Reactions
ChemicalBook > CAS DataBase List > Titanium tetraisopropanolate

Titanium tetraisopropanolate

Reactions
Product Name
Titanium tetraisopropanolate
CAS No.
546-68-9
Chemical Name
Titanium tetraisopropanolate
Synonyms
TITANIUM ISOPROPOXIDE;TITANIUM(IV) ISOPROPOXIDE;TITANIUM TETRAISOPROPOXIDE;TTIP;tetraisopropoxytitanium;TETRAISOPROPYL TITANATE;ISOPROPYL TITANATE;Titanium(Ⅳ) isopropoxide;TETRAISOPROPYL ORTHOTITANATE;TITANIUM(IV) TETRAISOPROPOXIDE
CBNumber
CB3363214
Molecular Formula
C12H28O4Ti
Formula Weight
284.22
MOL File
546-68-9.mol
More
Less

Titanium tetraisopropanolate Property

Melting point:
14-17 °C(lit.)
Boiling point:
232 °C(lit.)
Density 
0.96 g/mL at 20 °C(lit.)
vapor pressure 
60.2hPa at 25℃
refractive index 
n20/D 1.464(lit.)
Flash point:
72 °F
storage temp. 
Flammables area
solubility 
Soluble in anhydrous ethanol, ether, benzene and chloroform.
form 
Liquid
Specific Gravity
0.955
color 
Colorless to pale yellow
Water Solubility 
HYDROLYSIS
FreezingPoint 
14.8℃
Sensitive 
Moisture Sensitive
Hydrolytic Sensitivity
7: reacts slowly with moisture/water
Merck 
14,9480
BRN 
3679474
Stability:
Stable, but decomposes in the presence of moisture. Incompatible with aqueous solutions, strong acids, strong oxidizing agents. Flammable.
InChIKey
VXUYXOFXAQZZMF-UHFFFAOYSA-N
LogP
0.05
CAS DataBase Reference
546-68-9(CAS DataBase Reference)
EPA Substance Registry System
2-Propanol, titanium(4+) salt (546-68-9)
More
Less

Safety

Hazard Codes 
Xi,F
Risk Statements 
10-36-36/37/38-11-67
Safety Statements 
16-26-36/37/39-7/9
RIDADR 
UN 2413 3/PG 3
WGK Germany 
2
RTECS 
NT8060000
F 
21
TSCA 
Yes
HazardClass 
3
PackingGroup 
III
HS Code 
29051900
Hazardous Substances Data
546-68-9(Hazardous Substances Data)
More
Less

Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H226Flammable liquid and vapour

H319Causes serious eye irritation

H336May cause drowsiness or dizziness

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P233Keep container tightly closed.

P240Ground/bond container and receiving equipment.

P241Use explosion-proof electrical/ventilating/lighting/…/equipment.

P242Use only non-sparking tools.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

More
Less

N-Bromosuccinimide Price

Sigma-Aldrich
Product number
205273
Product name
Titanium(IV) isopropoxide
Purity
97%
Packaging
1l
Price
$145
Updated
2024/03/01
Sigma-Aldrich
Product number
205273
Product name
Titanium(IV) isopropoxide
Purity
97%
Packaging
2l
Price
$263
Updated
2024/03/01
TCI Chemical
Product number
T0133
Product name
Tetraisopropyl Orthotitanate
Packaging
25g
Price
$17
Updated
2024/03/01
TCI Chemical
Product number
T0133
Product name
Tetraisopropyl Orthotitanate
Packaging
500g
Price
$49
Updated
2024/03/01
Alfa Aesar
Product number
077115
Product name
Titanium(IV) isopropoxide, 97+%
Packaging
10g
Price
$31.65
Updated
2024/03/01
More
Less

Titanium tetraisopropanolate Chemical Properties,Usage,Production

Reactions

  • Catalyst for the synthesis of acyclic epoxy alcohols and allylic epoxy alcohols.
  • Useful for diastereoselective reduction of alpha-fluoroketones.
  • Catalyzes the asymmetric allylation of ketones.
  • Reagent for the synthesis of cyclopropylamines from aryl and alkenyl nitriles.
  • Useful for racemic and/or enantioselective addition of nucleophiles to aldehydes, ketones and imines.
  • Catalytic intramolecular formal [3+2] cycloaddition.
  • Catalyst for the synthesis of cyclopropanols from esters and organomagnesium reagents

Chemical Properties

colourless to light yellow liquid

Uses

Catalyst especially for asymmetric induction in organic syntheses; in preparation of nanosized TiO2. Complexing agent in sol-gel process.

