METHYL 5-BROMO-2-FUROATE

Product Name: METHYL 5-BROMO-2-FUROATE
CAS No.: 2527-99-3
Chemical Name: METHYL 5-BROMO-2-FUROATE
Synonyms: METHYL 5-BROMOFURAN-2-CARBOXYLATE;AKOS BBS-00004656;BUTTPARK 94\04-07;5-bromo-2-furoate;RARECHEM AL BF 0601;METHYL 5-BROMO-2-FURATE;METHYL 5-BROMO-2-FUROATE;Methyl 5-bromo-2-furanate;Methyl 5-bromo-2-furoate,98%;methyl 5-bromo-2-furoate 97%
CBNumber: CB1393880
Molecular Formula: C6H5BrO3
Formula Weight: 205.01
MOL File: 2527-99-3.mol

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METHYL 5-BROMO-2-FUROATE Property

Melting point:: 63-68 °C
Boiling point:: 80°C/0.7mmHg(lit.)
Density: 1.623±0.06 g/cm3(Predicted)
storage temp.: Keep in dark place,Sealed in dry,Room Temperature
solubility: Chloroform (Soluble), DMSO (Slightly)
form: Crystalline Powder
color: White to slightly yellow
Water Solubility: Slightly soluble in water.
λmax: 264nm(EtOH)(lit.)
InChIKey: FBPIDMAELBIRLE-UHFFFAOYSA-N
CAS DataBase Reference: 2527-99-3(CAS DataBase Reference)

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Safety

Hazard Codes: Xi
Risk Statements: 36/37/38
Safety Statements: 37/39-26
HazardClass: IRRITANT
HS Code: 29321900

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P405Store locked up.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: S810541
Product name: METHYL 5-BROMO-2-FUROATE
Purity: Aldrich<sup>CPR</sup>
Packaging: 1 unit
Price: $185
Updated: 2025/07/31

Sigma-Aldrich

Product number: S810541
Product name: METHYL 5-BROMO-2-FUROATE
Purity: Aldrich
Packaging: 50mg
Price: $179
Updated: 2024/03/01

TCI Chemical

Product number: M2538
Product name: Methyl 5-Bromo-2-furancarboxylate
Purity: >98.0%(GC)
Packaging: 1g
Price: $42
Updated: 2025/07/31

TCI Chemical

Product number: M2538
Product name: Methyl 5-Bromo-2-furancarboxylate
Purity: >98.0%(GC)
Packaging: 5g
Price: $124
Updated: 2025/07/31

TRC

Product number: M296140
Product name: Methyl5-bromofuran-2-carboxylate
Packaging: 1g
Price: $75
Updated: 2021/12/16

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METHYL 5-BROMO-2-FUROATE Chemical Properties,Usage,Production

Chemical Properties

White to slightly yellow crystalline powder

Uses

It is used in the preparation of hydroquinone bis(2-carbomethoxy-5-furyl ether).

Synthesis

67-56-1

585-70-6

2527-99-3

General procedure for the synthesis of methyl 5-bromofuran-2-carboxylate from methanol and 5-bromo-2-furoic acid: 5-bromo-2-furoic acid (950 mg, 5.00 mmol) was accurately weighed and dissolved in 10 mL of methanol, and 2 mL of sulfoxide chloride (SOCl2) was added slowly and dropwise. Upon completion of the reaction, the reaction mixture was cooled to room temperature and the solvent was subsequently removed by evaporation under reduced pressure. The residue was dissolved in an appropriate amount of toluene and this dissolution and evaporation process was repeated three times to give the intermediate 5-bromo-2-furoic acid methyl ester in 100% yield.

