3,4-Epoxycyclohexylmethyl 3,4-epoxycyclohexanecarboxylate

Product Name: 3,4-Epoxycyclohexylmethyl 3,4-epoxycyclohexanecarboxylate
CAS No.: 2386-87-0
Chemical Name: 3,4-Epoxycyclohexylmethyl 3,4-epoxycyclohexanecarboxylate
Synonyms: 2021P;3,4-EPOXYCYCLOHEXYLMETHYL;erl-4221;UVR-6110;7-OXABICYCLO[4.1.0]HEPTANE-3-CARBOXYLIC ACID;ut632;HS-21;EP6110;ERL-4211;3,4-EpoxycycL
CBNumber: CB1258622
Molecular Formula: C14H20O4
Formula Weight: 252.31
MOL File: 2386-87-0.mol

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3,4-Epoxycyclohexylmethyl 3,4-epoxycyclohexanecarboxylate Property

Melting point:: −37 °C(lit.)
Boiling point:: 355.49°C (rough estimate)
Density: 1.17 g/mL at 25 °C(lit.)
vapor pressure: 0.002Pa at 25℃
refractive index: n20/D 1.498(lit.)
Flash point:: 245 °F
storage temp.: 2-8°C
solubility: Chloroform (Slightly), Dichloromethane (Slightly)
form: Oil
pka: 4.61±0.20(Predicted)
Specific Gravity: 1.170
color: Colourless
Water Solubility: 13.85g/L at 20.2℃
InChIKey: NHJIDZUQMHKGRE-UHFFFAOYSA-N
LogP: 1.34 at 20℃
CAS DataBase Reference: 2386-87-0(CAS DataBase Reference)
EPA Substance Registry System: 7-Oxabicyclo[4.1.0]heptane-3-carboxylic acid, 7-oxabicyclo[4.1.0]hept-3-ylmethyl ester (2386-87-0)

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Safety

Hazard Codes: Xi
Risk Statements: 43
Safety Statements: 36/37
WGK Germany: 1
RTECS: RN7750000
HS Code: 29189900
Hazardous Substances Data: 2386-87-0(Hazardous Substances Data)
Toxicity: LD50 oral in rat: 4490mg/kg

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H317May cause an allergic skin reaction

H412Harmful to aquatic life with long lasting effects

Precautionary statements

P273Avoid release to the environment.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 407208
Product name: 3,4-Epoxycyclohexylmethyl 3,4-epoxycyclohexanecarboxylate
Packaging: 50ml
Price: $44.34
Updated: 2024/03/01

Sigma-Aldrich

Product number: 407208
Product name: 3,4-Epoxycyclohexylmethyl 3,4-epoxycyclohexanecarboxylate
Packaging: 250ml
Price: $244
Updated: 2024/03/01

TRC

Product number: E585920
Product name: 3,4-Epoxycyclohexylmethyl3,4-Epoxycyclohexaneca
Packaging: 1g
Price: $40
Updated: 2021/12/16

AK Scientific

Product number: V1829
Product name: 3,4-Epoxycyclohexylmethyl 3,4-epoxycyclohexanecarboxylate
Packaging: 25g
Price: $39
Updated: 2021/12/16

Medical Isotopes, Inc.

Product number: 38139
Product name: 7-Oxabicyclo[4.1.0]heptan-3-ylmethyl7-oxabicyclo[4.1.0]heptane-3-carboxylate
Purity: 95+%
Packaging: 25g
Price: $320
Updated: 2021/12/16

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3,4-Epoxycyclohexylmethyl 3,4-epoxycyclohexanecarboxylate Chemical Properties,Usage,Production

Description

3,4-Epoxycyclohexylmethyl 3,4-epoxycyclohexanecarboxylate TTA21S is a pale yellow to colorless transparent liquid. Two package and UV cure formulas use TTA21 to create better crosslinks and enhance adhesion. Each molecule creates high cross-linking due to the dual epoxide functionality, which can react with hydroxyl, carboxyl, or amine groups of polymers in the system. End users take advantage of the UV stability and low viscosity compared to other epoxy resins.

Chemical Properties

Pale yellow to colorless transparent liquid

Uses

This compound can be made by treatment of the corresponding bis-unsaturated ester with peracetic acid. It is used as a reactive diluent, for filament winding, as an acid scavenger, or as a plasticizer. Vapor hazard is slight at ambient temperature because of its moderately high boiling point. Skin contact is to be avoided.

