3-(Aminomethyl)pyridine
- Product Name
- 3-(Aminomethyl)pyridine
- CAS No.
- 3731-52-0
- Chemical Name
- 3-(Aminomethyl)pyridine
- Synonyms
- pyridin-3-ylmethanamine;Picolamine;3AMPY;NSC 59706;Picolamin;-Aminomethyl;3-PICOLYLAMINE;AKOS BBS-00003679;3-Picolylamine>TIMTEC-BB SBB004351
- CBNumber
- CB2284635
- Molecular Formula
- C6H8N2
- Formula Weight
- 108.14
- MOL File
- 3731-52-0.mol
3-(Aminomethyl)pyridine Property
- Melting point:
- −21 °C(lit.)
- Boiling point:
- 73-74 °C1 mm Hg(lit.)
- Density
- 1.062 g/mL at 25 °C(lit.)
- refractive index
- n20/D 1.551(lit.)
- Flash point:
- 213 °F
- storage temp.
- Keep in dark place,Sealed in dry,Room Temperature
- solubility
- soluble in Chloroform, Ethyl Acetate, Methanol
- pka
- 8.34±0.29(Predicted)
- form
- clear liquid
- color
- Colorless to Light yellow
- PH
- 11-12 (100g/l, H2O, 20℃)
- Water Solubility
- FREELY SOLUBLE
- Sensitive
- Air Sensitive
- BRN
- 108056
- CAS DataBase Reference
- 3731-52-0(CAS DataBase Reference)
- NIST Chemistry Reference
- Picolamine(3731-52-0)
- EPA Substance Registry System
- 3-Pyridinemethanamine (3731-52-0)
Safety
- Hazard Codes
- C,Xi
- Risk Statements
- 34-37-36/37/38
- Safety Statements
- 26-36/37/39-45-25-36
- RIDADR
- UN 2735 8/PG 2
- WGK Germany
- 3
- Hazard Note
- Irritant
- TSCA
- Yes
- HazardClass
- 8
- PackingGroup
- III
- HS Code
- 29333999
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Danger
- Hazard statements
-
H290May be corrosive to metals
H314Causes severe skin burns and eye damage
- Precautionary statements
-
P234Keep only in original container.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P363Wash contaminated clothing before reuse.
N-Bromosuccinimide Price
- Product number
- A65409
- Product name
- 3-Picolylamine
- Purity
- ≥99%
- Packaging
- 5g
- Price
- $31.1
- Updated
- 2024/03/01
- Product number
- A65409
- Product name
- 3-Picolylamine
- Purity
- ≥99%
- Packaging
- 100g
- Price
- $76
- Updated
- 2024/03/01
- Product number
- P0762
- Product name
- 3-Picolylamine
- Purity
- >99.0%(GC)
- Packaging
- 25mL
- Price
- $19
- Updated
- 2024/03/01
- Product number
- P0762
- Product name
- 3-Picolylamine
- Purity
- >99.0%(GC)
- Packaging
- 100mL
- Price
- $50
- Updated
- 2024/03/01
- Product number
- B23634
- Product name
- 3-(Aminomethyl)pyridine, 98+%
- Packaging
- 25g
- Price
- $45.2
- Updated
- 2024/03/01
3-(Aminomethyl)pyridine Chemical Properties,Usage,Production
Chemical Properties
CLEAR COLOURLESS TO SLIGHLY YELLOW LIQUID
Uses
It finds its application as a rubefacient.
Application
3-(Aminomethyl)pyridine can be used to prepare metal complexes. A number of complexes of cobalt(II), nickel(II) and copper(II) thiocyanates, chlorides and bromides with 3-pyridine amine were prepared and the stereochemical configurations of these complexes were deduced using spectroscopy and magnetism, and the decomposition of the complexes was studied by thermogravimetry and differential thermal analysis[2].
Synthesis
Synthesis of 3-(aminomethyl)pyridine by traceless C3-selective umpolung of 1-amidopyridin-1-ium salts?. A natural product inspired rapid access of 3-(aminomethyl)pyridine by one-pot reaction of 1-amidopyridin-1-ium salt with aminal followed by reductive cleavage of the N–N bond is developed. This C3-selective formal C–H activation of pyridine features a traceless umpolung of the 1-amidopyridin-1-ium salt toward a Mannich type C–C bond formation of the in situ generated 1-amido-2-dialkylamino-1,2-dihydropyridine intermediate[1].
References
[1] TANG P, XIAO D, WANG B. Synthesis of 3-(aminomethyl)pyridine by traceless C3-selective umpolung of 1-amidopyridin-1-ium salts?[J]. Chemical Communications, 2017. DOI:10.1039/C6CC09582H.
[2] J. R. ALLAN M. J P A D Paton. The preparation, characterisation and thermal analysis studies on complexes of cobalt(II), nickel(II), and copper(II) with 3-picolylamine[J]. Journal of Thermal Analysis and Calorimetry, 1985. DOI:10.1007/BF01913603.
3-(Aminomethyl)pyridine Preparation Products And Raw materials
Raw materials
Preparation Products
3-(Aminomethyl)pyridine Suppliers
- Tel
- --
- Fax
- --
- petr.blazek@blavo.cz
- Country
- Czech Republic
- ProdList
- 200
- Advantage
- 58
View Lastest Price from 3-(Aminomethyl)pyridine manufacturers
- Product
- Picolamine 3731-52-0
- Price
- US $122.00-1.00/KG
- Min. Order
- 1KG
- Purity
- 99%
- Supply Ability
- g-kg-tons, free sample is available
- Release date
- 2024-01-11
- Product
- 3-(Aminomethyl)pyridine 3731-52-0
- Price
- US $15.00-10.00/KG
- Min. Order
- 1KG
- Purity
- 99%+ HPLC
- Supply Ability
- Monthly supply of 1 ton
- Release date
- 2021-07-10
- Product
- 3-(Aminomethyl)pyridine 3731-52-0
- Price
- US $15.00-10.00/KG
- Min. Order
- 1KG
- Purity
- 99%+ HPLC
- Supply Ability
- Monthly supply of 1 ton
- Release date
- 2021-07-09