ChemicalBook > CAS DataBase List > 3,4-Epoxycyclohexylmethyl 3,4-epoxycyclohexanecarboxylate

3,4-Epoxycyclohexylmethyl 3,4-epoxycyclohexanecarboxylate

Product Name
3,4-Epoxycyclohexylmethyl 3,4-epoxycyclohexanecarboxylate
CAS No.
2386-87-0
Chemical Name
3,4-Epoxycyclohexylmethyl 3,4-epoxycyclohexanecarboxylate
Synonyms
2021P;3,4-EPOXYCYCLOHEXYLMETHYL;erl-4221;UVR-6110;7-OXABICYCLO[4.1.0]HEPTANE-3-CARBOXYLIC ACID;ut632;HS-21;EP6110;ERL-4211;3,4-EpoxycycL
CBNumber
CB1258622
Molecular Formula
C14H20O4
Formula Weight
252.31
MOL File
2386-87-0.mol
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3,4-Epoxycyclohexylmethyl 3,4-epoxycyclohexanecarboxylate Property

Melting point:
−37 °C(lit.)
Boiling point:
355.49°C (rough estimate)
Density 
1.17 g/mL at 25 °C(lit.)
vapor pressure 
0.002Pa at 25℃
refractive index 
n20/D 1.498(lit.)
Flash point:
245 °F
storage temp. 
2-8°C
solubility 
Chloroform (Slightly), Dichloromethane (Slightly)
form 
Oil
pka
4.61±0.20(Predicted)
color 
Colourless
Specific Gravity
1.170
Water Solubility 
13.85g/L at 20.2℃
InChIKey
NHJIDZUQMHKGRE-UHFFFAOYSA-N
LogP
1.34 at 20℃
CAS DataBase Reference
2386-87-0(CAS DataBase Reference)
EPA Substance Registry System
7-Oxabicyclo[4.1.0]heptane-3-carboxylic acid, 7-oxabicyclo[4.1.0]hept-3-ylmethyl ester (2386-87-0)
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Safety

Hazard Codes 
Xi
Risk Statements 
43
Safety Statements 
36/37
WGK Germany 
1
RTECS 
RN7750000
HS Code 
29189900
Hazardous Substances Data
2386-87-0(Hazardous Substances Data)
Toxicity
LD50 oral in rat: 4490mg/kg
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H317May cause an allergic skin reaction

H412Harmful to aquatic life with long lasting effects

Precautionary statements

P273Avoid release to the environment.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
407208
Product name
3,4-Epoxycyclohexylmethyl 3,4-epoxycyclohexanecarboxylate
Packaging
50ml
Price
$44.34
Updated
2024/03/01
Sigma-Aldrich
Product number
407208
Product name
3,4-Epoxycyclohexylmethyl 3,4-epoxycyclohexanecarboxylate
Packaging
250ml
Price
$244
Updated
2024/03/01
TRC
Product number
E585920
Product name
3,4-Epoxycyclohexylmethyl3,4-Epoxycyclohexaneca
Packaging
1g
Price
$40
Updated
2021/12/16
AK Scientific
Product number
V1829
Product name
3,4-Epoxycyclohexylmethyl 3,4-epoxycyclohexanecarboxylate
Packaging
25g
Price
$39
Updated
2021/12/16
Medical Isotopes, Inc.
Product number
38139
Product name
7-Oxabicyclo[4.1.0]heptan-3-ylmethyl7-oxabicyclo[4.1.0]heptane-3-carboxylate
Purity
95+%
Packaging
25g
Price
$320
Updated
2021/12/16
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3,4-Epoxycyclohexylmethyl 3,4-epoxycyclohexanecarboxylate Chemical Properties,Usage,Production

Description

3,4-Epoxycyclohexylmethyl 3,4-epoxycyclohexanecarboxylate TTA21S is a pale yellow to colorless transparent liquid. Two package and UV cure formulas use TTA21 to create better crosslinks and enhance adhesion. Each molecule creates high cross-linking due to the dual epoxide functionality, which can react with hydroxyl, carboxyl, or amine groups of polymers in the system. End users take advantage of the UV stability and low viscosity compared to other epoxy resins.