Uses

Titanium(IV) isopropoxide is used as a precursor for the preparation of titanium and barium-strontium-titanate thin films. It is useful to make porous titanosilicates and potential ion-exchange materials for cleanup of radioactive wastes. It is an active component of Sharpless epoxidation as well as involved in the synthesis of chiral epoxides. In Kulinkovich reaction, it is involved as a catalyst in the preparation of cyclopropanes.

Definition

ChEBI: Titanium(IV) isopropoxide is a titanium coordination entity consisting of a titanium(IV) cation with four propan-2-olate anions as counterions.

General Description

Tetraisopropyl titanate appears as a water-white to pale-yellow liquid with an odor like isopropyl alcohol. About the same density as water. Vapors heavier than air.

Air & Water Reactions

Highly flammable. Fumes in air. Soluble in water. Decomposes rapidly in water to form flammable isopropyl alcohol.

Reactivity Profile

Metal alkyls, such as TETRAISOPROPYL TITANATE, are reducing agents and react rapidly and dangerously with oxygen and with other oxidizing agents, even weak ones. Thus, they are likely to ignite on contact with alcohols.

Health Hazard

Inhalation or contact with material may irritate or burn skin and eyes. Fire may produce irritating, corrosive and/or toxic gases. Vapors may cause dizziness or suffocation. Runoff from fire control or dilution water may cause pollution.

Flammability and Explosibility

Flammable

Purification Methods

Dissolve it in dry *C6H6 , filter if a solid separates, evaporate and fractionate. It is hydrolysed by H2O to give solid Ti2O(iso-OPr)2 m ca 48o. [Bradley et al. J Chem Soc 2027, 1952, Bradley et al. J Chem Soc 469 1957, Beilstein 1 II 328, 1 IV 1469S.]

Titanium tetraisopropanolate Preparation Products And Raw materials

Raw materials

(S)-tert-Butyl 6-amino-2-((tert-butoxycarbonyl)amino)hexanoate hydrochloride Toluene Titanium tetrachloride Isopropyl alcohol

Preparation Products

3-PHENOXYBENZALDEHYDE CYANOHYDRIN 2,3-DIHYDROXYPROPYL METHACRYLATE 6-FLUORO-1H-PYRAZOLO[3,4-B]PYRIDINE-3-CARBONITRILE 6-FLUORO-1H-PYRAZOLO[3,4-B]PYRIDINE-3-CARBOXYLIC ACID Ti(BINOL)complex (+)-DISPARLURE
More
Less