References

[1] Patent: CN103992311, 2017, B. Location in patent: Paragraph 0103; 0104; 0105; 0106; 0123; 0124; 0125
[2] Organic Letters, 2012, vol. 14, # 22, p. 5644 - 5647
[3] Patent: CN106977476, 2017, A. Location in patent: Paragraph 0103-0105
[4] Patent: WO2015/159103, 2015, A1. Location in patent: Page/Page column 33; 34; 37
[5] Patent: WO2015/1024, 2015, A1. Location in patent: Page/Page column 65

METHYL 5-BROMO-2-FUROATE Preparation Products And Raw materials

Raw materials

Preparation Products

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METHYL 5-BROMO-2-FUROATE Suppliers

Americas 1 Belgium 3 China 145 Europe 1 Germany 8 India 8 Japan 1 Russia 1 Slovakia 2 Switzerland 1 The Netherlands 1 United Kingdom 13 United States 26 Global 211

Melrob Ltd (part of Nordmann)

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VWR International

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View Lastest Price from METHYL 5-BROMO-2-FUROATE manufacturers

Henan Aochuang Chemical Co.,Ltd.

Product: METHYL 5-BROMO-2-FUROATE 2527-99-3
Price: US $0.00-0.00/KG
Min. Order: 1KG
Purity: 98%
Supply Ability: 1Ton
Release date: 2022-10-13

Hebei Ganmiao New material Technology Co., LTD

Product: METHYL 5-BROMO-2-FUROATE 2527-99-3
Price: US $10.00-8.00/kg
Min. Order: 1kg
Purity: 99%
Supply Ability: 20ton
Release date: 2024-06-07

Shaanxi Haibo Biotechnology Co., Ltd

Product: METHYL 5-BROMO-2-FUROATE 2527-99-3
Price: US $0.00/kg
Min. Order: 1kg
Purity: 99%
Supply Ability: 2000ton
Release date: 2023-08-31

2527-99-3, METHYL 5-BROMO-2-FUROATERelated Search:

Methyl Oleate Isopropyl myristate methyl 5-nitro-2,6-dioxo-3H-pyrimidine-4-carboxylate methyl 5-bromo-1H-pyrrole-2-carboxylate 5-BROMO-2-BROMOMETHYL-BENZOIC ACID METHYL ESTER METHYL 5-BROMO-1H-PYRROLE-3-CARBOXYLATE Methyl 5-bromo-6-chloropyridine-3-carboxylate METHYL 5-BROMO-2-IODOBENZOATE 5-BROMO-4-METHOXYCARBONYL-2(1H)-PYRIDINONE Methyl 5-Bromo-2-Methyl-2H-1,2,3-triazole-4-carboxylate Methyl-5-bromo-2 pyrimidine carboxylate Methyl 5-bromo-2-chloropyridine-3-carboxylate 5-Bromo-6-methoxynicotinic acid methyl ester 5-BROMOPYRIDINE-2-CARBOXYLIC ACID METHYL ESTER Methyl 5-bromo-2-formylbenzoate, 98% METHYL 5-BROMOSALICYLATE Methyl 5-broMo-1H-pyrazole-3-carboxylate Methyl 5-Bromo-1-methyl-1H-1,2,3-triazole-4-carboxylate

RARECHEM AL BF 0601

BUTTPARK 94\04-07

methyl 5-bromo-2-furoate 97%

METHYL-2-BROMOFURAN-CARBOXYLATE

METHYL 5-BROMOFURAN-2-CARBOXYLATE

METHYL 5-BROMO-2-FUROATE

Methyl 5-bromo-2-furoate,98%

5-BROMO-2-FUROIC ACID METHYL ESTER

5-BROMO-FURAN-2-CARBOXYLIC ACID METHYL ESTER

AKOS BBS-00004656

METHYL 5-BROMO-2-FURATE

5-Bromo-2-furancarboxylic acid, methyl ester

Methyl 5-Bromo-2-furancarboxylate

BroMinatedfuranMethyl forMate to5--2-

5-bromo-2-furoate

Methyl 5-Bromo-2-furancarboxylate &gt

2-Furancarboxylic acid, 5-bromo-, methyl ester

Methyl 5-bromo-2-furanate

2527-99-3

C6H5BrO3

C6H5O3Br