4-Methoxybenzylchloride
- Product Name
- 4-Methoxybenzylchloride
- CAS No.
- 824-94-2
- Chemical Name
- 4-Methoxybenzylchloride
- Synonyms
- PMBCl;4-METHOXYBENZYL CHLORIDE;P-METHOXYBENZYL CHLORIDE;PBMCl;4-(Chloromethyl)-1-methoxybenzene;4-Methoxybenzylchloride, stabilized, 98% 5GR;p-Anisyl chloride;NSC 172955;ANISYL CHLORIDE;AKOS BBS-00003861
- CBNumber
- CB3330683
- Molecular Formula
- C8H9ClO
- Formula Weight
- 156.61
- MOL File
- 824-94-2.mol
4-Methoxybenzylchloride Property
- Melting point:
- −1 °C(lit.)
- Boiling point:
- 117-118 °C14 mm Hg(lit.)
- Density
- 1.155 g/mL at 25 °C(lit.)
- refractive index
- n20/D 1.548(lit.)
- Flash point:
- 229 °F
- storage temp.
- Inert atmosphere,2-8°C
- solubility
- Chloroform (Slightly), Ethyl Acetate (Slightly)
- form
- Liquid
- color
- Clear colorless to pale yellow
- Water Solubility
- slowly decomposes
- Stability:
- Moisture Sensitive
- InChIKey
- MOHYOXXOKFQHDC-UHFFFAOYSA-N
- CAS DataBase Reference
- 824-94-2(CAS DataBase Reference)
- NIST Chemistry Reference
- «alpha»-Chloro-4-methoxytoluene(824-94-2)
Safety
- Hazard Codes
- C
- Risk Statements
- 34
- Safety Statements
- 26-27-36/37/39-45
- RIDADR
- UN 3265 8/PG 3
- WGK Germany
- 3
- F
- 10-19-21
- Autoignition Temperature
- 109℃
- Hazard Note
- Corrosive
- TSCA
- No
- HazardClass
- 8
- PackingGroup
- III
- HS Code
- 29093090
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Danger
- Hazard statements
-
H290May be corrosive to metals
H314Causes severe skin burns and eye damage
- Precautionary statements
-
P234Keep only in original container.
P260Do not breathe dust/fume/gas/mist/vapours/spray.
P264Wash hands thoroughly after handling.
P264Wash skin thouroughly after handling.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P390Absorb spillage to prevent material damage.
P405Store locked up.
P406Store in corrosive resistant/… container with a resistant inner liner.
P501Dispose of contents/container to..…
N-Bromosuccinimide Price
- Product number
- M0676
- Product name
- 4-Methoxybenzyl Chloride (stabilized with Amylene)
- Purity
- >98.0%(GC)(T)
- Packaging
- 25mL
- Price
- $93
- Updated
- 2024/03/01
- Product number
- M0676
- Product name
- 4-Methoxybenzyl Chloride (stabilized with Amylene)
- Purity
- min. 98.0 %
- Packaging
- 100ML
- Price
- $267
- Updated
- 2024/03/01
- Product number
- M261105
- Product name
- 4-MethoxybenzylChloride(Stabilized)
- Packaging
- 5g
- Price
- $95
- Updated
- 2021/12/16
- Product number
- 00213
- Product name
- 4-Methoxybenzyl chloride,Contains Potassium carbonate as stabilizer.
- Purity
- ≥ 99% (GC)
- Packaging
- 100G
- Price
- $120
- Updated
- 2021/12/16
- Product number
- K468
- Product name
- 4-Methoxybenzylchloride,contains1%potassiumcarbonateasstabilizer
- Packaging
- 100g
- Price
- $154
- Updated
- 2021/12/16
4-Methoxybenzylchloride Chemical Properties,Usage,Production
Chemical Properties
Colorless liquid
Uses
O/N protecting group reagent which can be mildly oxidatively cleaved, e.g., with ceric ammonium nitrate.
Synthesis Reference(s)
Journal of Medicinal Chemistry, 20, p. 190, 1977 DOI: 10.1021/jm00212a002
The Journal of Organic Chemistry, 53, p. 3634, 1988 DOI: 10.1021/jo00250a048
General Description
4-Methoxybenzyl chloride undergoes mild oxidative claevage with ceric ammonium nitrate.
Purification Methods
Purify 4-anisyl chloride by fractional distillation under vacuum, and the middle fraction is redistilled at 10-6 mm at room temperature by intermittent cooling of the receiver in liquid N2, and the middle fraction is collected. [Mohammed & Kosower J Am Chem Soc 93 2709 1971, Beilstein 6 IV 2137.]
4-Methoxybenzylchloride Preparation Products And Raw materials
Raw materials
Preparation Products
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View Lastest Price from 4-Methoxybenzylchloride manufacturers
- Product
- 4-Methoxybenzylchloride 824-94-2
- Price
- US $10.00-1.00/kg
- Min. Order
- 1kg
- Purity
- 99%
- Supply Ability
- g-kg-tons, free sample is available
- Release date
- 2024-04-08
- Product
- 4-Methoxybenzylchloride 824-94-2
- Price
- US $100.00/kg
- Min. Order
- 1kg
- Purity
- 99%
- Supply Ability
- 500t/month
- Release date
- 2023-07-25
- Product
- 4-Methoxybenzylchloride 824-94-2
- Price
- US $5.00-2.00/KG
- Min. Order
- 1KG
- Purity
- 99%
- Supply Ability
- 10000kg
- Release date
- 2023-04-17