4-Methoxybenzylchloride

ChemicalBook > CAS DataBase List > 4-Methoxybenzylchloride

4-Methoxybenzylchloride

Product Name: 4-Methoxybenzylchloride
CAS No.: 824-94-2
Chemical Name: 4-Methoxybenzylchloride
Synonyms: PMBCl;4-METHOXYBENZYL CHLORIDE;P-METHOXYBENZYL CHLORIDE;PBMCl;4-(Chloromethyl)-1-methoxybenzene;4-Methoxybenzylchloride, stabilized, 98% 5GR;p-Anisyl chloride;NSC 172955;ANISYL CHLORIDE;AKOS BBS-00003861
CBNumber: CB3330683
Molecular Formula: C8H9ClO
Formula Weight: 156.61
MOL File: 824-94-2.mol

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4-Methoxybenzylchloride Property

Melting point:: −1 °C(lit.)
Boiling point:: 117-118 °C14 mm Hg(lit.)
Density: 1.155 g/mL at 25 °C(lit.)
refractive index: n20/D 1.548(lit.)
Flash point:: 229 °F
storage temp.: Inert atmosphere,2-8°C
solubility: Chloroform (Slightly), Ethyl Acetate (Slightly)
form: Liquid
color: Clear colorless to pale yellow
Water Solubility: slowly decomposes
Stability:: Moisture Sensitive
InChIKey: MOHYOXXOKFQHDC-UHFFFAOYSA-N
CAS DataBase Reference: 824-94-2(CAS DataBase Reference)
NIST Chemistry Reference: «alpha»-Chloro-4-methoxytoluene(824-94-2)

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Safety

Hazard Codes: C
Risk Statements: 34
Safety Statements: 26-27-36/37/39-45
RIDADR: UN 3265 8/PG 3
WGK Germany: 3
F: 10-19-21
Autoignition Temperature: 109℃
Hazard Note: Corrosive
TSCA: No
HazardClass: 8
PackingGroup: III
HS Code: 29093090

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Danger

Hazard statements

H290May be corrosive to metals

H314Causes severe skin burns and eye damage

Precautionary statements

P234Keep only in original container.

P260Do not breathe dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P390Absorb spillage to prevent material damage.

P405Store locked up.

P406Store in corrosive resistant/… container with a resistant inner liner.

P501Dispose of contents/container to..…

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N-Bromosuccinimide Price

TCI Chemical

Product number: M0676
Product name: 4-Methoxybenzyl Chloride (stabilized with Amylene)
Purity: >98.0%(GC)(T)
Packaging: 25mL
Price: $93
Updated: 2024/03/01

TCI Chemical

Product number: M0676
Product name: 4-Methoxybenzyl Chloride (stabilized with Amylene)
Purity: min. 98.0 %
Packaging: 100ML
Price: $267
Updated: 2024/03/01

TRC

Product number: M261105
Product name: 4-MethoxybenzylChloride(Stabilized)
Packaging: 5g
Price: $95
Updated: 2021/12/16

Chem-Impex

Product number: 00213
Product name: 4-Methoxybenzyl chloride,Contains Potassium carbonate as stabilizer.
Purity: ≥ 99% (GC)
Packaging: 100G
Price: $120
Updated: 2021/12/16

AK Scientific

Product number: K468
Product name: 4-Methoxybenzylchloride,contains1%potassiumcarbonateasstabilizer
Packaging: 100g
Price: $154
Updated: 2021/12/16

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4-Methoxybenzylchloride Chemical Properties,Usage,Production

Chemical Properties

Colorless liquid

Uses

O/N protecting group reagent which can be mildly oxidatively cleaved, e.g., with ceric ammonium nitrate.

Synthesis Reference(s)

Journal of Medicinal Chemistry, 20, p. 190, 1977 DOI: 10.1021/jm00212a002
The Journal of Organic Chemistry, 53, p. 3634, 1988 DOI: 10.1021/jo00250a048

General Description

4-Methoxybenzyl chloride undergoes mild oxidative claevage with ceric ammonium nitrate.

Purification Methods

Purify 4-anisyl chloride by fractional distillation under vacuum, and the middle fraction is redistilled at 10-6 mm at room temperature by intermittent cooling of the receiver in liquid N2, and the middle fraction is collected. [Mohammed & Kosower J Am Chem Soc 93 2709 1971, Beilstein 6 IV 2137.]

