ChemicalBook > CAS DataBase List > 1-Bromo-3-fluoro-5-nitrobenzene

1-Bromo-3-fluoro-5-nitrobenzene

Product Name
1-Bromo-3-fluoro-5-nitrobenzene
CAS No.
7087-65-2
Chemical Name
1-Bromo-3-fluoro-5-nitrobenzene
Synonyms
3-Bromo-5-fluoroaniline;1-Bromo-3-fluoro-5-nitrobenzene;5-AMINO-1-BROMO-3-FLUOROBENZENE;3-Bromo-5-fluoronitrobenzene 97%;Benzene, 1-bromo-3-fluoro-5-nitro-;1-Bromo-3-fluoro-5-nitrobenzene,98%;1-Bromo-3-fluoro-5-nitrobenzene, 97%;1-Bromo-3-fluoro-5-nitrobenzene ISO 9001：2015 REACH
CBNumber
CB0775539
Molecular Formula
C6H3BrFNO2
Formula Weight
220
MOL File
7087-65-2.mol
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1-Bromo-3-fluoro-5-nitrobenzene Property

Boiling point:
247.2±20.0 °C(Predicted)
Density 
1.808±0.06 g/cm3(Predicted)
storage temp. 
Sealed in dry,Room Temperature
form 
Liquid
color 
Yellow
CAS DataBase Reference
7087-65-2
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Safety

RIDADR 
UN2810
HazardClass 
6.1
HS Code 
2904990090
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H302Harmful if swallowed

H312Harmful in contact with skin

H315Causes skin irritation

H319Causes serious eye irritation

H331Toxic if inhaled

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P405Store locked up.

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N-Bromosuccinimide Price

TRC
Product number
B688643
Product name
1-Bromo-3-fluoro-5-nitrobenzene
Packaging
250mg
Price
$55
Updated
2021/12/16
Biosynth Carbosynth
Product number
FB29395
Product name
1-Bromo-3-fluoro-5-nitrobenzene
Packaging
1g
Price
$60
Updated
2021/12/16
ChemScene
Product number
CS-W007693
Product name
1-Bromo-3-fluoro-5-nitrobenzene
Purity
98.18%
Packaging
10g
Price
$78
Updated
2021/12/16
Biosynth Carbosynth
Product number
FB29395
Product name
1-Bromo-3-fluoro-5-nitrobenzene
Packaging
2g
Price
$90
Updated
2021/12/16
ChemScene
Product number
CS-W007693
Product name
1-Bromo-3-fluoro-5-nitrobenzene
Purity
98.18%
Packaging
5g
Price
$42
Updated
2021/12/16
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1-Bromo-3-fluoro-5-nitrobenzene Chemical Properties,Usage,Production

Synthesis

10472-88-5

7087-65-2

General procedure for the synthesis of 1-bromo-3-fluoro-5-nitrobenzene from 2-bromo-4-fluoro-6-nitroaniline: To a solution of 2-bromo-4-fluoro-6-nitroaniline (702 mg, 3 mmol) in ethanol (3 mL) was added 6 mL of 60% sulphuric acid at 0 °C, followed by the slow addition of sodium nitrite (414 mg, 6 mmol) in batches. After addition, stirring was continued for 1 hour while maintaining the reaction temperature at 0-5 °C. Subsequently, ferrous sulfate heptahydrate (4.38 g, 6 mmol) was added and the resulting mixture was continued to be stirred for 3 hours. After completion of the reaction, the mixture was concentrated, water was added and the aqueous phase was extracted with dichloromethane (20 mL x 3). The organic layers were combined, washed with brine (20 mL), dried over anhydrous sodium sulfate, filtered and concentrated. The residue was purified by preparative thin layer chromatography (TLC) with the eluent dichloromethane/methanol = 60/1 to afford the target product 1-bromo-3-fluoro-5-nitrobenzene (yellow solid, 448 mg, 68% yield).

References

[1] Patent: WO2016/161145, 2016, A1. Location in patent: Paragraph 00704
[2] Journal of Antibiotics, 1994, vol. 47, # 12, p. 1456 - 1465
[3] Bioorganic and Medicinal Chemistry Letters, 1998, vol. 8, # 23, p. 3397 - 3402
[4] Bioorganic and Medicinal Chemistry Letters, 2011, vol. 21, # 11, p. 3243 - 3247

1-Bromo-3-fluoro-5-nitrobenzene Preparation Products And Raw materials

Raw materials

Preparation Products

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View Lastest Price from 1-Bromo-3-fluoro-5-nitrobenzene manufacturers

Hebei Chuanghai Biotechnology Co., Ltd
Product
1-Bromo-3-fluoro-5-nitrobenzene 7087-65-2
Price
US $0.00-0.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
20 mt
Release date
2024-12-10
Career Henan Chemical Co
Product
2-Bromo-4-methylbenzoic acid 7087-65-2
Price
US $3.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
100kg
Release date
2019-07-09

7087-65-2, 1-Bromo-3-fluoro-5-nitrobenzeneRelated Search:

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