ChemicalBook > CAS DataBase List > 4-Methoxybenzylchloride

4-Methoxybenzylchloride

Product Name
4-Methoxybenzylchloride
CAS No.
824-94-2
Chemical Name
4-Methoxybenzylchloride
Synonyms
PMBCl;4-METHOXYBENZYL CHLORIDE;P-METHOXYBENZYL CHLORIDE;PBMCl;4-(Chloromethyl)-1-methoxybenzene;4-Methoxybenzylchloride, stabilized, 98% 5GR;p-Anisyl chloride;NSC 172955;ANISYL CHLORIDE;AKOS BBS-00003861
CBNumber
CB3330683
Molecular Formula
C8H9ClO
Formula Weight
156.61
MOL File
824-94-2.mol
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4-Methoxybenzylchloride Property

Melting point:
−1 °C(lit.)
Boiling point:
117-118 °C14 mm Hg(lit.)
Density 
1.155 g/mL at 25 °C(lit.)
refractive index 
n20/D 1.548(lit.)
Flash point:
229 °F
storage temp. 
Inert atmosphere,2-8°C
solubility 
Chloroform (Slightly), Ethyl Acetate (Slightly)
form 
Liquid
color 
Clear colorless to pale yellow
Water Solubility 
slowly decomposes
Stability:
Moisture Sensitive
InChIKey
MOHYOXXOKFQHDC-UHFFFAOYSA-N
CAS DataBase Reference
824-94-2(CAS DataBase Reference)
NIST Chemistry Reference
«alpha»-Chloro-4-methoxytoluene(824-94-2)
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Safety

Hazard Codes 
C
Risk Statements 
34
Safety Statements 
26-27-36/37/39-45
RIDADR 
UN 3265 8/PG 3
WGK Germany 
3
F 
10-19-21
Autoignition Temperature
109℃
Hazard Note 
Corrosive
TSCA 
No
HazardClass 
8
PackingGroup 
III
HS Code 
29093090
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H290May be corrosive to metals

H314Causes severe skin burns and eye damage

Precautionary statements

P234Keep only in original container.

P260Do not breathe dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P390Absorb spillage to prevent material damage.

P405Store locked up.

P406Store in corrosive resistant/… container with a resistant inner liner.

P501Dispose of contents/container to..…

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N-Bromosuccinimide Price

TCI Chemical
Product number
M0676
Product name
4-Methoxybenzyl Chloride (stabilized with Amylene)
Purity
>98.0%(GC)(T)
Packaging
25mL
Price
$93
Updated
2024/03/01
TCI Chemical
Product number
M0676
Product name
4-Methoxybenzyl Chloride (stabilized with Amylene)
Purity
min. 98.0 %
Packaging
100ML
Price
$267
Updated
2024/03/01
TRC
Product number
M261105
Product name
4-MethoxybenzylChloride(Stabilized)
Packaging
5g
Price
$95
Updated
2021/12/16
Chem-Impex
Product number
00213
Product name
4-Methoxybenzyl chloride,Contains Potassium carbonate as stabilizer.
Purity
≥ 99% (GC)
Packaging
100G
Price
$120
Updated
2021/12/16
AK Scientific
Product number
K468
Product name
4-Methoxybenzylchloride,contains1%potassiumcarbonateasstabilizer
Packaging
100g
Price
$154
Updated
2021/12/16
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4-Methoxybenzylchloride Chemical Properties,Usage,Production

Chemical Properties

Colorless liquid

Uses

O/N protecting group reagent which can be mildly oxidatively cleaved, e.g., with ceric ammonium nitrate.

Synthesis Reference(s)

Journal of Medicinal Chemistry, 20, p. 190, 1977 DOI: 10.1021/jm00212a002
The Journal of Organic Chemistry, 53, p. 3634, 1988 DOI: 10.1021/jo00250a048

General Description

4-Methoxybenzyl chloride undergoes mild oxidative claevage with ceric ammonium nitrate.

Purification Methods

Purify 4-anisyl chloride by fractional distillation under vacuum, and the middle fraction is redistilled at 10-6 mm at room temperature by intermittent cooling of the receiver in liquid N2, and the middle fraction is collected. [Mohammed & Kosower J Am Chem Soc 93 2709 1971, Beilstein 6 IV 2137.]

4-Methoxybenzylchloride Preparation Products And Raw materials

Raw materials

Preparation Products

4-Methoxybenzyl cyanide
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4-Methoxybenzylchloride Suppliers

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View Lastest Price from 4-Methoxybenzylchloride manufacturers

Wuhan Circle Star Chem-medical Technology Co.,Ltd
Product
4-Methoxybenzylchloride 824-94-2
Price
US $0.00-0.00/kg
Min. Order
1kg
Purity
98
Supply Ability
1000
Release date
2025-01-13
Hebei Chuanghai Biotechnology Co,.LTD
Product
4-Methoxybenzylchloride 824-94-2
Price
US $5.00-2.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
10000kg
Release date
2024-08-23
Henan Fengda Chemical Co., Ltd
Product
4-Methoxybenzylchloride 824-94-2
Price
US $10.00-1.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
g-kg-tons, free sample is available
Release date
2024-04-08

824-94-2, 4-MethoxybenzylchlorideRelated Search:

4-Methoxybenzoyl chloride 4-Fluorobenzyl chloride Anisole 2-Chlorobenzyl chloride 1,2-Dichloro-4-(chloromethyl)benzene 4-Methoxybenzyl alcohol 4-Methoxybenzylamine 4-Chlorobenzyl cyanide 4-Nitrobenzyl chloroformate 4-Chlorobenzyl chloride Benzyl chloroformate 3-Bromoanisole 4-Methylbenzyl chloride 4'-Methoxyacetophenone 4-Methoxybenzyl cyanide Methoxypropiophenone 4-Formylbenzoic acid 4-Methoxyphenethylamine

  • P-METHOXYBENZYL CHLORIDE
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  • METHOXYBENZYLCHLORIDE(P-)
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  • AKOS BBS-00003861
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  • 4-(CHLOROMETHYL)ANISOLE
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  • 4-Methoxybenzylchloride 99%
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  • 4-METHOXYBENZYL CHLORIDE (STABILIZED WITH CALCIUM CARBONATE)
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  • 4) PARA METHOXY BENZYL CHLORIDE
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  • 4-Methoxybenzyl Chloride (stabilized with Amylene)
  • 4-Methoxybenzylchloride, 98%, stabilized
  • 4-Chloromethylphenyl methyl ether
  • 4-Methoxy-1-(chloromethyl)benzene
  • 4-Methoxybenzylchloride ,98%
  • 4-Methoxybenzylchlor
  • 4-Methoxybenzylchloride, stabilized, 98% 25GR
  • 4-Methoxybenzyl chloride, 98%, for synthesis
  • 4-MethoxybenzylChloride(stabilizedwithAmylene)&gt
  • 4-methoxychlorobenzyl
  • 1-(Chloromethyl)-4-(methyloxy)benzene
  • 4-(Chloromethyl)-1-methoxybenzene
  • 4-(Chloromethyl)anisole (stabilized with Amylene)
  • 4-Methyloxybenzyl chloride
  • Anisyl Chloride (stabilized with Amylene)
  • NSC 172955
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  • PBMCl
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  • α-Chloro-p-methoxytoluene
  • p-methoxychlorbenzyl
  • 4-Methoxy Benzyl chloride, contains 1% potassium carbonate as stabilizer, 95%
  • 4-Methoxybenzyl Chloride (stabilized with Potassium carbonate)
  • Monensin Impurity 4
  • 824-94-2
  • C8H9ClO