3-BROMO-5-FLUOROBENZALDEHYDE

Product Name: 3-BROMO-5-FLUOROBENZALDEHYDE
CAS No.: 188813-02-7
Chemical Name: 3-BROMO-5-FLUOROBENZALDEHYDE
Synonyms: 3-FLUORO-5-BROMOBENZALDEHYDE;3-BROMO-5-FLUOROBENZALDEHYDE;Benzaldehyde, 3-bromo-5-fluoro-;3-Bromo-5-fluorobenzaldehyde98%;3-Bromo-5-fluorobenzaldehyde 98%;3-BROMO-5-FLUOROBENZALDEHYDE ISO 9001：2015 REACH
CBNumber: CB2175256
Molecular Formula: C7H4BrFO
Formula Weight: 203.01
MOL File: 188813-02-7.mol

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3-BROMO-5-FLUOROBENZALDEHYDE Property

Melting point:: 41-43℃
Boiling point:: 231.0±20.0 °C(Predicted)
Density: 1.43
storage temp.: Inert atmosphere,2-8°C
form: Solid
Appearance: White to yellow <41°C Solid,>43°C Liquid
Water Solubility: Slightly soluble in water.
Sensitive: Light Sensitive
CAS DataBase Reference: 188813-02-7(CAS DataBase Reference)

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Safety

Hazard Codes: Xi
Risk Statements: 36/37/38
Safety Statements: 26-36/37/39
HazardClass: IRRITANT
HS Code: 2913000090

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P405Store locked up.

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N-Bromosuccinimide Price

TRC

Product number: B686323
Product name: 3-Bromo-5-fluorobenzaldehyde
Packaging: 100mg
Price: $75
Updated: 2021/12/16

Matrix Scientific

Product number: 037416
Product name: 3-Bromo-5-fluorobenzaldehyde
Packaging: 5g
Price: $38
Updated: 2021/12/16

Biosynth Carbosynth

Product number: FB63996
Product name: 3-Bromo-5-fluorobenzaldehyde
Packaging: 2g
Price: $50
Updated: 2021/12/16

Apolloscientific

Product number: PC2392
Product name: 3-Bromo-5-fluorobenzaldehyde
Purity: 98%
Packaging: 5g
Price: $53
Updated: 2021/12/16

SynQuest Laboratories

Product number: 2615-B-X0
Product name: 3-Bromo-5-fluorobenzaldehyde
Purity: 98%
Packaging: 5G
Price: $58
Updated: 2021/12/16

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3-BROMO-5-FLUOROBENZALDEHYDE Chemical Properties,Usage,Production

Uses

3-Bromo-5-fluorobenzaldehyde is an intermediate in organic syntheses. Reatant in the synthesis of 3,4-diamino-3-cyclobutene-1,2-diones, 9,10-Dihydro-9,10-diboraanthracenes.

Synthesis

1435-51-4

68-12-2

188813-02-7

A 2M isopropylmagnesium chloride solution (10 mL, 20 mmol) was dissolved in 5 mL of tetrahydrofuran under ice bath conditions. To this solution was added a tetrahydrofuran solution of 1,3-dibromo-5-fluorobenzene (4.0 g, 15.70 mmol) and the reaction mixture was stirred for 2 hours. The reaction system was then warmed to 20°C and the reaction was continued for 30 minutes. After completion of the reaction, the system was cooled to 0°C, N,N-dimethylformamide (2.5 mL, 31.50 mmol) was slowly added dropwise and the reaction was stirred at this temperature for 1.5 hours. After that, the reaction mixture was stirred at room temperature for 12 hours. At the end of the reaction, the reaction was quenched by adding saturated ammonium chloride solution (20 mL). The reaction mixture was extracted with ethyl acetate (50 mL x 3), the organic phases were combined, dried over anhydrous sodium sulfate, filtered and the filtrate was concentrated under reduced pressure. Purification by silica gel column chromatography using eluent B afforded the target product 3-bromo-5-fluorobenzaldehyde (2.57 g, yellow liquid) in 81.0% yield.

References

[1] Patent: US6355648, 2002, B1. Location in patent: Page column 33-34
[2] Patent: CN103030646, 2016, B. Location in patent: Paragraph 0738; 0740-0743
[3] European Journal of Organic Chemistry, 2017, vol. 2017, # 4, p. 818 - 826
[4] Patent: US2007/88053, 2007, A1. Location in patent: Page/Page column 21
[5] Patent: CN105722823, 2016, A. Location in patent: Paragraph 0502; 0503

3-BROMO-5-FLUOROBENZALDEHYDE Preparation Products And Raw materials

Raw materials

Preparation Products

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3-BROMO-5-FLUOROBENZALDEHYDE Suppliers

China 171 Germany 1 India 4 Italy 1 Japan 1 United Kingdom 9 United States 21 Global 208

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View Lastest Price from 3-BROMO-5-FLUOROBENZALDEHYDE manufacturers

Career Henan Chemical Co

Product: 3-BROMO-5-FLUOROBENZALDEHYDE 188813-02-7
Price: US $2.00/kg
Min. Order: 1kg
Purity: 99%
Supply Ability: 100kg
Release date: 2018-12-24

188813-02-7, 3-BROMO-5-FLUOROBENZALDEHYDERelated Search:

3-Bromo-5-fluoroanisole 3-BROMO-5-FLUOROBENZALDEHYDE 3-Bromo-2,4,5-trifluorobenzoic acid METHYL 3-BROMO-5-FLUOROBENZOATE 3-Bromo-5-fluorobenzoic acid 3-BROMO-2,4,5,6-TETRAFLUOROBENZOYL CHLORIDE 2-BROMO-5-FLUOROBENZALDEHYDE 2-BROMO-6-FLUOROBENZALDEHYDE 4-Bromo-2-fluorobenzaldehyde 98%,4-Bromo-2-fluorobenzaldehyde98%,4-BROMO-2-FLUOROBENZALDEHYDE,4-Bromo-2-Fluorobenzaldehyde 2-Fluoro-4-Bromobenzaldehyde 5-Bromo-2-fluorobenzaldehyde 98%,5-Bromo-2-Fluorobenzaldehyde 2-Fluoro-5-Bromobenzaldehyde,5-Bromo-2-fluorobenzaldehyde98%,5-BROMO-2-FLUOROBENZALDEHYDE 4-BROMO-3-FLUOROBENZALDEHYDE,4-Bromo-3-fluorobenzaldehyde98%,4-Bromo-3-fluorobenzaldehyde 98% 3-Bromo-4-fluorobenzaldehyde 98%,3-Bromo-4-fluorobenzaldehyde98%,3-BROMO-4-FLUOROBENZALDEHYDE 2-BROMO-4-FLUOROBENZALDEHYDE 2-BROMO-3-FLUOROBENZALDEHYDE 2-AMINO-5-BROMO-3-FLUOROBENZOIC ACID 5-BROMO-3-FLUOROSALICYLALDEHYDE 2-AMINO-3-BROMO-5-FLUOROBENZOIC ACID 3-Bromo-5-fluorobenzoyl chloride

3-Bromo-5-fluorobenzaldehyde 98%

3-FLUORO-5-BROMOBENZALDEHYDE

3-Bromo-5-fluorobenzaldehyde98%

3-BROMO-5-FLUOROBENZALDEHYDE

Benzaldehyde, 3-bromo-5-fluoro-

3-BROMO-5-FLUOROBENZALDEHYDE ISO 9001：2015 REACH

188813-02-7

Fluorine series

Pyridine

Adehydes, Acetals & Ketones

Bromine Compounds

Fluorine Compounds