Chemical Properties

Pale yellow to colorless transparent liquid

Uses

This compound can be made by treatment of the corresponding bis-unsaturated ester with peracetic acid. It is used as a reactive diluent, for filament winding, as an acid scavenger, or as a plasticizer. Vapor hazard is slight at ambient temperature because of its moderately high boiling point. Skin contact is to be avoided.

Uses

EEC is an epoxy monomer that can be used as a resin in aerospace, electronics and automobile industries as an adhesive and a composite material.

General Description

3,4-Epoxycyclohexylmethyl 3,4-epoxycyclohexanecarboxylate (EEC) is a cycloaliphatic epoxy that can be synthesized by the reaction of 3′-cyclohexenylmethyl 3-cyclohexenecarboxylate with peracetic acid. Its aliphatic backbone and molecular structure provide a number of useful properties such as thermal stability, weatherability, and electrical conductivity.

Flammability and Explosibility

Non flammable

Synthesis

128.17kg of 3,4-epoxycyclohexyl-1-methanol, 312.36kg of 3,4-epoxycyclohexyl-1-methyl carboxylate, 9.61kg of tetrabutoxytitanium were added to the 500L reactor, and reacted at 100°C 7 hours (there is no apparent liquid steaming out at this time, sampling GC detection 3,4-epoxycyclohexyl-1-methanol content≤1.0wt%), stop the reaction; The reaction solution is at 500Pa vacuum, 95 vacuum distillation to remove excess Methyl 3,4-epoxycyclohexyl-1-carboxylate, the concentrated solution was distilled by molecular distillation, vacuum distillation at 2Pa, 144°C under reduced pressure to obtain 3,4-Epoxycyclohexylmethyl 3,4-epoxycyclohexanecarboxylate.

3,4-Epoxycyclohexylmethyl 3,4-epoxycyclohexanecarboxylate Preparation Products And Raw materials

Raw materials

Preparation Products

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3,4-Epoxycyclohexylmethyl 3,4-epoxycyclohexanecarboxylate Suppliers

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View Lastest Price from 3,4-Epoxycyclohexylmethyl 3,4-epoxycyclohexanecarboxylate manufacturers

Hebei Dangtong Import and export Co LTD
Product
3,4-Epoxycyclohexylmethyl 3,4-epoxycyclohexanecarboxylate 2386-87-0
Price
US $70.00/kilograms
Min. Order
10kilograms
Purity
99
Supply Ability
10
Release date
2023-03-01
Henan Fengda Chemical Co., Ltd
Product
3,4-Epoxycyclohexylmethyl 3,4-epoxycyclohexanecarboxylate 2386-87-0
Price
US $50.00-1.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
g-kg-tons, free sample is available
Release date
2023-12-22
Hebei Duling International Trade Co. LTD
Product
3,4-Epoxycyclohexylmethyl 3,4-epoxycyclohexanecarboxylate 2386-87-0
Price
US $1.00/kg
Min. Order
1kg
Purity
99.6%
Supply Ability
20tons
Release date
2023-03-20

2386-87-0, 3,4-Epoxycyclohexylmethyl 3,4-epoxycyclohexanecarboxylateRelated Search:

4-(Chloromethyl)benzoic acid Heptane 4-(Aminomethyl)benzoic acid 2-(Trifluoromethyl)benzoic acid 2-Methyl-2-propenoic acid cyclohexyl ester RESMETHRIN m-Toluic acid o-Toluic acid Cyclohexanecarboxylic acid p-Toluic acid METHYLCYCLOHEXANOL BIS(3,4-EPOXYCYCLOHEXYLMETHYL) ADIPATE 1,2-Epoxy-4-vinylcyclohexane Dicyclopentadiene diepoxide Cyclohexylacetic acid METHYL CYCLOHEXANEACETATE ETHYL CYCLOHEXYLACETATE 4-METHYL-1,2-CYCLOHEXENE OXIDE

