Physical Form Reaction
ChemicalBook > CAS DataBase List > Chloro[(tri-tert-butylphosphine)-2-(2-aMinobiphenyl)]palladiuM(II)

Chloro[(tri-tert-butylphosphine)-2-(2-aMinobiphenyl)]palladiuM(II)

Physical Form Reaction
Product Name
Chloro[(tri-tert-butylphosphine)-2-(2-aMinobiphenyl)]palladiuM(II)
CAS No.
1375325-71-5
Chemical Name
Chloro[(tri-tert-butylphosphine)-2-(2-aMinobiphenyl)]palladiuM(II)
Synonyms
P(tBu)3 Pd G2;tBu3PPdG2 catalyst;P(t-Bu)3 Palladacycle Gen.2;Chloro[(tri-t-butylphosphine)-2-(2-aminobiphenyl)]palladium(II);Chloro(tri-t-butylphosphine)(2'-amino-1,1'-biphenyl-2-yl)pal...;Chloro(tri-tert-butylphosphine)(2'-aminobiphenylyl)palladium(II);Chloro[(tri-tert-butylphosphine)-2-(2-aMinobiphenyl)]palladiuM(II);Chloro[(tri-tert-butylphosphine)(2-aminobiphenyl-2-yl)palladium(II);Chloro[(tri-tert-butylphosphine)-2-(2-aminobiphenyl)]palladium(II)>Chloro(tri-t-butylphosphine)(2'-amino-1,1'-biphenyl-2-yl)palladium(II)
CBNumber
CB42673226
Molecular Formula
C24H37ClNPPd
Formula Weight
512.41
MOL File
1375325-71-5.mol
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Chloro[(tri-tert-butylphosphine)-2-(2-aMinobiphenyl)]palladiuM(II) Property

Melting point:
158-160°C
form 
Powder
color 
yellow
InChI
InChI=1S/C12H9N.C12H27P.ClH.Pd/c13-12-9-5-4-8-11(12)10-6-2-1-3-7-10;1-10(2,3)13(11(4,5)6)12(7,8)9;;/h1-6,8-9,13H;1-9H3;1H;/q-2;;;+2
InChIKey
CCFGXRYKSYUWKT-UHFFFAOYSA-N
SMILES
P([Pd+2]1(NC2=CC=CC=C2C2=CC=CC=[C-]12)[Cl-])(C(C)(C)C)(C(C)(C)C)C(C)(C)C
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Safety

WGK Germany 
3
HS Code 
2931.90.6000
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

Precautionary statements

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P280Wear protective gloves/protective clothing/eye protection/face protection.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
756482
Product name
P(tBu)3 Pd G2
Packaging
2g
Price
$471
Updated
2024/03/01
Sigma-Aldrich
Product number
756482
Product name
P(tBu)3 Pd G2
Packaging
5g
Price
$792
Updated
2024/03/01
TCI Chemical
Product number
C2734
Product name
Chloro[(tri-tert-butylphosphine)-2-(2-aminobiphenyl)]palladium(II)
Purity
>98.0%(T)
Packaging
1g
Price
$288
Updated
2024/03/01
Strem Chemicals
Product number
46-0028
Product name
Chloro(tri-t-butylphosphine)(2'-amino-1,1'-biphenyl-2-yl)palladium(II), min. 98%
Packaging
250mg
Price
$60
Updated
2024/03/01
Strem Chemicals
Product number
46-0028
Product name
Chloro(tri-t-butylphosphine)(2'-amino-1,1'-biphenyl-2-yl)palladium(II), min. 98%
Packaging
1g
Price
$177
Updated
2024/03/01
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Chloro[(tri-tert-butylphosphine)-2-(2-aMinobiphenyl)]palladiuM(II) Chemical Properties,Usage,Production

Physical Form

Light yellow to Amber to Dark green powder to crystal.

Reaction

Catalyst for the Suzuki Coupling of brominated 2,1-borazaronaphthalenes and potassium organotrifluoroborates.

Uses

P(t-Bu)3 Pd G2 (Chloro[(tri-tert-butylphosphine)-2-(2-aminobiphenyl)] palladium(II), Pd/P(t-Bu)3) may be used as catalyst in the following studies:

  • Synthesis of sterically hindered biaryls (tetra-ortho-substituted), via cross-coupling reactions of aryl chlorides.
  • Stille cross-couplings reactions of aryl chloride.
  • Synthesis of chloropeptin I, via Stille cross-coupling reaction.
  • Heck reaction.
  • Negishi cross-coupling reactions.

Application

Catalyst for the Suzuki Coupling of brominated 2,1-borazaronaphthalenes and potassium organotrifluoroborates.

General Description

P(t-Bu)3 Pd G2 (Chloro[(tri-tert-butylphosphine)-2-(2-aminobiphenyl)] palladium(II)) is a second generation (G2) precatalyst containing a biphenyl-based ligand. Product participates in various palladium catalyzed cross-coupling reactions, C-C, C-N and C-O bond formation reactions, and Suzuki-Miyaura coupling reactions. It generates active Pd catalyst at room temperature in the presence of weak phosphate or carbonate bases. It has been proposed as an active catalyst for use in Stille reactions of aryl halides (bromides and chlorides).

