Chloro[(tri-tert-butylphosphine)-2-(2-aMinobiphenyl)]palladiuM(II)

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Chloro[(tri-tert-butylphosphine)-2-(2-aMinobiphenyl)]palladiuM(II)

Physical Form Reaction

Product Name: Chloro[(tri-tert-butylphosphine)-2-(2-aMinobiphenyl)]palladiuM(II)
CAS No.: 1375325-71-5
Chemical Name: Chloro[(tri-tert-butylphosphine)-2-(2-aMinobiphenyl)]palladiuM(II)
Synonyms: P(tBu)3 Pd G2;tBu3PPdG2 catalyst;P(t-Bu)3 Palladacycle Gen.2;Chloro[(tri-t-butylphosphine)-2-(2-aminobiphenyl)]palladium(II);Chloro(tri-t-butylphosphine)(2'-amino-1,1'-biphenyl-2-yl)pal...;Chloro(tri-tert-butylphosphine)(2'-aminobiphenylyl)palladium(II);Chloro[(tri-tert-butylphosphine)-2-(2-aMinobiphenyl)]palladiuM(II);Chloro[(tri-tert-butylphosphine)(2-aminobiphenyl-2-yl)palladium(II);Chloro[(tri-tert-butylphosphine)-2-(2-aminobiphenyl)]palladium(II)>Chloro(tri-t-butylphosphine)(2'-amino-1,1'-biphenyl-2-yl)palladium(II)
CBNumber: CB42673226
Molecular Formula: C24H37ClNPPd
Formula Weight: 512.41
MOL File: 1375325-71-5.mol

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Chloro[(tri-tert-butylphosphine)-2-(2-aMinobiphenyl)]palladiuM(II) Property

Melting point:: 158-160°C
form: Powder
color: yellow
InChI: InChI=1S/C12H9N.C12H27P.ClH.Pd/c13-12-9-5-4-8-11(12)10-6-2-1-3-7-10;1-10(2,3)13(11(4,5)6)12(7,8)9;;/h1-6,8-9,13H;1-9H3;1H;/q-2;;;+2
InChIKey: CCFGXRYKSYUWKT-UHFFFAOYSA-N
SMILES: P([Pd+2]1(NC2=CC=CC=C2C2=CC=CC=[C-]12)[Cl-])(C(C)(C)C)(C(C)(C)C)C(C)(C)C

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Safety

WGK Germany: 3
HS Code: 2931.90.6000

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

Precautionary statements

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P280Wear protective gloves/protective clothing/eye protection/face protection.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 756482
Product name: P(tBu)3 Pd G2
Packaging: 2g
Price: $471
Updated: 2024/03/01

Sigma-Aldrich

Product number: 756482
Product name: P(tBu)3 Pd G2
Packaging: 5g
Price: $792
Updated: 2024/03/01

TCI Chemical

Product number: C2734
Product name: Chloro[(tri-tert-butylphosphine)-2-(2-aminobiphenyl)]palladium(II)
Purity: >98.0%(T)
Packaging: 1g
Price: $288
Updated: 2024/03/01

Strem Chemicals

Product number: 46-0028
Product name: Chloro(tri-t-butylphosphine)(2'-amino-1,1'-biphenyl-2-yl)palladium(II), min. 98%
Packaging: 250mg
Price: $60
Updated: 2024/03/01

Strem Chemicals

Product number: 46-0028
Product name: Chloro(tri-t-butylphosphine)(2'-amino-1,1'-biphenyl-2-yl)palladium(II), min. 98%
Packaging: 1g
Price: $177
Updated: 2024/03/01

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Chloro[(tri-tert-butylphosphine)-2-(2-aMinobiphenyl)]palladiuM(II) Chemical Properties,Usage,Production

Physical Form

Light yellow to Amber to Dark green powder to crystal.

Reaction

Catalyst for the Suzuki Coupling of brominated 2,1-borazaronaphthalenes and potassium organotrifluoroborates.

Uses

P(t-Bu)₃ Pd G2 (Chloro[(tri-tert-butylphosphine)-2-(2-aminobiphenyl)] palladium(II), Pd/P(t-Bu)₃) may be used as catalyst in the following studies:

Synthesis of sterically hindered biaryls (tetra-ortho-substituted), via cross-coupling reactions of aryl chlorides.
Stille cross-couplings reactions of aryl chloride.
Synthesis of chloropeptin I, via Stille cross-coupling reaction.
Heck reaction.
Negishi cross-coupling reactions.

Application

Catalyst for the Suzuki Coupling of brominated 2,1-borazaronaphthalenes and potassium organotrifluoroborates.

General Description

P(t-Bu)₃ Pd G2 (Chloro[(tri-tert-butylphosphine)-2-(2-aminobiphenyl)] palladium(II)) is a second generation (G2) precatalyst containing a biphenyl-based ligand. Product participates in various palladium catalyzed cross-coupling reactions, C-C, C-N and C-O bond formation reactions, and Suzuki-Miyaura coupling reactions. It generates active Pd catalyst at room temperature in the presence of weak phosphate or carbonate bases. It has been proposed as an active catalyst for use in Stille reactions of aryl halides (bromides and chlorides).

