ChemicalBook > CAS DataBase List > METHYL 5-BROMO-2-FUROATE

METHYL 5-BROMO-2-FUROATE

Product Name
METHYL 5-BROMO-2-FUROATE
CAS No.
2527-99-3
Chemical Name
METHYL 5-BROMO-2-FUROATE
Synonyms
METHYL 5-BROMOFURAN-2-CARBOXYLATE;AKOS BBS-00004656;BUTTPARK 94\04-07;5-bromo-2-furoate;RARECHEM AL BF 0601;METHYL 5-BROMO-2-FURATE;METHYL 5-BROMO-2-FUROATE;Methyl 5-bromo-2-furanate;Methyl 5-bromo-2-furoate,98%;methyl 5-bromo-2-furoate 97%
CBNumber
CB1393880
Molecular Formula
C6H5BrO3
Formula Weight
205.01
MOL File
2527-99-3.mol
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METHYL 5-BROMO-2-FUROATE Property

Melting point:
63-68 °C
Boiling point:
80°C/0.7mmHg(lit.)
Density 
1.623±0.06 g/cm3(Predicted)
storage temp. 
Keep in dark place,Sealed in dry,Room Temperature
solubility 
Chloroform (Soluble), DMSO (Slightly)
form 
Crystalline Powder
color 
White to slightly yellow
Water Solubility 
Slightly soluble in water.
λmax
264nm(EtOH)(lit.)
InChIKey
FBPIDMAELBIRLE-UHFFFAOYSA-N
CAS DataBase Reference
2527-99-3(CAS DataBase Reference)
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Safety

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
37/39-26
HazardClass 
IRRITANT
HS Code 
29321900
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P405Store locked up.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
S810541
Product name
METHYL 5-BROMO-2-FUROATE
Purity
Aldrich<sup>CPR</sup>
Packaging
1 unit
Price
$185
Updated
2025/07/31
Sigma-Aldrich
Product number
S810541
Product name
METHYL 5-BROMO-2-FUROATE
Purity
Aldrich
Packaging
50mg
Price
$179
Updated
2024/03/01
TCI Chemical
Product number
M2538
Product name
Methyl 5-Bromo-2-furancarboxylate
Purity
>98.0%(GC)
Packaging
1g
Price
$42
Updated
2025/07/31
TCI Chemical
Product number
M2538
Product name
Methyl 5-Bromo-2-furancarboxylate
Purity
>98.0%(GC)
Packaging
5g
Price
$124
Updated
2025/07/31
TRC
Product number
M296140
Product name
Methyl5-bromofuran-2-carboxylate
Packaging
1g
Price
$75
Updated
2021/12/16
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METHYL 5-BROMO-2-FUROATE Chemical Properties,Usage,Production

Chemical Properties

White to slightly yellow crystalline powder

Uses

It is used in the preparation of hydroquinone bis(2-carbomethoxy-5-furyl ether).

Synthesis

67-56-1

585-70-6

2527-99-3

General procedure for the synthesis of methyl 5-bromofuran-2-carboxylate from methanol and 5-bromo-2-furoic acid: 5-bromo-2-furoic acid (950 mg, 5.00 mmol) was accurately weighed and dissolved in 10 mL of methanol, and 2 mL of sulfoxide chloride (SOCl2) was added slowly and dropwise. Upon completion of the reaction, the reaction mixture was cooled to room temperature and the solvent was subsequently removed by evaporation under reduced pressure. The residue was dissolved in an appropriate amount of toluene and this dissolution and evaporation process was repeated three times to give the intermediate 5-bromo-2-furoic acid methyl ester in 100% yield.

References

[1] Patent: CN103992311, 2017, B. Location in patent: Paragraph 0103; 0104; 0105; 0106; 0123; 0124; 0125
[2] Organic Letters, 2012, vol. 14, # 22, p. 5644 - 5647
[3] Patent: CN106977476, 2017, A. Location in patent: Paragraph 0103-0105
[4] Patent: WO2015/159103, 2015, A1. Location in patent: Page/Page column 33; 34; 37
[5] Patent: WO2015/1024, 2015, A1. Location in patent: Page/Page column 65

METHYL 5-BROMO-2-FUROATE Preparation Products And Raw materials

Raw materials

Preparation Products

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METHYL 5-BROMO-2-FUROATE Suppliers

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View Lastest Price from METHYL 5-BROMO-2-FUROATE manufacturers

Henan Aochuang Chemical Co.,Ltd.
Product
METHYL 5-BROMO-2-FUROATE 2527-99-3
Price
US $0.00-0.00/KG
Min. Order
1KG
Purity
98%
Supply Ability
1Ton
Release date
2022-10-13
Hebei Ganmiao New material Technology Co., LTD
Product
METHYL 5-BROMO-2-FUROATE 2527-99-3
Price
US $10.00-8.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
20ton
Release date
2024-06-07
Shaanxi Haibo Biotechnology Co., Ltd
Product
METHYL 5-BROMO-2-FUROATE 2527-99-3
Price
US $0.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
2000ton
Release date
2023-08-31

2527-99-3, METHYL 5-BROMO-2-FUROATERelated Search:


  • RARECHEM AL BF 0601
  • BUTTPARK 94\04-07
  • methyl 5-bromo-2-furoate 97%
  • METHYL-2-BROMOFURAN-CARBOXYLATE
  • METHYL 5-BROMOFURAN-2-CARBOXYLATE
  • METHYL 5-BROMO-2-FUROATE
  • Methyl 5-bromo-2-furoate,98%
  • 5-BROMO-2-FUROIC ACID METHYL ESTER
  • 5-BROMO-FURAN-2-CARBOXYLIC ACID METHYL ESTER
  • AKOS BBS-00004656
  • METHYL 5-BROMO-2-FURATE
  • 5-Bromo-2-furancarboxylic acid, methyl ester
  • Methyl 5-Bromo-2-furancarboxylate
  • BroMinatedfuranMethyl forMate to5--2-
  • 5-bromo-2-furoate
  • Methyl 5-Bromo-2-furancarboxylate &gt
  • 2-Furancarboxylic acid, 5-bromo-, methyl ester
  • Methyl 5-bromo-2-furanate
  • 2527-99-3
  • C6H5BrO3
  • C6H5O3Br