Titanium tetraisopropanolate Suppliers

Belgium 4 China 297 Europe 2 France 2 Germany 13 India 35 Italy 1 Japan 9 Singapore 1 Switzerland 1 United Kingdom 11 United States 44 Global 420
HBCChem, Inc.
Tel
+1-510-219-6317
Fax
+1-650-486-1361
Email
sales@hbcchem.com
Country
United States
ProdList
10648
Advantage
60
Aladdin Scientific
Tel
+1-+1(833)-552-7181
Email
sales@aladdinsci.com
Country
United States
ProdList
57505
Advantage
58
Alfa Chemistry
Tel
--
Fax
--
Email
info@Alfa-Chemistry.com
Country
United States
ProdList
6814
Advantage
0
Accela ChemBio Inc.
Tel
--
Fax
--
Email
info@accelachem.com
Country
United States
ProdList
1054
Advantage
50
Ereztech LLC
Tel
--
Fax
--
Email
customerservice@ereztech.com
Country
United States
ProdList
793
Advantage
58
Wintersun International Inc.
Tel
--
Fax
--
Email
orders@wintersunchem.com
Country
United States
ProdList
191
Advantage
58
Roopal Products, Inc.
Tel
--
Fax
--
Email
info@roopalproducts.com
Country
United States
ProdList
2
Advantage
58
Wego Chemical Group
Tel
--
Fax
--
Email
sales@wegochem.com
Country
United States
ProdList
443
Advantage
58
Redox Scientific
Tel
--
Fax
--
Email
info@redoxsci.com
Country
United States
ProdList
2380
Advantage
58
MilliporeSigma (Sigma-Aldrich Corp.)
Tel
--
Fax
--
Email
@sial.com
Country
United States
ProdList
5414
Advantage
58
GFS Chemicals, Inc.
Tel
--
Fax
--
Email
Development@gfschemicals.com
Country
United States
ProdList
338
Advantage
58
VWR International, LLC.
Tel
--
Fax
--
Email
@sargentwelch.com
Country
United States
ProdList
6262
Advantage
58
TCI America, Inc. (part of Tokyo Chemical Industry)
Tel
--
Fax
--
Email
Angelina.Crew@tcichemicals.com
Country
United States
ProdList
2053
Advantage
58
Oakwood Products, Inc.
Tel
--
Fax
--
Email
sales@oakwoodchemical.com
Country
United States
ProdList
6193
Advantage
74
Strem Chemicals, Inc.
Tel
--
Fax
--
Email
info@strem.com
Country
United States
ProdList
4910
Advantage
86
United States Biological
Tel
--
Fax
--
Email
chemicals@usbio.net
Country
United States
ProdList
6214
Advantage
80
Combi-Blocks Inc.
Tel
--
Fax
--
Email
sales@combi-blocks.com
Country
United States
ProdList
6618
Advantage
69
Rare Earth Products Inc
Tel
--
Fax
--
Email
sales@rareearthproducts.com
Country
United States
ProdList
1095
Advantage
58
GFS Chemicals Inc
Tel
--
Fax
--
Email
service@gfschemicals.com
Country
United States
ProdList
2329
Advantage
58
Riedel-de Haen AG
Tel
--
Fax
--
Country
United States
ProdList
6773
Advantage
87
TCI America
Tel
--
Fax
--
Email
sales@tciamerica.com
Country
United States
ProdList
6909
Advantage
75
Matrix Scientific
Tel
--
Fax
--
Email
sales@matrixscientific.com
Country
United States
ProdList
6632
Advantage
80
AK Scientific, Inc.
Tel
--
Fax
--
Email
sales@aksci.com
Country
United States
ProdList
6347
Advantage
65
Anvia Chemicals, LLC
Tel
--
Fax
--
Email
sales@anviachem.com
Country
United States
ProdList
3933
Advantage
0
Ereztech LLC
Tel
--
Fax
--
Email
sales@ereztech.com
Country
United States
ProdList
450
Advantage
0
HBCChem Inc.
Tel
--
Fax
--
Email
sales@hbcchem-inc.com
Country
United States
ProdList
4569
Advantage
30
Waterstone Technology, LLC
Tel
--
Fax
--
Email
sales@waterstonetech.com
Country
United States
ProdList
6786
Advantage
30
ProChem, Inc.
Tel
--
Fax
--
Email
prochem1@aol.com
Country
United States
ProdList
1691
Advantage
66
ChemService Inc.
Tel
--
Fax
--
Country
United States
ProdList
6379
Advantage
68
Advanced Synthesis Technologies
Tel
--
Fax
--
Email
sales@advancedsynthesis.com
Country
United States
ProdList
4775
Advantage
61
Pfaltz & Bauer, Inc.
Tel
--
Fax
--
Email
sales@pfaltzandbauer.com
Country
United States
ProdList
6828
Advantage
72
Gelest, Inc.
Tel
--
Fax
--
Email
info@gelest.com
Country
United States
ProdList
3973
Advantage
84
Alfa Aesar
Tel
--
Fax
--
Email
tech@alfa.com
Country
United States
ProdList
6814
Advantage
81
2A PharmaChem USA
Tel
--
Fax
--
Email
sales@2apharmachem.com
Country
United States
ProdList
6137
Advantage
39
HONEST JOY HOLDINGS LIMITED
Tel
--
Fax
--
Email
sales@honestjoy.cn
Country
United States
ProdList
6675
Advantage
54
City Chemical LLC
Tel
--
Fax
--
Email
sales@citychemical.com
Country
United States
ProdList
6708
Advantage
72
3B Scientific Corporation
Tel
--
Fax
--
Email
sales@3bsc.com
Country
United States
ProdList
6718
Advantage
47
Aceto Corporation
Tel
--
Fax
--
Email
contact@aceto.com
Country
United States
ProdList
2619
Advantage
75
City Chemicals Corporation
Tel
--
Fax
--
Country
United States
ProdList
6460
Advantage
72
Aithaca Chemical Corp.
Tel
--
Fax
--
Email
sales@aithaca.com
Country
United States
ProdList
1684
Advantage
30
GFS Chemicals
Tel
--
Fax
--
Email
gfschem@gfschemicals.com
Country
United States
ProdList
3403
Advantage
75
Chemat Technology, Inc.
Tel
--
Fax
--
Email
info@chemat.com
Country
United States
ProdList
569
Advantage
72
ChemPacific Corporation
Tel
--
Fax
--
Email
sales@chempacific.com
Country
United States
ProdList
6891
Advantage
51
Davos Chemical Corporation
Tel
--
Fax
--
Email
info@davos.com
Country
United States
ProdList
1640
Advantage
65
More
Less

