Chloro[(tri-tert-butylphosphine)-2-(2-aMinobiphenyl)]palladiuM(II)
Physical Form Reaction- Product Name
- Chloro[(tri-tert-butylphosphine)-2-(2-aMinobiphenyl)]palladiuM(II)
- CAS No.
- 1375325-71-5
- Chemical Name
- Chloro[(tri-tert-butylphosphine)-2-(2-aMinobiphenyl)]palladiuM(II)
- Synonyms
- P(tBu)3 Pd G2;tBu3PPdG2 catalyst;P(t-Bu)3 Palladacycle Gen.2;P(t-Bu)3 Pd G2;Chloro[(tri-tert-butylphosphine)-2-(2-aMinobiphenyl)]palladiuM;Chloro[(tri-t-butylphosphine)-2-(2-aminobiphenyl)]palladium(II);Chloro(tri-t-butylphosphine)(2'-amino-1,1'-biphenyl-2-yl)pal...;Chloro(tri-tert-butylphosphine)(2'-aminobiphenylyl)palladium(II);Chloro(tri-tert-butylphosphine)(2’-aminobiphenylyl)palladium(II);Chloro[(tri-tert-butylphosphine)-2-(2-aMinobiphenyl)]palladiuM(II)
- CBNumber
- CB42673226
- Molecular Formula
- C24H37ClNPPd
- Formula Weight
- 512.41
- MOL File
- 1375325-71-5.mol
Chloro[(tri-tert-butylphosphine)-2-(2-aMinobiphenyl)]palladiuM(II) Property
- Melting point:
- 158-160°C
- storage temp.
- 2-8°C, protect from light, stored under nitrogen
- form
- Powder
- color
- yellow
- InChI
- InChI=1S/C12H9N.C12H27P.ClH.Pd/c13-12-9-5-4-8-11(12)10-6-2-1-3-7-10;1-10(2,3)13(11(4,5)6)12(7,8)9;;/h1-6,8-9,13H;1-9H3;1H;/q-2;;;+2
- InChIKey
- CCFGXRYKSYUWKT-UHFFFAOYSA-N
- SMILES
- P([Pd+2]1(NC2=CC=CC=C2C2=CC=CC=[C-]12)[Cl-])(C(C)(C)C)(C(C)(C)C)C(C)(C)C
Safety
- WGK Germany
- 3
- HS Code
- 2931.90.6000
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H315Causes skin irritation
H319Causes serious eye irritation
- Precautionary statements
-
P264Wash hands thoroughly after handling.
P264Wash skin thouroughly after handling.
P280Wear protective gloves/protective clothing/eye protection/face protection.
N-Bromosuccinimide Price
- Product number
- 756482
- Product name
- P(tBu)3 Pd G2
- Packaging
- 2g
- Price
- $450.04
- Updated
- 2025/07/31
- Product number
- 756482
- Product name
- P(tBu)3 Pd G2
- Packaging
- 5g
- Price
- $755.62
- Updated
- 2025/07/31
- Product number
- C2734
- Product name
- Chloro[(tri-tert-butylphosphine)-2-(2-aminobiphenyl)]palladium(II)
- Purity
- >98.0%(T)
- Packaging
- 1g
- Price
- $288
- Updated
- 2025/07/31
- Product number
- 46-0028
- Product name
- Chloro(tri-t-butylphosphine)(2'-amino-1,1'-biphenyl-2-yl)palladium(II), min. 98%
- Packaging
- 250mg
- Price
- $60
- Updated
- 2024/03/01
- Product number
- 46-0028
- Product name
- Chloro(tri-t-butylphosphine)(2'-amino-1,1'-biphenyl-2-yl)palladium(II), min. 98%
- Packaging
- 1g
- Price
- $177
- Updated
- 2024/03/01
Chloro[(tri-tert-butylphosphine)-2-(2-aMinobiphenyl)]palladiuM(II) Chemical Properties,Usage,Production
Physical Form
Light yellow to Amber to Dark green powder to crystal.