Uses

EEC is an epoxy monomer that can be used as a resin in aerospace, electronics and automobile industries as an adhesive and a composite material.

General Description

3,4-Epoxycyclohexylmethyl 3,4-epoxycyclohexanecarboxylate (EEC) is a cycloaliphatic epoxy that can be synthesized by the reaction of 3′-cyclohexenylmethyl 3-cyclohexenecarboxylate with peracetic acid. Its aliphatic backbone and molecular structure provide a number of useful properties such as thermal stability, weatherability, and electrical conductivity.

Flammability and Explosibility

Non flammable

Synthesis

128.17kg of 3,4-epoxycyclohexyl-1-methanol, 312.36kg of 3,4-epoxycyclohexyl-1-methyl carboxylate, 9.61kg of tetrabutoxytitanium were added to the 500L reactor, and reacted at 100°C 7 hours (there is no apparent liquid steaming out at this time, sampling GC detection 3,4-epoxycyclohexyl-1-methanol content≤1.0wt%), stop the reaction; The reaction solution is at 500Pa vacuum, 95 vacuum distillation to remove excess Methyl 3,4-epoxycyclohexyl-1-carboxylate, the concentrated solution was distilled by molecular distillation, vacuum distillation at 2Pa, 144°C under reduced pressure to obtain 3,4-Epoxycyclohexylmethyl 3,4-epoxycyclohexanecarboxylate.

3,4-Epoxycyclohexylmethyl 3,4-epoxycyclohexanecarboxylate Preparation Products And Raw materials

Raw materials

Preparation Products

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3,4-Epoxycyclohexylmethyl 3,4-epoxycyclohexanecarboxylate Suppliers

Canada 2 China 283 Germany 1 India 2 Japan 1 Switzerland 1 United Kingdom 1 United States 17 Global 308

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Beijing Isomersyn Technology CO;LTD

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Shanghai G&K Biomedical Scientific Inc.

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View Lastest Price from 3,4-Epoxycyclohexylmethyl 3,4-epoxycyclohexanecarboxylate manufacturers

Hebei Zhuanglai Chemical Trading Co Ltd

Product: 3,4-Epoxycyclohexylmethyl 2386-87-0
Price: US $10.00/kg
Min. Order: 1kg
Purity: 99%
Supply Ability: 20 ton
Release date: 2024-12-18

HEBEI SHENGSUAN CHEMICAL INDUSTRY CO.,LTD

Product: 3,4-Epoxycyclohexylmethyl 3,4-epoxycyclohexanecarboxylate 2386-87-0
Price: US $100.00-75.00/kg
Min. Order: 1kg
Purity: 99%
Supply Ability: 5000
Release date: 2024-08-14

Hebei Dangtong Import and export Co LTD

Product: 3,4-Epoxycyclohexylmethyl 3,4-epoxycyclohexanecarboxylate 2386-87-0
Price: US $70.00/kilograms
Min. Order: 10kilograms
Purity: 99
Supply Ability: 10
Release date: 2023-03-01

2386-87-0, 3,4-Epoxycyclohexylmethyl 3,4-epoxycyclohexanecarboxylateRelated Search:

4-(Chloromethyl)benzoic acid Heptane 4-(Aminomethyl)benzoic acid 2-(Trifluoromethyl)benzoic acid 2-Methyl-2-propenoic acid cyclohexyl ester RESMETHRIN m-Toluic acid o-Toluic acid Cyclohexanecarboxylic acid p-Toluic acid METHYLCYCLOHEXANOL BIS(3,4-EPOXYCYCLOHEXYLMETHYL) ADIPATE 1,2-Epoxy-4-vinylcyclohexane Dicyclopentadiene diepoxide Cyclohexylacetic acid METHYL CYCLOHEXANEACETATE ETHYL CYCLOHEXYLACETATE 4-METHYL-1,2-CYCLOHEXENE OXIDE

