ChemicalBook > CAS DataBase List > 3-Bromo-2-fluorobenzoic acid methyl ester

3-Bromo-2-fluorobenzoic acid methyl ester

Product Name
3-Bromo-2-fluorobenzoic acid methyl ester
CAS No.
206551-41-9
Chemical Name
3-Bromo-2-fluorobenzoic acid methyl ester
Synonyms
methyl 2-fluoro-3-bromobenzoate;Methyl3-bromo-2-fluorobenzoate,98%;3-Bromo-2-fluorobenzoic acid methyl ester;Benzoic acid, 3-bromo-2-fluoro-, methyl ester
CBNumber
CB11180393
Molecular Formula
C8H6BrFO2
Formula Weight
233.03
MOL File
206551-41-9.mol
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3-Bromo-2-fluorobenzoic acid methyl ester Property

Melting point:
35-37℃
Boiling point:
255℃
Density 
1.577
Flash point:
108℃
storage temp. 
Sealed in dry,Room Temperature
solubility 
soluble in Methanol
form 
Fused Solid
color 
White to cream
InChI
InChI=1S/C8H6BrFO2/c1-12-8(11)5-3-2-4-6(9)7(5)10/h2-4H,1H3
InChIKey
ZWOFHFOFKBYRHV-UHFFFAOYSA-N
SMILES
C(OC)(=O)C1=CC=CC(Br)=C1F
CAS DataBase Reference
206551-41-9
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Safety

HS Code 
2916399090
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

Precautionary statements

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P332+P313IF SKIN irritation occurs: Get medical advice/attention.

P337+P313IF eye irritation persists: Get medical advice/attention.

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N-Bromosuccinimide Price

TCI Chemical
Product number
M2711
Product name
Methyl 3-Bromo-2-fluorobenzoate
Purity
>98.0%(GC)
Packaging
1g
Price
$45
Updated
2025/07/31
TCI Chemical
Product number
M2711
Product name
Methyl 3-Bromo-2-fluorobenzoate
Purity
>98.0%(GC)
Packaging
5g
Price
$180
Updated
2025/07/31
TRC
Product number
M296525
Product name
Methyl 3-Bromo-2-fluorobenzoate
Packaging
50mg
Price
$60
Updated
2021/12/16
Matrix Scientific
Product number
075913
Product name
Methyl 3-bromo-2-fluorobenzoate
Purity
95+%
Packaging
1g
Price
$34
Updated
2021/12/16
SynQuest Laboratories
Product number
2623-B-04
Product name
Methyl 3-bromo-2-fluorobenzoate
Packaging
1g
Price
$40
Updated
2021/12/16
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3-Bromo-2-fluorobenzoic acid methyl ester Chemical Properties,Usage,Production

Chemical Properties

off-white powder

Synthesis

1007-16-5

74-88-4

206551-41-9

To a 100 mL round-bottom flask was added 3-bromo-4-fluorobenzoic acid (5.00 g, 22.8 mmol, Oakwood), potassium carbonate (3.17 g, 22.9 mmol), and N,N-dimethylformamide (DMF, 30 mL). Subsequently, iodomethane (2 M in methyl tert-butyl ether (MTBE), 11.6 mL, 23.2 mmol) was slowly added and the reaction mixture was stirred at room temperature for 16 hours. After completion of the reaction, the mixture was filtered and the filtrate was concentrated under reduced pressure. The obtained brown crude product was dissolved with ethyl acetate (EtOAc), filtered and concentrated again to finally obtain methyl 3-bromo-2-fluorobenzoate (4.76 g, 20.4 mmol, 89.5% yield) as a brown slurry, which could be used in subsequent steps without further purification.

References

[1] Patent: WO2007/61930, 2007, A1. Location in patent: Page/Page column 63

3-Bromo-2-fluorobenzoic acid methyl ester Preparation Products And Raw materials

Raw materials

Preparation Products

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View Lastest Price from 3-Bromo-2-fluorobenzoic acid methyl ester manufacturers

Shaanxi Dideu New Materials Co. Ltd
Product
3-Bromo-2-fluorobenzoic acid methyl ester 206551-41-9
Price
US $0.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
10000KGS
Release date
2025-07-05
Hebei Chuanghai Biotechnology Co., Ltd
Product
3-Bromo-2-fluorobenzoic acid methyl ester 206551-41-9
Price
US $10.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
10 mt
Release date
2025-03-10
Shaanxi Dideu Medichem Co. Ltd
Product
3-Bromo-2-fluorobenzoic acid methyl ester 206551-41-9
Price
US $0.00-0.00/KG
Min. Order
5mg
Purity
99%HPLC
Supply Ability
2000tons
Release date
2020-01-07

206551-41-9, 3-Bromo-2-fluorobenzoic acid methyl esterRelated Search:

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  • 206551-41-9
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