3-Nitrobenzyl bromide

Product Name: 3-Nitrobenzyl bromide
CAS No.: 3958-57-4
Chemical Name: 3-Nitrobenzyl bromide
Synonyms: 1-(Bromomethyl)-3-nitrobenzene;NSC 66499;3-Nitrobromobenzyl;3-Nitrobenzyl bromid;M-NITROBENZYL BROMIDE;3-NITROBENZYL BROMIDE;α-Bromo-3-nitrotoluene;A-BROMO-M-NITROTOLUENE;a-Bromo-3-nitrotoluene;à-bromo-3-nitrotoluene
CBNumber: CB3402571
Molecular Formula: C7H6BrNO2
Formula Weight: 216.03
MOL File: 3958-57-4.mol

More

Less

3-Nitrobenzyl bromide Property

Melting point:: 58-59 °C(lit.)
Boiling point:: 153-154 °C (7 mmHg)
Density: 1.6841 (rough estimate)
refractive index: 1.6120 (estimate)
Flash point:: 153-154°C/7mm
storage temp.: under inert gas (nitrogen or Argon) at 2-8°C
solubility: Dichloromethane, Hot Ethanol
form: Crystalline Powder or Crystals
color: Yellow to light brown
Water Solubility: insoluble
BRN: 742795
InChIKey: LNWXALCHPJANMJ-UHFFFAOYSA-N
CAS DataBase Reference: 3958-57-4(CAS DataBase Reference)
NIST Chemistry Reference: Benzene, 1-(bromomethyl)-3-nitro-(3958-57-4)
EPA Substance Registry System: Benzene, 1-(bromomethyl)-3-nitro- (3958-57-4)

More

Less

Safety

Hazard Codes: C
Risk Statements: 34-36/37
Safety Statements: 26-27-28-36/37/39-45
RIDADR: UN 3261 8/PG 2
WGK Germany: 3
TSCA: Yes
HazardClass: 8
PackingGroup: II
HS Code: 29049090

More

Less

Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Danger

Hazard statements

H314Causes severe skin burns and eye damage

H335May cause respiratory irritation

Precautionary statements

P260Do not breathe dust/fume/gas/mist/vapours/spray.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P330+P331IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

More

Less

N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 222518
Product name: 3-Nitrobenzyl bromide
Purity: 98%
Packaging: 5g
Price: $43.1
Updated: 2025/07/31

TCI Chemical

Product number: N0625
Product name: 3-Nitrobenzyl Bromide
Purity: >98.0%(GC)
Packaging: 10g
Price: $16
Updated: 2025/07/31

TCI Chemical

Product number: N0625
Product name: 3-Nitrobenzyl Bromide
Purity: >98.0%(GC)
Packaging: 25g
Price: $27
Updated: 2025/07/31

Usbiological

Product number: 232095
Product name: 3-Nitrobenzyl bromide 98+%
Packaging: 5g
Price: $156
Updated: 2021/12/16

TRC

Product number: N493635
Product name: 3-Nitrobenzyl Bromide
Packaging: 25g
Price: $710
Updated: 2021/12/16

More

Less

3-Nitrobenzyl bromide Chemical Properties,Usage,Production

Chemical Properties

Pale Yellow Crystalline Solid

Uses

3-Nitrobenzyl bromide was used in the synthesis of 1,4-disubstituted imidazoles.

Synthesis

619-25-0

3958-57-4

General procedure for the synthesis of 3-nitrobenzyl bromide from 3-nitrobenzyl alcohol: Powdered 3-nitrobenzyl alcohol (0.5 mmol) was mixed with halosilanes (0.55 mmol) in a 4 mL screw-capped vial and stirred or heated at room temperature. The reaction mixture was kept at 70-75 °C for 0.5-24 h, during which the reaction progress was monitored by TLC. Upon completion of the reaction, the crude product was cooled to room temperature and the volatile by-product (TMS) was removed by evaporation under reduced pressure (30-35 °C).2O. The residue was confirmed by 1H NMR analysis. If necessary, the pure 3-nitrobenzyl bromide was purified by column chromatography on dry silica to obtain pure 3-nitrobenzyl bromide. Detailed experimental data, including isolated yields, spectral and other characterization data, are given in the Final Product Characterization section of the Supporting Information.

References

[1] Tetrahedron Letters, 2016, vol. 57, # 22, p. 2430 - 2433
[2] Organic Process Research and Development, 2002, vol. 6, # 2, p. 190 - 191
[3] Beilstein Journal of Organic Chemistry, 2014, vol. 10, p. 1397 - 1405
[4] Patent: WO2014/151871, 2014, A2. Location in patent: Page/Page column 59; 60
[5] Journal of the American Chemical Society, 1949, vol. 71, p. 2137,2138,2140

3-Nitrobenzyl bromide Preparation Products And Raw materials

Raw materials

Benzoyl peroxide N-Bromosuccinimide Carbon tetrachloride 3-Nitrotoluene

Preparation Products

3-NITROPHENYLACETIC ACID 3-NITROBENZYLAMINE

More

Less

3-Nitrobenzyl bromide Suppliers

Americas 1 Belgium 1 Canada 1 China 193 Europe 2 Germany 3 India 24 Japan 3 Slovakia 1 South Korea 1 Switzerland 4 Ukraine 1 United Kingdom 15 United States 39 Global 289

HBCChem, Inc.

