ChemicalBook > CAS DataBase List > Bis(benzonitrile)palladium chloride
Bis(benzonitrile)palladium chloride
Reaction- Product Name
- Bis(benzonitrile)palladium chloride
- CAS No.
- 14220-64-5
- Chemical Name
- Bis(benzonitrile)palladium chloride
- Synonyms
- Pd(PhCN)2Cl2;BIS(BENZONITRILE)PALLADIUM(II) DICHLORIDE;Dichlorobis(benzonitrile)palladium;Bis(benzonitrile)palladium dichloride;BIS(BENZONITRILE)PALLADIUM(II) CHLORIDE;Bis(benzonitrile)palladiuM(II);DICHLOROBIS(BENZONITRILE)PALLADIUM(II);Bis(benzonitriL;Bis(benzonitrile;Bis (benzonitrile) palladiuM
- CBNumber
- CB4339461
- Molecular Formula
- C14H10Cl2N2Pd
- Formula Weight
- 383.57
- MOL File
- 14220-64-5.mol
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Bis(benzonitrile)palladium chloride Property
- Melting point:
- 131 °C(lit.)
- storage temp.
- Inert atmosphere,2-8°C
- solubility
- Soluble in acetone, chloroform
- form
- Crystalline Powder
- color
- Orange to brown
- Water Solubility
- insoluble
- Hydrolytic Sensitivity
- 4: no reaction with water under neutral conditions
- BRN
- 3981730
- Exposure limits
- NIOSH: IDLH 25 mg/m3
- InChI
- InChI=1S/2C7H5N.2ClH.Pd/c2*8-6-7-4-2-1-3-5-7;;;/h2*1-5H;2*1H;/q;;;;+2/p-2
- InChIKey
- WXNOJTUTEXAZLD-UHFFFAOYSA-L
- SMILES
- C1(C#N)=CC=CC=C1.C1(C#N)=CC=CC=C1.[Pd](Cl)Cl
- CAS DataBase Reference
- 14220-64-5(CAS DataBase Reference)
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Safety
- Hazard Codes
- Xn
- Risk Statements
- 20/21-23/24/25
- Safety Statements
- 22-24/25-23-45-36/37-27-20-9-4
- RIDADR
- UN3439
- WGK Germany
- 3
- F
- 9
- TSCA
- No
- HazardClass
- 6.1
- PackingGroup
- III
- HS Code
- 28439090
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Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Danger
- Hazard statements
-
H302Harmful if swallowed
H312Harmful in contact with skin
H315Causes skin irritation
H319Causes serious eye irritation
H332Harmful if inhaled
- Precautionary statements
-
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P264Wash hands thoroughly after handling.
P264Wash skin thouroughly after handling.
P270Do not eat, drink or smoke when using this product.
P271Use only outdoors or in a well-ventilated area.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.
P321Specific treatment (see … on this label).
P403+P233Store in a well-ventilated place. Keep container tightly closed.
P405Store locked up.
P501Dispose of contents/container to..…
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N-Bromosuccinimide Price
Sigma-Aldrich
- Product number
- 223689
- Product name
- Bis(benzonitrile)palladium(II) chloride
- Purity
- 95%
- Packaging
- 1g
- Price
- $87.6
- Updated
- 2024/03/01
Sigma-Aldrich
- Product number
- 223689
- Product name
- Bis(benzonitrile)palladium(II) chloride
- Purity
- 95%
- Packaging
- 10g
- Price
- $806
- Updated
- 2024/03/01
TCI Chemical
- Product number
- B1668
- Product name
- Bis(benzonitrile)palladium(II) Dichloride
- Purity
- >98.0%(T)
- Packaging
- 1g
- Price
- $199
- Updated
- 2024/03/01
TCI Chemical
- Product number
- B1668
- Product name
- Bis(benzonitrile)palladium(II) Dichloride
- Purity
- >98.0%(T)
- Packaging
- 5g
- Price
- $747
- Updated
- 2024/03/01
Alfa Aesar
- Product number
- 010006
- Product name
- trans-Bis(benzonitrile)dichloropalladium(II), Pd 27.1%
- Packaging
- 1g
- Price
- $128.65
- Updated
- 2024/03/01
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Bis(benzonitrile)palladium chloride Chemical Properties,Usage,Production
Reaction
- Catalyst for the cyclization of δ-acetylenic carboxylic acids to butenolides.
- Catalyst for the aza-Michael reaction of carbamates with enones.
- Catalyst for the rearrangement of allylic imidates to allylic amides.
- Catalyst for the Nazarov cyclization of α-alkoxy dienones.
- Catalyst for the diamination of conjugated dienes.
- Three component Michael addition, cyclization, cross-coupling reaction.
- C-H activation of indoles.
Chemical Properties
yellow powder
Uses
suzuki reaction
Uses
Catalyst for greener amine synthesis from terminal olefins by Wacker oxidation followed by transfer hydrogenation of the resultant imine.
Uses
Bis(benzonitrile)palladium(II) chloride can be used as a catalyst:
- For greener amine synthesis from terminal olefins by Wacker oxidation, followed by transfer hydrogenation of the resultant imine.
- In cross-coupling reactions and α-O-glycosidation.
Formal anti-Markovnikov hydroamination of terminal olefins
General Description
This product has been enhanced for catalytic efficiency.
Bis(benzonitrile)palladium chloride Preparation Products And Raw materials
Raw materials
Preparation Products
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Bis(benzonitrile)palladium chloride Suppliers
- Tel
- --
- Fax
- --
- Country
- Singapore
- ProdList
- 2215
- Advantage
- 39
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View Lastest Price from Bis(benzonitrile)palladium chloride manufacturers
Shanghai Daken Advanced Materials Co.,Ltd
- Product
- Bis(benzonitrile)palladium(II)chloride 14220-64-5
- Price
- US $0.00/KG
- Min. Order
- 1KG
- Purity
- 98.00%
- Supply Ability
- 100KG /month
- Release date
- 2021-11-05
henan kanbei chemical co.,ltd
- Product
- Bis(benzonitrile)palladium chloride 14220-64-5
- Price
- US $0.00/kg
- Min. Order
- 1kg
- Purity
- 99%
- Supply Ability
- 1000kg
- Release date
- 2022-09-23
Zhuozhou Wenxi import and Export Co., Ltd
- Product
- Bis(benzonitrile)palladium chloride 14220-64-5
- Price
- US $15.00-10.00/KG
- Min. Order
- 1KG
- Purity
- 99%+ HPLC
- Supply Ability
- Monthly supply of 1 ton
- Release date
- 2021-07-11
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