Reaction
Catalyst for the Suzuki Coupling of brominated 2,1-borazaronaphthalenes and potassium organotrifluoroborates.
Uses
P(t-Bu)3 Pd G2 (Chloro[(tri-tert-butylphosphine)-2-(2-aminobiphenyl)] palladium(II), Pd/P(t-Bu)3) may be used as catalyst in the following studies:
- Synthesis of sterically hindered biaryls (tetra-ortho-substituted), via cross-coupling reactions of aryl chlorides.
- Stille cross-couplings reactions of aryl chloride.
- Synthesis of chloropeptin I, via Stille cross-coupling reaction.
- Heck reaction.
- Negishi cross-coupling reactions.
Application
Catalyst for the Suzuki Coupling of brominated 2,1-borazaronaphthalenes and potassium organotrifluoroborates.
General Description
P(t-Bu)3 Pd G2 (Chloro[(tri-tert-butylphosphine)-2-(2-aminobiphenyl)] palladium(II)) is a second generation (G2) precatalyst containing a biphenyl-based ligand. Product participates in various palladium catalyzed cross-coupling reactions, C-C, C-N and C-O bond formation reactions, and Suzuki-Miyaura coupling reactions. It generates active Pd catalyst at room temperature in the presence of weak phosphate or carbonate bases. It has been proposed as an active catalyst for use in Stille reactions of aryl halides (bromides and chlorides).
reaction suitability
core: palladium
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: catalyst
reaction type: Cross Couplings
Chloro[(tri-tert-butylphosphine)-2-(2-aMinobiphenyl)]palladiuM(II) Preparation Products And Raw materials
Raw materials
Preparation Products
Chloro[(tri-tert-butylphosphine)-2-(2-aMinobiphenyl)]palladiuM(II) Suppliers
- Tel
- 166-166-37336996 15690792173
- Fax
- 0373-7759608
- chenxi.song@runvmat.com
- Country
- China
- ProdList
- 285
- Advantage
- 55
- Tel
- 18610472091
- Fax
- 010-59092859
- gfdskj@163.com
- Country
- China
- ProdList
- 494
- Advantage
- 58
- Tel
- 02763499399 13797220777
- lpbchem@163.com
- Country
- China
- ProdList
- 99
- Advantage
- 58
- Tel
- 025-58851090 15955137747
- Fax
- (6)02557626880
- sales01@aikonchem.com
- Country
- China
- ProdList
- 15949
- Advantage
- 58
- Tel
- 0371-65511006 18625597674
- sales@kingorgchem.com
- Country
- China
- ProdList
- 976
- Advantage
- 55
- Tel
- 131-21959385 18804271668
- Fax
- 010-62925455
- chemrocking@bjgreenchem.com
- Country
- China
- ProdList
- 273
- Advantage
- 58
- Tel
- 0512-67216630 67216634
- Fax
- 0512-56316689
- sales@sinocompound.com
- Country
- China
- ProdList
- 271
- Advantage
- 64
- Tel
- 13080686708; 13080686708
- houshuangchem@163.com
- Country
- China
- ProdList
- 78
- Advantage
- 58
- Tel
- 18210857532; 18210857532
- Fax
- 86-10-82849933
- jkinfo@jkchemical.com
- Country
- China
- ProdList
- 96815
- Advantage
- 76
- Tel
- 021-67121386
- Fax
- 021-67121385
- Sales-CN@TCIchemicals.com
- Country
- China
- ProdList
- 24529
- Advantage
- 81
- Tel
- 400-021-7337 2355568890
- Fax