  • 3,4-epoxycyclohexanecarboxylicacid(3,4-epoxycyclohexylmethyl)ester
  • 3,4-epoxycyclohexanemethyl3,4-epoxycyclohexanecarboxylate
  • 3,4-epoxycyclohexylmethyl3,4-epoxycyclo-hexaneca
  • 7-oxabicyclo(4.1.0)heptane-3-carboxylicacid,7-oxabicyclo(4.1.0)hept-3-ylmethy
  • 7-Oxabicyclo[4,1,0]heptane-3-carboxylicacid,7-oxabicyclo[4,1,0]hept-3-ylmethylester
  • 3,4-Epoxycyclohexylmethyl-3,4-epoxycy-clohexane Carboxylate （JR-HS-21）
  • 7-Oxabicyclo[4.1.0]heptan-3-ylmethyl 7-oxabicyclo[4.1.0]heptane-3-carboxylate
  • 1,2-Epoxycyclohexane-4-carboxylic acid 1,2-epoxycyclohexane-4-ylmethyl ester
  • 3,4-Epoxy-1-cyclohexanecarboxylic acid (3,4-epoxycyclohexan-1-yl)methyl ester
  • 3,4-Epoxycyclohexane-1-carboxylic acid (3,4-epoxycyclohexane-1-yl)methyl ester
  • 7-Oxabicyclo[4.1.0]heptane-3-carboxylic acid 7-oxabicyclo[4.1.0]heptan-3-ylmethyl ester
  • ERL-4211
  • UVR-6110
  • Cycloaliphatic Epoxide Resin ERL-4221
  • 1-{7-oxabicyclo[4.1.0]heptan-3-ylMethyl}-7-oxabicyclo[4.1.0]heptane-3-carboxylate
  • 3,4-EpoxycyclohexylM
  • ：Cycloaliphatic Epoxy
  • 3,4-Epoxycyclohexylmethyl, 3,4-Epoxycyclohexanecarboxylate (UVR-6110,6103,6105,6107)
  • 3'-4'-Epoxycyclohexane)Methyl 3'-4'-Epoxycyclohexyl-carboxylate
  • 3,4-Epoxycyclohexylmethyl, 3,4-Epocyclohexane Carboxylate (UVR-6110,6103,6105,6107)
  • 3,4-EpoxycycL
  • 3,4-Epoxycyclohexylmethyl, 3,4-Epoxcyclohexane Carboxylate Uvr-6110
  • chissonox221monomer
  • erl-4221
  • ut632
  • 3,4-EPOXYCYCLOHEXYLMETHYL 3',4'-EPOXYCYCLOHEXANECARBOXYLATE
  • 3,4-EPOXYCYCLOHEXYLMETHYL 3,4-EPOXYCYCLOHEXANECARBOXYLATE
  • 3,4-EPOXYCYCLOHEXYLMETHYL-3,4-EPOXYCYCLOHEXYLCARBOXYLATE
  • 7-oxabicyclo[4.1.0]hept-3-ylmethyl 7-oxabicyclo[4.1.0]heptane-3-carboxylate
  • 3,4-EPOXYCYCLOHEXYLMETHYL
  • EPOXYCYCLOHEXYLMETHYL-EPOXYCYCLO-HEXANECARBOXYLATE
  • 7-OXABICYCLOHEPTANE-3-CARBOXYLICACID,7-OXABICYCLOHEPT-3-YLMETHYLESTER
  • 7-OXABICYCLOHEPTANE-3-CARBOXYLICACID
  • 7-Oxabicyclo(4.1.0)hept-3-ylmethyl-7-oxabicyclo(4.1.0)heptan-3-carboxylat
  • 7-OXABICYCLO[4.1.0]HEPTANE-3-CARBOXYLIC ACID
  • EMBEDDING MEDIUM ERL-4221D
  • HS-21
  • Daicel Celloxide 2021
  • Cycloaliphatic epoxy resin Daicel Celloxide
  • Syna Epoxy 21 (UVR6110, ERL4221)
  • Syna Epoxy 06E (UVR6105, ERL4221D)
  • Syna Epoxy 10
  • 4-epoxycyclohexanecarboxylate
  • 4-Epoxycyclohexylmethyl 3
  • 2021P
  • CAS 2386-87-0 3, 4-Epoxycyclohexylmethyl 3, 4-Epoxycyclo-Hexaneca Uvr-6110
  • 3,4-Epoxycyclohexylmethyl-3’
  • 3, 4-Epoxycyclo-Hexaneca Uvr-6110
  • 3,4-epoxycyclohexylmethyl 3,4-epoxycyclodecanoate
  • EP6110
  • 2386-87-0
  • Epoxide Monomers
  • Monomers
  • Polymer Science