4-Methoxybenzylchloride Preparation Products And Raw materials

Raw materials

Preparation Products

4-Methoxybenzyl cyanide

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View Lastest Price from 4-Methoxybenzylchloride manufacturers

Wuhan Circle Star Chem-medical Technology Co.,Ltd

Product: 4-Methoxybenzylchloride 824-94-2
Price: US $0.00-0.00/kg
Min. Order: 1kg
Purity: 98
Supply Ability: 1000
Release date: 2025-01-13

Hebei Chuanghai Biotechnology Co,.LTD

Product: 4-Methoxybenzylchloride 824-94-2
Price: US $5.00-2.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 10000kg
Release date: 2024-08-23

Henan Fengda Chemical Co., Ltd

Product: 4-Methoxybenzylchloride 824-94-2
Price: US $10.00-1.00/kg
Min. Order: 1kg
Purity: 99%
Supply Ability: g-kg-tons, free sample is available
Release date: 2024-04-08

824-94-2, 4-MethoxybenzylchlorideRelated Search:

4-Methoxybenzoyl chloride 4-Fluorobenzyl chloride Anisole 2-Chlorobenzyl chloride 1,2-Dichloro-4-(chloromethyl)benzene 4-Methoxybenzyl alcohol 4-Methoxybenzylamine 4-Chlorobenzyl cyanide 4-Nitrobenzyl chloroformate 4-Chlorobenzyl chloride Benzyl chloroformate 3-Bromoanisole 4-Methylbenzyl chloride 4'-Methoxyacetophenone 4-Methoxybenzyl cyanide Methoxypropiophenone 4-Formylbenzoic acid 4-Methoxyphenethylamine

P-METHOXYBENZYL CHLORIDE

alpha-Chloro-4-methoxytoluene

Anisole, p-(chloromethyl)-

Benzene, 1-(chloromethyl)-4-methoxy-

p-(Chloromethyl)anisole

p-Anisyl chloride

4-Methoxybenzylchloride, stabilized, 98% 5GR

Anisyl Chloride 4-(Chloromethyl)anisole

4-Methoxybenzyl chloride contains potassiuM carbonate as stabilizer, 98%

The Methoxy benzyl chloride

para-chloromethylanisole

4-Methoxybenzyl chloride, 98%, stabilized with potassium carbonate

PMBCl

4-Methoxybenzyl chloride, 98% (Stabilized with Calcium carbote)

METHOXYBENZYLCHLORIDE(P-)

1-CHLOROMETHYL-4-METHOXYBENZENE

AKOS BBS-00003861

ANISYL CHLORIDE

4-METHOXYBENZYL CHLORIDE

4-(CHLOROMETHYL)ANISOL

4-(CHLOROMETHYL)ANISOLE

P-methoxyl benzylchloride

4-Methoxybenzylchloride99%

4-Methoxybenzylchloride 99%

4-Methoxybenzene methyl chloride

α-Chloro-4-methoxytoluene

4-Methoxybenzylchloride, stabilized, 98%

4-METHOXYBENZYL CHLORIDE (STABILIZED WITH CALCIUM CARBONATE)

4-METHYOXYBENZYL CHLORIDE

4-METHOXYBENZYLCHLORIDE / 4-(CHLOROMETHYL)ANISOLE

4) PARA METHOXY BENZYL CHLORIDE

1-(Chloromethyl)-4-methoxybenzene, 4-(Chloromethyl)anisole

4-Methoxybenzyl Chloride (stabilized with Amylene)

4-Methoxybenzylchloride, 98%, stabilized

4-Chloromethylphenyl methyl ether

4-Methoxy-1-(chloromethyl)benzene

4-Methoxybenzylchloride ,98%

4-Methoxybenzylchlor

4-Methoxybenzylchloride, stabilized, 98% 25GR

4-Methoxybenzyl chloride, 98%, for synthesis

4-MethoxybenzylChloride(stabilizedwithAmylene)&gt

4-methoxychlorobenzyl

1-(Chloromethyl)-4-(methyloxy)benzene

4-(Chloromethyl)-1-methoxybenzene

4-(Chloromethyl)anisole (stabilized with Amylene)

4-Methyloxybenzyl chloride

Anisyl Chloride (stabilized with Amylene)

NSC 172955

p-(Chloromethyl)(methoxy)benzene

PBMCl

α-Chloro-4-methoxytoluene

α-Chloro-p-methoxytoluene

p-methoxychlorbenzyl

4-Methoxy Benzyl chloride, contains 1% potassium carbonate as stabilizer, 95%

4-Methoxybenzyl Chloride (stabilized with Potassium carbonate)

Monensin Impurity 4

824-94-2

C8H9ClO