaphthene 95-15-8
Price
US $10.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
10 mt
Release date
2024-11-19
Hebei Mujin Biotechnology Co.,Ltd
Product
Thianaphthene 95-15-8
Price
US $0.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
50000KG/month
Release date
2024-08-22

95-15-8, ThianaphtheneRelated Search:

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  • Benzo(beta)thiophene
  • Benzothiofuran
  • Benzothiophen
  • Thianaphtene
  • Thianaphthen
  • Thianapthene
  • Thionaphthen
  • Benzo[b]thiophene, 98+%
  • Thianaphthene, Thionaphthene
  • Benzo[b]thiophene, Benzothiophene, Thionaphthene
  • Benzobüthiophene, 98+%
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  • Thianaphthene@50 μg/mL in Toluene
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  • Thianaphthene, 98%, for synthesis
  • 1-BENZOTHIOPHENE FOR SYNTHESIS
  • Thianaphthene ISO 9001：2015 REACH
  • Brexpiprazole Impurity 95
  • Benzo[b]thiophene, ≥ 97.0%
  • ianaphthene
  • Benzothiophene in isooctane
  • Brexpiprazole Dimer Impurity 95
  • 95-15-8
  • C8H6S1
  • C6H4CHCHS
  • 95158
  • C8H6S
  • Building Blocks
  • Benzothiophenes
  • Heterocyclic Building Blocks
  • Heterocycle-oher series
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