4-IODO-N-METHYLANILINE
- Product Name
- 4-IODO-N-METHYLANILINE
- CAS No.
- 60577-34-6
- Chemical Name
- 4-IODO-N-METHYLANILINE
- Synonyms
- 4-IODO-N-METHYLANILINE;p-Iodo-N-methylaniline;N-Methyl-4-iodoaniline;4-Methylaminophenyl iodide;4-Iodo-N-methyl-benzenamine;(4-IODO-PHENYL)-METHYL-AMINE;Benzenamine, 4-iodo-N-methyl-
- CBNumber
- CB1815027
- Molecular Formula
- C7H8IN
- Formula Weight
- 233.05
- MOL File
- 60577-34-6.mol
4-IODO-N-METHYLANILINE Property
- Melting point:
- 28-29 °C(Solv: hexane (110-54-3))
- Boiling point:
- 261.1±23.0 °C(Predicted)
- Density
- 1.779±0.06 g/cm3(Predicted)
- storage temp.
- Keep in dark place,Inert atmosphere,Store in freezer, under -20°C
- pka
- 3.82±0.12(Predicted)
- Appearance
- Dark purple to black <28°C Solid,>29°C Liquid
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H315Causes skin irritation
H319Causes serious eye irritation
H335May cause respiratory irritation
- Precautionary statements
-
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
N-Bromosuccinimide Price
- Product number
- I715703
- Product name
- 4-Iodo-n-methylaniline
- Packaging
- 500mg
- Price
- $140
- Updated
- 2021/12/16
- Product number
- 074702
- Product name
- 4-Iodo-N-methylaniline
- Purity
- 95+%
- Packaging
- 1g
- Price
- $462
- Updated
- 2021/12/16
- Product number
- W7309
- Product name
- 4-iodo-N-methylaniline
- Packaging
- 5g
- Price
- $480
- Updated
- 2021/12/16
- Product number
- HCH0049746
- Product name
- (4-IODO-PHENYL)-METHYL-AMINE
- Purity
- 95.00%
- Packaging
- 100MG
- Price
- $592.05
- Updated
- 2021/12/16
- Product number
- HCH0049746
- Product name
- (4-IODO-PHENYL)-METHYL-AMINE
- Purity
- 95.00%
- Packaging
- 500MG
- Price
- $624.07
- Updated
- 2021/12/16
4-IODO-N-METHYLANILINE Chemical Properties,Usage,Production
Uses
4-Iodo-n-methylaniline is useful in general efficient method for direct N-methylation of aromatic primary amines with methanol .
Synthesis
100-61-8
60577-34-6
General procedure: The iodination of aryl amines was carried out under solvent-free conditions. The procedure was as follows: DBDABCODCI (0.5 mmol) was mixed and ground with N-methylaniline (1 mmol) in a porcelain mortar at room temperature. The reaction process was monitored by thin layer chromatography (TLC). Upon completion of the reaction, ethyl acetate was added to the mixture and subsequently filtered. The organic layer was washed with 5% aqueous sodium thiosulfate and dried with anhydrous magnesium sulfate. The solvent was evaporated under reduced pressure and the resulting crude product was purified by column chromatography, the eluent being a solvent mixture of ethyl acetate and hexane. The structure of the purified product was confirmed by melting point determination and 1H NMR spectroscopy.
References
[1] Organic Letters, 2001, vol. 3, # 7, p. 991 - 992
[2] Journal of Organic Chemistry, 2018, vol. 83, # 15, p. 7606 - 7621
[3] Bulletin of the Chemical Society of Ethiopia, 2015, vol. 29, # 1, p. 157 - 162
[4] Bulletin of the Chemical Society of Japan, 1988, vol. 61, # 2, p. 600 - 602
[5] Bulletin of the Chemical Society of Japan, 2012, vol. 85, # 11, p. 1239 - 1243
4-IODO-N-METHYLANILINE Preparation Products And Raw materials
Raw materials
Preparation Products
4-IODO-N-METHYLANILINE Suppliers
- Tel
- --
- Fax
- --
- y.barysheva@ukrorgsynth.com
- Country
- Ukraine
- ProdList
- 6230
- Advantage
- 38
View Lastest Price from 4-IODO-N-METHYLANILINE manufacturers
- Product
- METHYL HENEICOSANOATE 6064-90-0
- Price
- US $1.00/KG
- Min. Order
- 1KG
- Purity
- 98%
- Supply Ability
- 200kgs
- Release date
- 2020-01-10
- Product
- 4-IODO-N-METHYLANILINE 60577-34-6
- Price
- US $1.00/KG
- Min. Order
- 1KG
- Purity
- 85.0-99.8%
- Supply Ability
- 200kgs
- Release date
- 2020-01-10