- 0086-21-50182339
- sales@demochem.com
- Country
- China
- ProdList
- 2572
- Advantage
- 57
- Tel
- 18515581800 18501085097
- Fax
- 010-89508210
- sales.bj@hwrkchemical.com
- Country
- China
- ProdList
- 9400
- Advantage
- 55
- Tel
- 021-021-58432009 400-005-6266
- Fax
- 021-58436166
- sales8178@energy-chemical.com
- Country
- China
- ProdList
- 44801
- Advantage
- 61
- Tel
- 021-50795510 4000665055
- Fax
- 021-50795055
- sales@accelachem.com
- Country
- China
- ProdList
- 11035
- Advantage
- 64
- Tel
- 0550-5618439 15951861180
- Fax
- 0550-5610690
- cynthiachem@163.com
- Country
- China
- ProdList
- 291
- Advantage
- 62
- Tel
- 027-027-87680032 18963957250
- taiyuchem@163.com
- Country
- China
- ProdList
- 180
- Advantage
- 55
- Tel
- 021-61551611 13296011611
- Fax
- +86 21-50676805
- contact@trustwe.com
- Country
- China
- ProdList
- 9895
- Advantage
- 58
- Tel
- 150-2103-5486 18017383231
- Fax
- qq:2817624287
- 983544897@qq.com
- Country
- China
- ProdList
- 9342
- Advantage
- 55
- Tel
- 4009209199
- Fax
- 86-021-52271987
- sales@9dingchem.com
- Country
- China
- ProdList
- 22514
- Advantage
- 55
- Tel
- 400-164-7117 13681763483
- Fax
- +86-21-61629029
- product02@bidepharm.com
- Country
- China
- ProdList
- 39966
- Advantage
- 60
- Tel
- 400-6087598 15021221957
- Fax
- 4006087598-8012
- order@canspecsci.com
- Country
- China
- ProdList
- 2001
- Advantage
- 56
- Tel
- 0917-8888777, 3380777,18691786767; 15619786767
- xuya@bjrock.com
- Country
- China
- ProdList
- 310
- Advantage
- 62
- Tel
- 021-60455363 18019463053
- Fax
- 50966098
- sales@coolpharm.com
- Country
- China
- ProdList
- 12346
- Advantage
- 58
- Tel
- 0571-82896630 18969958410
- sales_hz@milestonepharmtech.com
- Country
- China
- ProdList
- 4894
- Advantage
- 55
- Tel
- 021-61415566 800-8193336
- orderCN@merckgroup.com
- Country
- China
- ProdList
- 51395
- Advantage
- 80
- Tel
- 021-58088081 Q2635253576
- Fax
- QQ3382968513
- hailey@shsendpharm.com
- Country
- China
- ProdList
- 2081
- Advantage
- 55
- Tel
- 526763801 13301653310
- Fax
- +86-21-51619052
- 526763801@qq.com
- Country
- China
- ProdList
- 9279
- Advantage
- 55
- Tel
- 021-61312847; 18021002903
- Fax
- QQ:3008007432
- 3008007409@qq.com
- Country
- China
- ProdList
- 71826
- Advantage
- 60
- Tel
- 02781293128
- orders@biochemsafebuy.com
- Country
- China
- ProdList
- 9923
- Advantage
- 55
- Tel
- 15076683720
- Fax
- 022-23754520
- klq@cw-bio.com
- Country
- China
- ProdList
- 8011
- Advantage
- 55
- Tel
- 0371-0371-55629727 13323845623
- Fax
- 037155629727
- 2885676761@qq.com
- Country
- China
- ProdList
- 10110
- Advantage
- 58
- Tel
- 010-60605840 18892239720
- Fax
- 010-60605840
- psaitong@jm-bio.com
- Country
- China
- ProdList
- 12306
- Advantage
- 58
- Tel
- 021-60702684 18516024827
- huang.jiayi@sinocompound.com
- Country
- China
- ProdList
- 2280
- Advantage
- 58