Chloro[(tri-tert-butylphosphine)-2-(2-aMinobiphenyl)]palladiuM(II) Preparation Products And Raw materials

Raw materials

Preparation Products

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Chloro[(tri-tert-butylphosphine)-2-(2-aMinobiphenyl)]palladiuM(II) Suppliers

Americas 1 China 105 Europe 1 India 3 Japan 1 Switzerland 1 United States 7 Global 119
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View Lastest Price from Chloro[(tri-tert-butylphosphine)-2-(2-aMinobiphenyl)]palladiuM(II) manufacturers

Henan Fengda Chemical Co., Ltd
Product
Chloro[(tri-tert-butylphosphine)-2-(2-aMinobiphenyl)]palladiuM(II) 1375325-71-5
Price
US $10.00-2.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
g-kg-tons, free sample is available
Release date
2024-04-28
Wuhan LPBchem Technology Co.,Ltd
Product
Chloro[(tri-tert-butylphosphine)(2-aminobiphenyl-2-yl)palladium(II) / P(tBu)3 Pd G2 1375325-71-5
Price
US $10.00-10.00/g
Min. Order
1g
Purity
0.98
Supply Ability
50KG
Release date
2020-11-26
Chemwill Asia Co.,Ltd.
Product
Chloro[(tri-tert-butylphosphine)-2-(2-aMinobiphenyl)]palladiuM(II) in stock Factory 1375325-71-5
Price
US $1.00/kg
Min. Order
1kg
Purity
High quality purified manufacturer
Supply Ability
Top 3 production capacity Factory
Release date
2019-04-04

1375325-71-5, Chloro[(tri-tert-butylphosphine)-2-(2-aMinobiphenyl)]palladiuM(II)Related Search:

CHLORO[1,3-BIS(2,6-DI-I-PROPYLPHENYL)IMIDAZOL-2-YLIDENE]COPPER(I) CHLORO(1,5-CYCLOOCTADIENE)(PENTAMETHYLCYCLOPENTADIENYL)RUTHENIUM (II) tBuXPhos-Pd-G3 cataCXium A-Pd-G2 Methanesulfonato(tricyclohexylphosphine)(2'-aMino-1,1'-biphenyl-2-yl)palladiuM(II) dichloroMethane adduct P(t-Bu)3 Pd G4 Chloro[(tricyclohexylphosphine)-2-(2'-aminobiphenyl)]palladium(II) XPhos Pd G2 SPhos Pd G2 RuPhos Pd G2 Chloro[tri(p-tolyl)phosphine]gold(I),97% XantPhos-Pd-G2 Chloro[(S)-(-)-2,2'-bis(di-p-tolylphosphino)-1,1'-binaphthyl](p-cymene)ruthenium(II)chloride (2-BIPHENYL)DI-TERT-BUTYLPHOSPHINE GOLD& Chloro[(R)-(+)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole](p-cymene)ruthenium(II) chloride [RuCl(p-cymene)((R)-segphos)]Cl BrettPhosPalladacycle Chloro[tri(o-tolyl)phosphine]gold(I) Chloro{[(1R,2R)-(-)-2-amino-1,2-diphenylethyl](4-toluenesulfonyl)amido}(mesitylene)ruthenium(II), min. 90% RuCl[(R,R)-Tsdpen(mesitylene)

  • Chloro[(tri-tert-butylphosphine)-2-(2-aMinobiphenyl)]palladiuM(II)
  • P(tBu)3 Pd G2
  • Chloro(tri-t-butylphosphine)(2'-amino-1,1'-biphenyl-2-yl)palladium(II)
  • Chloro[(tri-tert-butylphosphine)-2'-amino[1,1'-biphenyl]-2-yl]palladium(II)
  • Chloro[(tri-t-butylphosphine)-2-(2-aminobiphenyl)]palladium(II)
  • Chloro[(tri-<i>tert</i>-butylphosphine)-2-(2-aminobiphenyl)]palladium(II)
  • tBu3PPdG2 catalyst
  • Chloro(tri-t-butylphosphine)(2'-amino-1,1'-biphenyl-2-yl)palladium(II), min. 98%
  • P(t-Bu)3 Palladacycle Gen.2
  • [2'-(Amino-κN)[1,1'-biphenyl]-2-yl-κC]chloro[tris(1,1-dimethylethyl)phosphine]palladium
  • Chloro(tri-tert-butylphosphine)(2'-aminobiphenylyl)palladium(II)
  • Chloro[(tri-tert-butylphosphine)-2-(2-aMinobiphenyl)]palladiuM(II) in stock Factory
  • Chloro[(tri-tert-butylphosphine)(2-aminobiphenyl-2-yl)palladium(II)
  • Chloro[(tri-tert-butylphosphine)-2-(2-aminobiphenyl)]palladium(II)&gt
  • Chloro[(tri-tert-butylphosphine)(2-aminobiphenyl-2-yl)palladium(II) / P(tBu)3 Pd G2
  • Palladium, [2'-(amino-κN)[1,1'-biphenyl]-2-yl-κC]chloro[tris(1,1-dimethylethyl)phosphine]-
  • Chloro[(tri-tert-butylphosphine)-2-(2-aMinobiphenyl)]palladiuM(II) ISO 9001：2015 REACH
  • Palladium, [2'-(amino-kN)[1,1'-biphenyl]-2-yl-kC]chloro[tris(1,1-dimethylethyl)phosphine)-
  • Chloro(tri-t-butylphosphine)(2'-amino-1,1'-biphenyl-2-yl)pal...
  • (2'-Amino-2-biphenylyl)(chloro)palladium - tris(2-methyl-2-propanyl)phosphine (1:1)
  • P(tBu)3 Pd G2 / Chloro[(tri-tert-butylphosphine)(2-aminobiphenyl-2-yl)palladium(II)
  • Chloro[(tri-tert-butylphosphine)-2-(2-aminobiphenyl)]palladium(II) [P(tbu)3 PD g2]
  • 1375325-71-5
  • C24H37ClNPPd
  • Pd