Reaction
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Bis(benzonitrile)palladium chloride

Reaction
Product Name
Bis(benzonitrile)palladium chloride
CAS No.
14220-64-5
Chemical Name
Bis(benzonitrile)palladium chloride
Synonyms
Pd(PhCN)2Cl2;BIS(BENZONITRILE)PALLADIUM(II) DICHLORIDE;Dichlorobis(benzonitrile)palladium;Bis(benzonitrile)palladium dichloride;BIS(BENZONITRILE)PALLADIUM(II) CHLORIDE;Bis(benzonitrile)palladiuM(II);DICHLOROBIS(BENZONITRILE)PALLADIUM(II);Bis(benzonitriL;Bis(benzonitrile;Bis (benzonitrile) palladiuM
CBNumber
CB4339461
Molecular Formula
C14H10Cl2N2Pd
Formula Weight
383.57
MOL File
14220-64-5.mol
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Bis(benzonitrile)palladium chloride Property

Melting point:
131 °C(lit.)
storage temp. 
Inert atmosphere,2-8°C
solubility 
Soluble in acetone, chloroform
form 
Crystalline Powder
color 
Orange to brown
Water Solubility 
insoluble
Hydrolytic Sensitivity
4: no reaction with water under neutral conditions
BRN 
3981730
Exposure limits
NIOSH: IDLH 25 mg/m3
InChI
InChI=1S/2C7H5N.2ClH.Pd/c2*8-6-7-4-2-1-3-5-7;;;/h2*1-5H;2*1H;/q;;;;+2/p-2
InChIKey
WXNOJTUTEXAZLD-UHFFFAOYSA-L
SMILES
C1(C#N)=CC=CC=C1.C1(C#N)=CC=CC=C1.[Pd](Cl)Cl
CAS DataBase Reference
14220-64-5(CAS DataBase Reference)
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Safety

Hazard Codes 
Xn
Risk Statements 
20/21-23/24/25
Safety Statements 
22-24/25-23-45-36/37-27-20-9-4
RIDADR 
UN3439
WGK Germany 
3
9
TSCA 
No
HazardClass 
6.1
PackingGroup 
III
HS Code 
28439090
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H302Harmful if swallowed

H312Harmful in contact with skin

H315Causes skin irritation

H319Causes serious eye irritation

H332Harmful if inhaled

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P270Do not eat, drink or smoke when using this product.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.

P321Specific treatment (see … on this label).

P403+P233Store in a well-ventilated place. Keep container tightly closed.

P405Store locked up.

P501Dispose of contents/container to..…

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
223689
Product name
Bis(benzonitrile)palladium(II) chloride
Purity
95%
Packaging
1g
Price
$87.6
Updated
2024/03/01
Sigma-Aldrich
Product number
223689
Product name
Bis(benzonitrile)palladium(II) chloride
Purity
95%
Packaging
10g
Price
$806
Updated
2024/03/01
TCI Chemical
Product number
B1668
Product name
Bis(benzonitrile)palladium(II) Dichloride
Purity
>98.0%(T)
Packaging
1g
Price
$199
Updated
2024/03/01
TCI Chemical
Product number
B1668
Product name
Bis(benzonitrile)palladium(II) Dichloride
Purity
>98.0%(T)
Packaging
5g
Price
$747
Updated
2024/03/01
Alfa Aesar
Product number
010006
Product name
trans-Bis(benzonitrile)dichloropalladium(II), Pd 27.1%
Packaging
1g
Price
$128.65
Updated
2024/03/01
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Bis(benzonitrile)palladium chloride Chemical Properties,Usage,Production

Reaction

  1. Catalyst for the cyclization of δ-acetylenic carboxylic acids to butenolides.
  2. Catalyst for the aza-Michael reaction of carbamates with enones.
  3. Catalyst for the rearrangement of allylic imidates to allylic amides.
  4. Catalyst for the Nazarov cyclization of α-alkoxy dienones.
  5. Catalyst for the diamination of conjugated dienes.
  6. Three component Michael addition, cyclization, cross-coupling reaction.
  7. C-H activation of indoles.