Chloro[(tri-tert-butylphosphine)-2-(2-aMinobiphenyl)]palladiuM(II) Preparation Products And Raw materials

Raw materials

Preparation Products

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View Lastest Price from Chloro[(tri-tert-butylphosphine)-2-(2-aMinobiphenyl)]palladiuM(II) manufacturers

Henan Fengda Chemical Co., Ltd

Product: Chloro[(tri-tert-butylphosphine)-2-(2-aMinobiphenyl)]palladiuM(II) 1375325-71-5
Price: US $10.00-2.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: g-kg-tons, free sample is available
Release date: 2024-04-28

Wuhan LPBchem Technology Co.,Ltd

Product: Chloro[(tri-tert-butylphosphine)(2-aminobiphenyl-2-yl)palladium(II) / P(tBu)3 Pd G2 1375325-71-5
Price: US $10.00-10.00/g
Min. Order: 1g
Purity: 0.98
Supply Ability: 50KG
Release date: 2020-11-26

Chemwill Asia Co.,Ltd.

Product: Chloro[(tri-tert-butylphosphine)-2-(2-aMinobiphenyl)]palladiuM(II) in stock Factory 1375325-71-5
Price: US $1.00/kg
Min. Order: 1kg
Purity: High quality purified manufacturer
Supply Ability: Top 3 production capacity Factory
Release date: 2019-04-04

1375325-71-5, Chloro[(tri-tert-butylphosphine)-2-(2-aMinobiphenyl)]palladiuM(II)Related Search:

CHLORO[1,3-BIS(2,6-DI-I-PROPYLPHENYL)IMIDAZOL-2-YLIDENE]COPPER(I) CHLORO(1,5-CYCLOOCTADIENE)(PENTAMETHYLCYCLOPENTADIENYL)RUTHENIUM (II) tBuXPhos-Pd-G3 cataCXium A-Pd-G2 Methanesulfonato(tricyclohexylphosphine)(2'-aMino-1,1'-biphenyl-2-yl)palladiuM(II) dichloroMethane adduct P(t-Bu)3 Pd G4 Chloro[(tricyclohexylphosphine)-2-(2'-aminobiphenyl)]palladium(II) XPhos Pd G2 SPhos Pd G2 RuPhos Pd G2 Chloro[tri(p-tolyl)phosphine]gold(I),97% XantPhos-Pd-G2 Chloro[(S)-(-)-2,2'-bis(di-p-tolylphosphino)-1,1'-binaphthyl](p-cymene)ruthenium(II)chloride (2-BIPHENYL)DI-TERT-BUTYLPHOSPHINE GOLD& Chloro[(R)-(+)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole](p-cymene)ruthenium(II) chloride [RuCl(p-cymene)((R)-segphos)]Cl BrettPhosPalladacycle Chloro[tri(o-tolyl)phosphine]gold(I) Chloro{[(1R,2R)-(-)-2-amino-1,2-diphenylethyl](4-toluenesulfonyl)amido}(mesitylene)ruthenium(II), min. 90% RuCl[(R,R)-Tsdpen(mesitylene)

Chloro[(tri-tert-butylphosphine)-2-(2-aMinobiphenyl)]palladiuM(II)

P(tBu)3 Pd G2

Chloro(tri-t-butylphosphine)(2'-amino-1,1'-biphenyl-2-yl)palladium(II)

Chloro[(tri-tert-butylphosphine)-2'-amino[1,1'-biphenyl]-2-yl]palladium(II)

Chloro[(tri-t-butylphosphine)-2-(2-aminobiphenyl)]palladium(II)

Chloro[(tri-<i>tert</i>-butylphosphine)-2-(2-aminobiphenyl)]palladium(II)

tBu3PPdG2 catalyst

Chloro(tri-t-butylphosphine)(2'-amino-1,1'-biphenyl-2-yl)palladium(II), min. 98%

P(t-Bu)3 Palladacycle Gen.2

[2'-(Amino-κN)[1,1'-biphenyl]-2-yl-κC]chloro[tris(1,1-dimethylethyl)phosphine]palladium

Chloro(tri-tert-butylphosphine)(2'-aminobiphenylyl)palladium(II)

Chloro[(tri-tert-butylphosphine)-2-(2-aMinobiphenyl)]palladiuM(II) in stock Factory

Chloro[(tri-tert-butylphosphine)(2-aminobiphenyl-2-yl)palladium(II)

Chloro[(tri-tert-butylphosphine)-2-(2-aminobiphenyl)]palladium(II)&gt

Chloro[(tri-tert-butylphosphine)(2-aminobiphenyl-2-yl)palladium(II) / P(tBu)3 Pd G2

Palladium, [2'-(amino-κN)[1,1'-biphenyl]-2-yl-κC]chloro[tris(1,1-dimethylethyl)phosphine]-

Chloro[(tri-tert-butylphosphine)-2-(2-aMinobiphenyl)]palladiuM(II) ISO 9001：2015 REACH

Palladium, [2'-(amino-kN)[1,1'-biphenyl]-2-yl-kC]chloro[tris(1,1-dimethylethyl)phosphine)-

Chloro(tri-t-butylphosphine)(2'-amino-1,1'-biphenyl-2-yl)pal...

(2'-Amino-2-biphenylyl)(chloro)palladium - tris(2-methyl-2-propanyl)phosphine (1:1)

P(tBu)3 Pd G2 / Chloro[(tri-tert-butylphosphine)(2-aminobiphenyl-2-yl)palladium(II)

Chloro[(tri-tert-butylphosphine)-2-(2-aminobiphenyl)]palladium(II) [P(tbu)3 PD g2]

1375325-71-5

C24H37ClNPPd