- Tel
- 13127280945
- 285424065@qq.com
- Country
- China
- ProdList
- 9976
- Advantage
- 55
- Tel
- 0539-6362799 20)
- Fax
- 0539-6362799(To 20)
- Country
- China
- ProdList
- 9998
- Advantage
- 58
- Tel
- 021-58950110 13124863828
- Fax
- 021-20922272
- sales@linkchem.cn
- Country
- China
- ProdList
- 2998
- Advantage
- 58
- Tel
- 86-0573-85866609 13325730825
- Fax
- 0573-85866609
- 945717149@qq.com
- Country
- China
- ProdList
- 8595
- Advantage
- 58
- Tel
- 0755-89880280
- Fax
- 0755-89880280
- 3004662104@qq.com
- Country
- China
- ProdList
- 1829
- Advantage
- 58
- Tel
- 400-8210725 400821072
- Fax
- 021-58955996
- malulu@leyan.com
- Country
- China
- ProdList
- 25000
- Advantage
- 58
- Tel
- 0371-55051623 18137891487
- Fax
- QQ:2853979817
- 2853979817@qq.com
- Country
- China
- ProdList
- 9988
- Advantage
- 58
- Tel
- 400-668-9898
- Fax
- 010-51582189
- service@3achem.com
- Country
- China
- ProdList
- 20557
- Advantage
- 58
- Tel
- 021-54252912-8903
- leona.xin@forneeds.cn
- Country
- China
- ProdList
- 4759
- Advantage
- 58
- Tel
- 4009004166/18616739031 18616739031
- 3007523370@qq.com
- Country
- China
- ProdList
- 52687
- Advantage
- 58
- Tel
- +86-400-002-6226 +86-13028896684;
- sales@rrkchem.com
- Country
- China
- ProdList
- 57422
- Advantage
- 58
- Tel
- +862156762820 +86-13564624040
- sales@myuchem.com
- Country
- China
- ProdList
- 8460
- Advantage
- 58
- Tel
- +86-29-89586680 +86-15129568250
- 1026@dideu.com
- Country
- China
- ProdList
- 20284
- Advantage
- 58
- Tel
- 021-64478606 +8615900664856
- daeyeon001@vip.163.com
- Country
- China
- ProdList
- 2062
- Advantage
- 58
- Tel
- +86-0551-65418684 +8618949823763
- Fax
- 0086-551-65418684
- sales@tnjchem.com
- Country
- China
- ProdList
- 25356
- Advantage
- 58
- Tel
- +8615986615575
- Fax
- 0086-13651442114
- info@codchem.com
- Country
- China
- ProdList
- 20342
- Advantage
- 58
- Tel
- 02120970332; +8613524231522
- Fax
- +86-21-58816016
- sales@zhuoerchem.com
- Country
- China
- ProdList
- 2904
- Advantage
- 58
View Lastest Price from Chloro[(tri-tert-butylphosphine)-2-(2-aMinobiphenyl)]palladiuM(II) manufacturers
- Product
- Chloro[(tri-tert-butylphosphine)-2-(2-aMinobiphenyl)]palladiuM(II) 1375325-71-5
- Price
- US $10.00-2.00/KG
- Min. Order
- 1KG
- Purity
- 99%
- Supply Ability
- g-kg-tons, free sample is available
- Release date
- 2024-04-28
- Product
- Chloro[(tri-tert-butylphosphine)(2-aminobiphenyl-2-yl)palladium(II) / P(tBu)3 Pd G2 1375325-71-5
- Price
- US $10.00-10.00/g
- Min. Order
- 1g
- Purity
- 0.98
- Supply Ability
- 50KG
- Release date
- 2020-11-26
- Product
- Chloro[(tri-tert-butylphosphine)-2-(2-aMinobiphenyl)]palladiuM(II) in stock Factory 1375325-71-5
- Price
- US $1.00/kg
- Min. Order
- 1kg
- Purity
- High quality purified manufacturer
- Supply Ability
- Top 3 production capacity Factory
- Release date
- 2019-04-04