3,4-epoxycyclohexanecarboxylicacid(3,4-epoxycyclohexylmethyl)ester

3,4-epoxycyclohexanemethyl3,4-epoxycyclohexanecarboxylate

3,4-epoxycyclohexylmethyl3,4-epoxycyclo-hexaneca

7-oxabicyclo(4.1.0)heptane-3-carboxylicacid,7-oxabicyclo(4.1.0)hept-3-ylmethy

7-Oxabicyclo[4,1,0]heptane-3-carboxylicacid,7-oxabicyclo[4,1,0]hept-3-ylmethylester

3,4-Epoxycyclohexylmethyl-3,4-epoxycy-clohexane Carboxylate （JR-HS-21）

7-Oxabicyclo[4.1.0]heptan-3-ylmethyl 7-oxabicyclo[4.1.0]heptane-3-carboxylate

1,2-Epoxycyclohexane-4-carboxylic acid 1,2-epoxycyclohexane-4-ylmethyl ester

3,4-Epoxy-1-cyclohexanecarboxylic acid (3,4-epoxycyclohexan-1-yl)methyl ester

3,4-Epoxycyclohexane-1-carboxylic acid (3,4-epoxycyclohexane-1-yl)methyl ester

7-Oxabicyclo[4.1.0]heptane-3-carboxylic acid 7-oxabicyclo[4.1.0]heptan-3-ylmethyl ester

ERL-4211

UVR-6110

Cycloaliphatic Epoxide Resin ERL-4221

1-{7-oxabicyclo[4.1.0]heptan-3-ylMethyl}-7-oxabicyclo[4.1.0]heptane-3-carboxylate

3,4-EpoxycyclohexylM

：Cycloaliphatic Epoxy

3,4-Epoxycyclohexylmethyl, 3,4-Epoxycyclohexanecarboxylate (UVR-6110,6103,6105,6107)

3'-4'-Epoxycyclohexane)Methyl 3'-4'-Epoxycyclohexyl-carboxylate

3,4-Epoxycyclohexylmethyl, 3,4-Epocyclohexane Carboxylate (UVR-6110,6103,6105,6107)

3,4-EpoxycycL

3,4-Epoxycyclohexylmethyl, 3,4-Epoxcyclohexane Carboxylate Uvr-6110

chissonox221monomer

erl-4221

ut632

3,4-EPOXYCYCLOHEXYLMETHYL 3',4'-EPOXYCYCLOHEXANECARBOXYLATE

3,4-EPOXYCYCLOHEXYLMETHYL 3,4-EPOXYCYCLOHEXANECARBOXYLATE

3,4-EPOXYCYCLOHEXYLMETHYL-3,4-EPOXYCYCLOHEXYLCARBOXYLATE

7-oxabicyclo[4.1.0]hept-3-ylmethyl 7-oxabicyclo[4.1.0]heptane-3-carboxylate

3,4-EPOXYCYCLOHEXYLMETHYL

EPOXYCYCLOHEXYLMETHYL-EPOXYCYCLO-HEXANECARBOXYLATE

7-OXABICYCLOHEPTANE-3-CARBOXYLICACID,7-OXABICYCLOHEPT-3-YLMETHYLESTER

7-OXABICYCLOHEPTANE-3-CARBOXYLICACID

7-Oxabicyclo(4.1.0)hept-3-ylmethyl-7-oxabicyclo(4.1.0)heptan-3-carboxylat

7-OXABICYCLO[4.1.0]HEPTANE-3-CARBOXYLIC ACID

EMBEDDING MEDIUM ERL-4221D

HS-21

Daicel Celloxide 2021

Cycloaliphatic epoxy resin Daicel Celloxide

Syna Epoxy 21 (UVR6110, ERL4221)

Syna Epoxy 06E (UVR6105, ERL4221D)

Syna Epoxy 10

4-epoxycyclohexanecarboxylate

4-Epoxycyclohexylmethyl 3

2021P

CAS 2386-87-0 3, 4-Epoxycyclohexylmethyl 3, 4-Epoxycyclo-Hexaneca Uvr-6110

3,4-Epoxycyclohexylmethyl-3’

3, 4-Epoxycyclo-Hexaneca Uvr-6110

3,4-epoxycyclohexylmethyl 3,4-epoxycyclodecanoate

EP6110

3,4-Epoxycyclohexylmethyl -3',4'-epoxycyclohexane Carboxylate

2386-87-0

Epoxide Monomers

Monomers

Polymer Science