3,4-Epoxycyclohexylmethyl 3,4-epoxycyclohexanecarboxylate
- Product Name
- 3,4-Epoxycyclohexylmethyl 3,4-epoxycyclohexanecarboxylate
- CAS No.
- 2386-87-0
- Chemical Name
- 3,4-Epoxycyclohexylmethyl 3,4-epoxycyclohexanecarboxylate
- Synonyms
- 2021P;3,4-EPOXYCYCLOHEXYLMETHYL;erl-4221;UVR-6110;7-OXABICYCLO[4.1.0]HEPTANE-3-CARBOXYLIC ACID;ut632;HS-21;EP6110;ERL-4211;3,4-EpoxycycL
- CBNumber
- CB1258622
- Molecular Formula
- C14H20O4
- Formula Weight
- 252.31
- MOL File
- 2386-87-0.mol
3,4-Epoxycyclohexylmethyl 3,4-epoxycyclohexanecarboxylate Property
- Melting point:
- −37 °C(lit.)
- Boiling point:
- 355.49°C (rough estimate)
- Density
- 1.17 g/mL at 25 °C(lit.)
- vapor pressure
- 0.002Pa at 25℃
- refractive index
- n20/D 1.498(lit.)
- Flash point:
- 245 °F
- storage temp.
- 2-8°C
- solubility
- Chloroform (Slightly), Dichloromethane (Slightly)
- form
- Oil
- pka
- 4.61±0.20(Predicted)
- Specific Gravity
- 1.170
- color
- Colourless
- Water Solubility
- 13.85g/L at 20.2℃
- InChIKey
- NHJIDZUQMHKGRE-UHFFFAOYSA-N
- LogP
- 1.34 at 20℃
- CAS DataBase Reference
- 2386-87-0(CAS DataBase Reference)
- EPA Substance Registry System
- 7-Oxabicyclo[4.1.0]heptane-3-carboxylic acid, 7-oxabicyclo[4.1.0]hept-3-ylmethyl ester (2386-87-0)
Safety
- Hazard Codes
- Xi
- Risk Statements
- 43
- Safety Statements
- 36/37
- WGK Germany
- 1
- RTECS
- RN7750000
- HS Code
- 29189900
- Hazardous Substances Data
- 2386-87-0(Hazardous Substances Data)
- Toxicity
- LD50 oral in rat: 4490mg/kg
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H317May cause an allergic skin reaction
H412Harmful to aquatic life with long lasting effects
- Precautionary statements
-
P273Avoid release to the environment.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P302+P352IF ON SKIN: wash with plenty of soap and water.
N-Bromosuccinimide Price
- Product number
- 407208
- Product name
- 3,4-Epoxycyclohexylmethyl 3,4-epoxycyclohexanecarboxylate
- Packaging
- 50ml
- Price
- $44.34
- Updated
- 2024/03/01
- Product number
- 407208
- Product name
- 3,4-Epoxycyclohexylmethyl 3,4-epoxycyclohexanecarboxylate
- Packaging
- 250ml
- Price
- $244
- Updated
- 2024/03/01
- Product number
- E585920
- Product name
- 3,4-Epoxycyclohexylmethyl3,4-Epoxycyclohexaneca
- Packaging
- 1g
- Price
- $40
- Updated
- 2021/12/16
- Product number
- V1829
- Product name
- 3,4-Epoxycyclohexylmethyl 3,4-epoxycyclohexanecarboxylate
- Packaging
- 25g
- Price
- $39
- Updated
- 2021/12/16
- Product number
- 38139
- Product name
- 7-Oxabicyclo[4.1.0]heptan-3-ylmethyl7-oxabicyclo[4.1.0]heptane-3-carboxylate
- Purity
- 95+%
- Packaging
- 25g
- Price
- $320
- Updated
- 2021/12/16
3,4-Epoxycyclohexylmethyl 3,4-epoxycyclohexanecarboxylate Chemical Properties,Usage,Production
Description
3,4-Epoxycyclohexylmethyl 3,4-epoxycyclohexanecarboxylate TTA21S is a pale yellow to colorless transparent liquid. Two package and UV cure formulas use TTA21 to create better crosslinks and enhance adhesion. Each molecule creates high cross-linking due to the dual epoxide functionality, which can react with hydroxyl, carboxyl, or amine groups of polymers in the system. End users take advantage of the UV stability and low viscosity compared to other epoxy resins.
Chemical Properties
Pale yellow to colorless transparent liquid
Uses
This compound can be made by treatment of the corresponding bis-unsaturated ester with peracetic acid. It is used as a reactive diluent, for filament winding, as an acid scavenger, or as a plasticizer. Vapor hazard is slight at ambient temperature because of its moderately high boiling point. Skin contact is to be avoided.
Uses
EEC is an epoxy monomer that can be used as a resin in aerospace, electronics and automobile industries as an adhesive and a composite material.
General Description
3,4-Epoxycyclohexylmethyl 3,4-epoxycyclohexanecarboxylate (EEC) is a cycloaliphatic epoxy that can be synthesized by the reaction of 3′-cyclohexenylmethyl 3-cyclohexenecarboxylate with peracetic acid. Its aliphatic backbone and molecular structure provide a number of useful properties such as thermal stability, weatherability, and electrical conductivity.
Flammability and Explosibility
Non flammable
Synthesis
128.17kg of 3,4-epoxycyclohexyl-1-methanol, 312.36kg of 3,4-epoxycyclohexyl-1-methyl carboxylate, 9.61kg of tetrabutoxytitanium were added to the 500L reactor, and reacted at 100°C 7 hours (there is no apparent liquid steaming out at this time, sampling GC detection 3,4-epoxycyclohexyl-1-methanol content≤1.0wt%), stop the reaction; The reaction solution is at 500Pa vacuum, 95 vacuum distillation to remove excess Methyl 3,4-epoxycyclohexyl-1-carboxylate, the concentrated solution was distilled by molecular distillation, vacuum distillation at 2Pa, 144°C under reduced pressure to obtain 3,4-Epoxycyclohexylmethyl 3,4-epoxycyclohexanecarboxylate.
3,4-Epoxycyclohexylmethyl 3,4-epoxycyclohexanecarboxylate Preparation Products And Raw materials
Raw materials
Preparation Products
3,4-Epoxycyclohexylmethyl 3,4-epoxycyclohexanecarboxylate Suppliers
- Tel
- --
- Fax
- --
- labchem-tec@wako-chem.co.jp
- Country
- Japan
- ProdList
- 6819
- Advantage
- 80
View Lastest Price from 3,4-Epoxycyclohexylmethyl 3,4-epoxycyclohexanecarboxylate manufacturers
- Product
- 3,4-Epoxycyclohexylmethyl 2386-87-0
- Price
- US $10.00/kg
- Min. Order
- 1kg
- Purity
- 99%
- Supply Ability
- 20 ton
- Release date
- 2024-12-18
- Product
- 3,4-Epoxycyclohexylmethyl 3,4-epoxycyclohexanecarboxylate 2386-87-0
- Price
- US $100.00-75.00/kg
- Min. Order
- 1kg
- Purity
- 99%
- Supply Ability
- 5000
- Release date
- 2024-08-14
- Product
- 3,4-Epoxycyclohexylmethyl 3,4-epoxycyclohexanecarboxylate 2386-87-0
- Price
- US $70.00/kilograms
- Min. Order
- 10kilograms
- Purity
- 99
- Supply Ability
- 10
- Release date
- 2023-03-01