Tel: +1-510-219-6317
Fax: +1-650-486-1361
Email: sales@hbcchem.com
Country: United States
ProdList: 10648
Advantage: 60

AbaChemScene

Tel: 732-484-9848
Fax: 888-484-5008
Email: sales@chemscene.com
Country: United States
ProdList: 3982
Advantage: 60

Alchem Pharmtech,Inc.

Tel: 8485655694
Email: sales@alchempharmtech.com
Country: United States
ProdList: 63687
Advantage: 58

Aladdin Scientific

Tel
Email: tp@aladdinsci.com
Country: United States
ProdList: 57505
Advantage: 58

Aceschem Inc.

Tel: +1-817863-6948 +1-（817）863-6948
Email: sales@aceschem.com
Country: United States
ProdList: 19632
Advantage: 58

United States Biological

Tel: --
Fax: --
Email: sales@advtechind.com
Country: United States
ProdList: 6075
Advantage: 58

Synthonix Inc

Tel: --
Fax: --
Email: info@synthonix.com
Country: United States
ProdList: 6872
Advantage: 58

BromOrganics Corporation

Tel: --
Fax: --
Email: sales@bromorganics.com
Country: United States
ProdList: 1065
Advantage: 58

OChem Incorporation

Tel: --
Fax: --
Email: sales@ocheminc.com
Country: United States
ProdList: 6501
Advantage: 60

Oakwood Products, Inc.

Tel: --
Fax: --
Email: sales@oakwoodchemical.com
Country: United States
ProdList: 6193
Advantage: 74

Combi-Blocks Inc.

Tel: --
Fax: --
Email: sales@combi-blocks.com
Country: United States
ProdList: 6618
Advantage: 69

Medical Isotopes, Inc

Tel: --
Fax: --
Email: info@medicalisotopes.com
Country: United States
ProdList: 3180
Advantage: 58

SynQuest Laboratories, Inc.

Tel: --
Fax: --
Email: info@synquestlabs.com
Country: United States
ProdList: 6871
Advantage: 62

Riedel-de Haen AG

Tel: --
Fax: --
Country: United States
ProdList: 6773
Advantage: 87

TCI America

Tel: --
Fax: --
Email: sales@tciamerica.com
Country: United States
ProdList: 6909
Advantage: 75

Frontier Scientific, Inc.

Tel: --
Fax: --
Email: sales@frontiersci.com
Country: United States
ProdList: 6222
Advantage: 86

Chemlex Pharmaceuticals LLC

Tel: --
Fax: --
Email: chemlexpharma@yahoo.com
Country: United States
ProdList: 238
Advantage: 0

DeLong Chemicals America

Tel: --
Fax: --
Email: sales@delongchemicals.com
Country: United States
ProdList: 529
Advantage: 50

Ivy Fine Chemicals

Tel: --
Fax: --
Email: sales@ivychem.com
Country: United States
ProdList: 6493
Advantage: 58

3B Scientific Corporation

Tel: --
Fax: --
Email: sales@3bsc.com
Country: United States
ProdList: 6962
Advantage: 56

Waterstone Technology, LLC

Tel: --
Fax: --
Email: sales@waterstonetech.com
Country: United States
ProdList: 6786
Advantage: 30

AlliChem, LLC

Tel: --
Fax: --
Email: sales@allichemllc.com
Country: United States
ProdList: 6516
Advantage: 60

Medical Isotopes

Tel: --
Fax: --
Email: stohler@medicalisotopes.com
Country: United States
ProdList: 6181
Advantage: 68

Beta Pharma, Inc.

Tel: --
Fax: --
Email: sales@betapharma.com
Country: United States
ProdList: 6226
Advantage: 60

Ryan Scientific, Inc.

Tel: --
Fax: --
Email: ryan.reichlyn@ryansci.com
Country: United States
ProdList: 6439
Advantage: 60

Narchem Corporation

Tel: --
Fax: --
Email: sales@narchem.com
Country: United States
ProdList: 2813
Advantage: 60

HONEST JOY HOLDINGS LIMITED

Tel: --
Fax: --
Email: sales@honestjoy.cn
Country: United States
ProdList: 6675
Advantage: 54

2A PharmaChem USA

Tel: --
Fax: --
Email: sales@2apharmachem.com
Country: United States
ProdList: 6137
Advantage: 39

3B Scientific Corporation

Tel: --
Fax: --
Email: sales@3bsc.com
Country: United States
ProdList: 6718
Advantage: 47

AK Scientific, Inc.

