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platyphylline

Product Name
platyphylline
CAS No.
480-78-4
Chemical Name
platyphylline
Synonyms
Platifillin;Platiphyllin;Platiphillin;Platyphyllin;platyphylline;Einecs 207-558-6;66641-38-1 (Hydrochloride);PLATYPHYLLINI HYDROTARTRAS;12-Hydroxy-1,2-dihydrosenecionan-11,16-dione;(1R)-1,2-Dihydro-12-hydroxysenecionan-11,16-dione
CBNumber
CB3914285
Molecular Formula
C18H27NO5
Formula Weight
337.41
MOL File
480-78-4.mol
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platyphylline Property

Melting point:
129°
alpha 
D20 -56.4° (c = 0.7 in chloroform)
Boiling point:
539.6±50.0 °C(Predicted)
Density 
1.22±0.1 g/cm3(Predicted)
pka
12.83±0.40(Predicted)
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Safety

RIDADR 
1544
HazardClass 
6.1(b)
PackingGroup 
III
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Hazard and Precautionary Statements (GHS)

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N-Bromosuccinimide Price

Matrix Scientific
Product number
059765
Product name
12-Hydroxy-1,2-dihydrosenecionan-11,16-dione
Packaging
500mg
Price
$199
Updated
2021/12/16
American Custom Chemicals Corporation
Product number
API0016155
Product name
PLATYPHYLLINE
Purity
95.00%
Packaging
1G
Price
$232.05
Updated
2021/12/16
Matrix Scientific
Product number
059765
Product name
12-Hydroxy-1,2-dihydrosenecionan-11,16-dione
Packaging
1g
Price
$306
Updated
2021/12/16
Matrix Scientific
Product number
059765
Product name
12-Hydroxy-1,2-dihydrosenecionan-11,16-dione
Packaging
5g
Price
$1071
Updated
2021/12/16
Arctom
Product number
CFN00403
Product name
Platyphylline
Purity
≥98%
Packaging
5mg
Price
$468
Updated
2021/12/16
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platyphylline Chemical Properties,Usage,Production

Description

A hepatotoxic alkaloid, the base has been isolated from Senecio adnatus D.C., S. hygrophilus Dyer & Sm. and S. piatyphyllus D.C. The alkaloid is only sparingly soluble in petroleum ether or hot H20, more so in Me2CO, EtOH, C6H6 or Et20 and readily soluble in CHCI3. It is laevorotatory with [α]D - 45.09° (CHCI3). The perchlorate occurs as colourless prisms from H20, m.p. 222-3°C (dec.); the picrolonate, dark yellow needles, m.p. 205-6°C (dec.); aurichloride, m.p. 200-loC (dec.) and the methiodide, m.p. 216-7°C; [α]D - 31.27° (EtOH). The alkaloid contains one hydroxyl group but no methoxyl or methylimino groups. On hydrolysis it furnishes platynecine, CSH1S0 2N, m.p. 148°C; [α]D - 56.8° (CHCI3) and platynecic acid, ClOH140 4 , m.p. l54-5°C which is identical with senecic acid lactone.

Uses

12-Hydroxy-1,2-dihydrosenecionan-11,16-dione is a pyrrolizidine alkaloid which can be found in various Senecio species. It can be useful in the generation and characterization of monoclonal antibodies against the pyrrolizidine alkaloid retrorsine .

Definition

ChEBI: Platyphylline is a macrolide.

References

Orekhov, Tiedebel., Ber., 68,653 (1935)
Orekhov, Konovalova, Tiedebel., ibid, 68, 1886 (1935)
Orekhov, Tiedebel., J. Gen. Chern. USSR, 8,273 (1938)
de Waal., Onderstepoort J., 15,251 (1940)
Koekemoer, Warren., J. Chern. Soc., 63 (1955)

platyphylline Preparation Products And Raw materials

Raw materials

Preparation Products

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platyphylline Suppliers

CHEMSWORTH
Tel
--
Fax
--
Email
info@chemsworth.com
Country
India
ProdList
6700
Advantage
30

480-78-4, platyphyllineRelated Search:


  • platyphylline
  • (1R)-1,2-Dihydro-12-hydroxysenecionan-11,16-dione
  • [1R,(-)]-1,2-Dihydro-12-hydroxysenecionan-11,16-dione
  • Platifillin
  • (1-alpha)-1,2-Dihydro-12-hydroxysenecionan-11,16-dione
  • 66641-38-1 (Hydrochloride)
  • Einecs 207-558-6
  • Platiphillin
  • Platiphyllin
  • Senecionan-11,16-dione, 1,2-dihydro-12-hydroxy-, (1-alpha)-
  • 12-Hydroxy-1,2-dihydrosenecionan-11,16-dione
  • Platyphyllin
  • [1,6]Dioxacyclododecino[2,3,4-gh]pyrrolizine-2,7-dione, 3-ethylidenedodecahydro-6-hydroxy-5,6-dimethyl-, (3Z,5R,6R,9aS,14aR,14bR)-
  • PLATYPHYLLINI HYDROTARTRAS
  • 480-78-4