View Lastest Price from Titanium tetraisopropanolate manufacturers

Hebei Yanxi Chemical Co., Ltd.
Product
Titanium tetraisopropanolate 546-68-9
Price
US $50.00/kg
Min. Order
1kg
Purity
0.99
Supply Ability
10000
Release date
2023-11-01
Hebei Weibang Biotechnology Co., Ltd
Product
Titanium tetraisopropanolate 546-68-9
Price
US $1.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
10 mt
Release date
2024-10-24
Hebei Chuanghai Biotechnology Co,.LTD
Product
Tetra Isopropyl Titanate 546-68-9
Price
US $19.00/KG
Min. Order
1KG
Purity
99.%
Supply Ability
10 ton
Release date
2024-08-15

546-68-9, Titanium tetraisopropanolateRelated Search:

TITANIUM ISOBUTOXIDE Rutile Chloromethyl isopropyl carbonate TITANIUM Isopropyl palmitate Isopropyl salicylate Isopropyl isocyanate Diisopropyl azodicarboxylate Isopropyl myristate Isopropyl acetate Tetrabutyl titanate (R)-Glycidyl butyrate Titanium ethoxide Tazobactam Diphenylmethyl Ester Titanium propoxide Titanium ethylhexoxide Titanium tetrachloride Diethyl carbonate

  • ISOPROPYL TITANATE
  • ISOPROPYL TITANATE(IV)
  • TITANIUM ISOPROPOXIDE
  • TITANIUM ISO-PROPYLATE
  • TITANIUM (IV) I-PROPOXIDE
  • TITANIUM(IV) ISOPROPOXIDE
  • TITANIUM (IV) TETRA-I-PROPOXIDE
  • TITANIUM(IV) TETRAISOPROPOXIDE
  • Titanium tetraisopropanolate
  • TITANIUM TETRAISOPROPOXIDE
  • TITANIUM TETRAISOPROPYLATE
  • TITANIUM(+4)ISOPROPOXIDE
  • TITANIC ACID TETRAISOPROPYL ESTER
  • TETRAISOPROPYL TITANATE
  • TETRAISOPROPYL ORTHOTITANATE
  • ORTHOTITANIC ACID TETRAISOPROPYL ESTER
  • VERTEC(TM) TIPT
  • TYZOR(R) ORGANIC TITANATE
  • Titanium(4+) tetrapropan-2-olate
  • tetraisopropoxidetitanium
  • tetraisopropoxytitanium
  • tetraisopropyltitanate(flammableliquids,n.o.s.)
  • tetrakis(1-methylethoxy)-titaniu
  • tetrakis(isopropoxy)titanium
  • tiisopropylate
  • titanic(iv)acid,tetraisopropylester
  • Titanium(IV) isopropoxide, 99.999% metals basis
  • TITANIUM(IV) ISOPROPOXIDE, FOR CAMBRIDG&
  • Tetra-#niso-propyl orthotitanate
  • Titanium(IV)isopropoxide,95%
  • Titanium(IV)isopropoxide,99.995%(metalsbasis)
  • Titanium(IV) isopropoxide, 98+%
  • Titanium(IV)i-propoxide,min.98%
  • titanium(iv) isopropoxide, vertec
  • TETRA-ISO-PROPYL-O-TITANATE
  • Titantetraisopropanolat
  • 2-Propanol, titanium salt
  • Titanium(IV) isopropoxide, VERTEC(R) TIPT, 97+%
  • Isopropyl titanate(IV): (Titanium(IV) isopropoxide)
  • Titanium (IV) isopropoxide, 97% min
  • Titanium(IV) isopropoxide, VERTEC TIPT, 97+%
  • Iso-propy titanate
  • Tetraisopropoxytitanium(IV)
  • Titanium(IV) i-propoxide, min. 98%
  • Titanium(IV) isopropoxide, 99.995% trace metals basis
  • Tetraisopropyl Titanate(monomer) 〔Titanium(Ⅳ) Isopropoxide〕
  • Titanium(IV) isopropoxide (Tetra isopropyl titanate)
  • Titanium(IV) i-propoxide, min. 98%, 93-2216, contained in 50 ml Swagelok(R) cylinder (96-1070) for CVD/ALD
  • TTIP: Ti[OCH(CH3)2]4
  • A-1(TPT)
  • TYZOR TP
  • Titanium(IV) i-propoxide, min. 98%, 93-2216, contained in 50 ml Swagelok cylinder (96-1070) for CVD/ALD
  • TITANIUM ISOPROPOXIDETITANIUM ISOPROPOXIDETITANIUM ISOPROPOXIDE
  • Titanium(IV) isopropoxide, 97+%
  • titanicacidisopropylester
  • titanium(4+)salt
  • titaniumisopropoxide(ti(oc3h7)4)
  • Titaniumispropoxide