Tel: --
Fax: --
Email: sales@aksci.com
Country: United States
ProdList: 6347
Advantage: 65

Leonid Chemicals Private Limited

Tel: --
Fax: --
Email: careers@leonidchemicals.com
Country: United States
ProdList: 1700
Advantage: 43

Sciencelab.com, Inc.

Tel: --
Fax: --
Email: accounting@sciencelab.com
Country: United States
ProdList: 4159
Advantage: 82

Advance Scientific & Chemical

Tel: --
Fax: --
Email: sales@advance-scientific.com
Country: United States
ProdList: 6419
Advantage: 71

BOSCHE SCIENTIFIC, LLC

Tel: --
Fax: --
Email: Sales@BoscheSci.com
Country: United States
ProdList: 6477
Advantage: 55

Alfa Aesar

Tel: --
Fax: --
Email: tech@alfa.com
Country: United States
ProdList: 6814
Advantage: 81

ChemPacific Corporation

Tel: --
Fax: --
Email: sales@chempacific.com
Country: United States
ProdList: 6891
Advantage: 51

Pfaltz & Bauer, Inc.

Tel: --
Fax: --
Email: sales@pfaltzandbauer.com
Country: United States
ProdList: 6828
Advantage: 72

Matrix Scientific

Tel: --
Fax: --
Email: sales@matrixscientific.com
Country: United States
ProdList: 6632
Advantage: 80

Spectrum Chemicals & Laboratory Products

Tel: --
Fax: --
Email: sales@spectrumchemical.com
Country: United States
ProdList: 6699
Advantage: 77

More

Less

View Lastest Price from 3-Nitrobenzyl bromide manufacturers

Henan Aochuang Chemical Co.,Ltd.

Product: 3-Nitrobenzyl bromide 3958-57-4
Price: US $0.00-0.00/KG
Min. Order: 1KG
Purity: 98%
Supply Ability: 1ton
Release date: 2022-09-29

Xi'an Yutbon Pharmaceutical Technology Co., Ltd

Product: 3-Nitrobenzyl bromide 3958-57-4
Price: US $0.00/KG
Min. Order: 1KG
Purity: 98%
Supply Ability: 200kgs
Release date: 2020-09-28

Career Henan Chemical Co

Product: 3-Nitrobenzyl bromide 3958-57-4
Price: US $1.00/KG
Min. Order: 1KG
Purity: ≥98%
Supply Ability: 200kg
Release date: 2019-08-30

3958-57-4, 3-Nitrobenzyl bromideRelated Search:

3-Bromobenzyl alcohol (3-NITROPHENYL)ACETIC ACID METHYL ESTER 3-Bromoanisole 3-Nitroacetophenone 3-Bromobenzyl bromide 3-Nitrobenzaldehyde 1-Bromo-3-iodobenzene 3-Bromobenzonitrile 3-Bromobenzaldehyde 4-Methoxy-2-nitrobenzyl bromide 4,5-DIMETHOXY-2-NITROBENZYL BROMIDE,4,5-Dimethoxy-2-nitrobenzyl bromide 95%,4,5-dimenoxy-2-nitrobenzyl bromide 4-BROMO-2-NITROBENZYL BROMIDE 2-Fluoro-6-nitrobenzyl bromide 98%,2-FLUORO-6-NITROBENZYL BROMIDE 4-NITROBENZYL BROMOACETATE 2-Nitrobenzyl bromide, 98+%,O-NITROBENZYL BROMIDE,2-NITROBENZYL BROMIDE 3-FLUORO-4-NITROBENZYL BROMIDE 4-Nitrobenzyl bromide 3-Nitrotoluene

3-(BroMoMethyl)-1-nitrobenzene

NSC 66499

3-Nitrobenzyl bromid

α-Bromo-3-nitrotoluene

3-Nitrobenzyl bromide,99%

A-BROMO-M-NITROTOLUENE

ALPHA-BROMO-3-NITROTOLUENE

ALPHA-BROMO-M-NITROTOLUENE

3-NITROBENZYL BROMIDE

M-NITROBENZYL BROMIDE

1-(bromomethyl)-3-nitro-benzen

1-(Bromomethyl)-3-nitrobenzene

m-(Bromomethyl)nitrobenzene

m-Nitro-alpha-bromotoluene

Toluene, alpha-bromo-m-nitro-

a-Bromo-3-nitrotoluene

3-Nitrobenzyl bromide, 98+%

à-bromo-3-nitrotoluene

α-bromo-m-nitrotoluene

3-(Bromomethyl)nitrobenzene

m-Nitro-a-bromotoluene

3-Nitro-1-(bromomethyl)benzene

3-NitrobenzylBromide&gt

3-Nitrobenzyl bromide, 98%, for synthesis

Benzene, 1-(bromomethyl)-3-nitro-

Rizatriptan Impurity 14

3-Nitrobromobenzyl

Rizatriptan EP Impurity4

3958-57-4

Organic Building Blocks

Nitrogen Compounds

Nitro Compounds

Building Blocks

Aromatics Compounds

Aromatics

Halides

Aromatic Halides (substituted)