Chemical Properties

yellow powder

Uses

suzuki reaction

Uses

Catalyst for greener amine synthesis from terminal olefins by Wacker oxidation followed by transfer hydrogenation of the resultant imine.

Uses

Bis(benzonitrile)palladium(II) chloride can be used as a catalyst:

  • For greener amine synthesis from terminal olefins by Wacker oxidation, followed by transfer hydrogenation of the resultant imine.
  • In cross-coupling reactions and α-O-glycosidation.

Formal anti-Markovnikov hydroamination of terminal olefins

General Description

This product has been enhanced for catalytic efficiency.

Bis(benzonitrile)palladium chloride Preparation Products And Raw materials

Raw materials

Preparation Products

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Bis(benzonitrile)palladium chloride Suppliers

Shaanxi Rock New Materials Co., Ltd.
Tel
0917-8888777, 3380777,18691786767; 15619786767
Email
xuya@bjrock.com
Country
China
ProdList
310
Advantage
62
Nanjing Pharmaluxury Co., Ltd.
Tel
025-83726959 15851816062
Fax
025-8666-0986
Email
goodsalejs@163.com
Country
China
ProdList
128
Advantage
58
Shandong Carbene New Material Technology Co., Ltd
Tel
183-6607-2789 13305403391
Email
sdcarbene@163.com
Country
China
ProdList
327
Advantage
58
J & K SCIENTIFIC LTD.
Tel
010-82848833 400-666-7788
Fax
86-10-82849933
Email
jkinfo@jkchemical.com
Country
China
ProdList
96815
Advantage
76
Meryer (Shanghai) Chemical Technology Co., Ltd.
Tel
021-61259108 18621169109
Fax
86-21-61259102
Email
market03@meryer.com
Country
China
ProdList
40228
Advantage
62
Alfa Aesar
Tel
400-6106006
Fax
021-67582001/03/05
Email
saleschina@alfa-asia.com
Country
China
ProdList
30123
Advantage
84
TCI (Shanghai) Development Co., Ltd.
Tel
021-67121386
Fax
021-67121385
Email
Sales-CN@TCIchemicals.com
Country
China
ProdList
24529
Advantage
81
ShangHai DEMO Chemical Co.,Ltd
Tel
400-021-7337 2355568890
Fax
0086-21-50182339
Email
sales@demochem.com
Country
China
ProdList
2572
Advantage
57
Beijing HwrkChemical Technology Co., Ltd
Tel
010-89508211 18501085097
Fax
010-89508210
Email
sales.bj@hwrkchemical.com
Country
China
ProdList
8418
Advantage
55
Energy Chemical
Tel
021-021-58432009 400-005-6266
Fax
021-58436166
Email
sales8178@energy-chemical.com
Country
China
ProdList
44688
Advantage
61
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View Lastest Price from Bis(benzonitrile)palladium chloride manufacturers

Shanghai Daken Advanced Materials Co.,Ltd
Product
Bis(benzonitrile)palladium(II)chloride 14220-64-5
Price
US $0.00/KG
Min. Order
1KG
Purity
98.00%
Supply Ability
100KG /month
Release date
2021-11-05
henan kanbei chemical co.,ltd
Product
Bis(benzonitrile)palladium chloride 14220-64-5
Price
US $0.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
1000kg
Release date
2022-09-23
Zhuozhou Wenxi import and Export Co., Ltd
Product
Bis(benzonitrile)palladium chloride 14220-64-5
Price
US $15.00-10.00/KG
Min. Order
1KG
Purity
99%+ HPLC
Supply Ability
Monthly supply of 1 ton
Release date
2021-07-11

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  • PdCl2C6H5CN2
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  • C14H10N2PdCl2
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  • Classes of Metal Compounds
  • Transition Metal Compounds